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From a chemistry aspect, graphene is the extrapolated extreme of condensed polycyclic hydrocarbon molecules to infinite size. Here, the concept on aromaticity which organic chemists utilize is applicable. Interesting issues appearing between physics and chemistry are pronounced in nano-sized graphene (nanographene), as we recognize the importance of the shape of nanographene in understanding its electronic structure. In this book, the fundamental issues on the electronic, magnetic, and chemical properties of condensed polycyclic hyodrocarbon molecules, nanographene and graphene are comprehensively discussed.
The author explores 250 of the most significant and interesting chemistry milestones from c. 500,000 BCE to 2030. Chronologically organized, the entries each consist of a short summary and an image. The book presents an array of discoveries, theories, and technological applications as it traces the evolution of the "central science"--Publisher's description.
What are the chemical aspects of graphene as a novel 2D material and how do they relate to the molecular structure? This book addresses these important questions from a theoretical and computational standpoint. Graphene Chemistry: Theoretical Perspectives presents recent exciting developments to correlate graphene’s properties and functions to its structure through state-of-the-art computational studies. This book focuses on the chemistry aspect of the structure-property relationship for many fascinating derivatives of graphene; various properties such as electronic structure, magnetism, and chemical reactivity, as well as potential applications in energy storage, catalysis, and nanoelectronics are covered. The book also includes two chapters with significant experimental portions, demonstrating how deep insights can be obtained by joint experimental and theoretical efforts. Topics covered include: Graphene ribbons: Edges, magnetism, preparation from unzipping, and electronic transport Nanographenes: Properties, reactivity, and synthesis Clar sextet rule in nanographene and graphene nanoribbons Porous graphene, nanomeshes, and graphene-based architecture and assemblies Doped graphene: Theory, synthesis, characterization and applications Mechanisms of graphene growth in chemical vapor deposition Surface adsorption and functionalization of graphene Conversion between graphene and graphene oxide Applications in gas separation, hydrogen storage, and catalysis Graphene Chemistry: Theoretical Perspectives provides a useful overview for computational and theoretical chemists who are active in this field and those who have not studied graphene before. It is also a valuable resource for experimentalist scientists working on graphene and related materials, who will benefit from many concepts and properties discussed here.
This book focuses on a group of new materials labeled "graphene oxides." It provides a comprehensive overview of graphene oxide-based nanomaterials in terms of their synthesis, structures, properties, and extensive applications in catalysis, separation, filtration, energy storage and conversion. The book also covers emerging research on graphite oxides and the impact of the research on fundamental and applied sciences.
Graphene: Fabrication, Characterizations, Properties and Applications presents a comprehensive review of the current status of graphene, especially focused on synthesis, fundamental properties and future applications, aiming to giving a comprehensive reference for scientists, researchers and graduate students from various sectors. Graphene, a single atomic layer of carbon hexagons, has stimulated a lot of research interest owing to its unique structure and fascinating properties. The book is devoted to understanding graphene fundamentally yet comprehensively through a wide range of issues in the areas of materials science, chemistry, physics, electronics and biology. The book is an important resource of comprehensive knowledge pertinent to graphene and to related expanding areas. This valuable book will attract scientists, researchers and graduate students in physics and chemistry because it aims at providing all common knowledge of these communities including essential aspects of material synthesis and characterization, fundamental physical properties and detailed chapters focused on the most promising applications. Presents a comprehensive and up-to-date review of current research of graphene, especially focused on synthesis, fundamental properties and future applications Includes not only fundamental knowledge of graphene materials, but also an overview of special properties for different potential applications of graphene in the fields of solar cells, photodetectors, energy storage, composites, environmental materials and bio-materials Emphasizes graphene-based applications that are quickly emerging as potential building blocks for nanotechnological commercial applications
Analytical Applications of Graphene for Comprehensive Analytical Chemistry, Volume 91 in the Comprehensive Analytical Chemistry series, highlights new advances in the field, with this new volume presenting interesting chapters on a variety of interesting topics, including Graphene based Nanocomposites: Synthesis, Properties and Application as Electrochemical Sensors, Graphene based Sample Preparation Techniques, Graphene Based Sample Preparation Techniques, Graphene-based thin film nanocomposite membranes for separation and purification, Analytical Applications of Graphene Oxide for Membrane Processes as Separation and Concentration Methods, Physico-chemically Functionalized Hybrid Graphene Derivatives for Miniaturized Microfluidics and Biotransducer Platform, and much more. Other chapters cover Graphene-based chemiresistive gas sensors, Graphene based Sensors, Applications of graphene-based sensors for biomedical industries, Point of care applications with graphene in human life, Ethical, Legal, Social & Economics Issues of Graphene, Safety and toxicity concerns of graphene and its composites, and the Future of Analytical Chemistry with Graphene. - Provides the authority and expertise of leading contributors from an international board of authors - Presents the latest release in the Comprehensive Analytical Chemistry series - Contains the latest information on the analytical applications of graphene for analytical chemistry
Chemistry of Graphene - Synthesis, Reactivity, Applications, and Toxicities presents an in-depth exploration of new trends, concepts, and phenomena in the general field of graphene research to introduce graphene science in a multidimensional manner providing a definitive foundation and provoking new ideas and critical insight into the emerging areas of research for the professional researchers and other practitioners. The development of graphene science, which has been rapidly expanding since the year 2024, still attracts a lot of attention with expanding new opportunities and potential in the global market. The current book opens with an in-depth survey of novel methods that have characterized graphene production research over the last three decades. It lends itself to the shifting trends toward the scalability of graphene technologies, the diversified emerging graphene-related materials, processes, and opportunities for fashioning novel scalable applications. The book continues to explore the prospects of graphene in electrochemical applications and wraps up with a survey of the potential harmful effects of graphene and its implications on graphene applications in medicine, environment, and related fields. The work represents an in-depth effort that can serve to introduce early career scholars and practitioners to graphene research but also remains adequately engaging to provoke new thought lines that stimulate the development of new research topics for expert professionals.
Introduction to Graphene: Chemical and Biochemical Applications addresses a broad range of graphene research, including the prehistory and background of graphene, synthetic approaches, characterization techniques, composites/derivatives, inorganic graphene analogues, and applications of graphene. The book's special emphasis on solution chemistry and graphene sets it apart from less practical titles in that its concepts are immediately implementable in the laboratories of chemists and biochemists. The book presents a variety of experimental approaches from the authors' research laboratories and others around the world for graphene preparation in the solution phase, especially under aqueous conditions or in animal serum—the most practical kind of graphene for chemists and biochemists. The book is ideally suited for a broad range of readers, including advanced undergraduates, graduate research students and professionals in state-of-the-art research labs who want to use graphene to develop novel applications. - Features reviews of the most recent advances in graphene research across chemistry and biochemistry - Emphasizes chemical and biological applications for specialists, aiding more multi-disciplinary research - Presents a variety of experimental approaches for graphene preparation in the solution phase, especially under aqueous conditions or even in animal serum
Graphene’s nickname ‘miracle material’ normally means the material superior properties. However, all these characteristics are only the outward manifestation of the wonderful nature of graphene. The real miracle of graphene is that the specie is a union of two entities: a physical - and a chemical one, each of which is unique in its own way. The book concerns a very close interrelationship between graphene physics and chemistry as expressed via typical spin effects of a chemical physics origin. Based on quantum-chemical computations, the book is nevertheless addressed to the reflection of physical reality and it is aimed at an understanding of what constitutes graphene as an object of material science – sci graphene – on the one hand, and as a working material- high tech graphene - for a variety of attractive applications largely discussed and debated in the press, on the other. The book is written by a user of quantum chemistry, sufficiently experienced in material science, and the chemical physics of graphene is presented as the user view based on results of extended computational experiments in tight connection with their relevance to physical and chemical realities. The experiments have been carried out at the same theoretical platform, which allows considering different sides of the graphene life at the same level in light of its chemical peculiarity.