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Grain boundaries are a main feature of crystalline materials. They play a key role in determining the properties of materials, especially when grain size decreases and even more so with the current improvements of processing tools and methods that allow us to control various elements in a polycrystal. This book presents the theoretical basis of the study of grain boundaries and aims to open up new lines of research in this area. The treatment is light on mathematical approaches while emphasizing practical examples; the issues they raise are discussed with reference to theories. The general approach of the book has two main goals: to lead the reader from the concept of ‘ideal’ to ‘real’ grain boundaries; to depart from established knowledge and address the opportunities emerging through "grain boundary engineering", the control of morphological and crystallographic features that affect material properties. The book is divided in three parts: I ‘From interganular order to disorder’ deals with the concept of the perfect grain boundary, at equilibrium, and questions the maintenance of its crystalline state. II ‘From the ideal to the real grain boundary’ deals with the concept of the faulted grain boundary. It attempts to reveal the influence of the grain boundary structure on its defects, their formation and their accommodation. III ‘From free to constrained grain boundaries’ is devoted to grain boundary ensembles starting from the triple junction (the elemental configuration) to real grain boundary networks in polycrystals This part covers a new and topical development in the field. It presents for the first time an avenue for researchers working on macroscopic aspects, to approach the scale of description of grain boundaries. Audience: graduate students, researchers and engineers in Materials Science and all those scientists pursuing grain boundary engineering in order to improve materials performance.
Grain boundaries are important structural components of polycrystalline materials used in the vast majority of technical applications. Because grain boundaries form a continuous network throughout such materials, their properties may limit their practical use. One of the serious phenomena which evoke these limitations is the grain boundary segregation of impurities. It results in the loss of grain boundary cohesion and consequently, in brittle fracture of the materials. The current book deals with fundamentals of grain boundary segregation in metallic materials and its relationship to the grain boundary structure, classification and other materials properties.
The behavior of adjacent materials at the boundary where they meet is an essential aspect of creating new engineering materials. Grain Boundary Migration in Metals is an authoritative account of the physics of grain boundary motion, written by two highly respected researchers. They provide a comprehensive overview of current knowledge regarding the migration process and how it affects microstructure evolution, focusing their treatment exclusively on the properties and behavior of grain boundaries with well defined geometry and crystallography. With their emphasis on applications-such as the characterization of microstructure and texture, recrystallization, and grain growth-the authors effectively fill the gap between the physics of grain boundary motion and its engineering practicality. The need for better microstructural design motivates permanent thrust for research in the field, and continued rapid progress appears inevitable. Grain Boundary Migration in Metals provides a solid foundation in the phenomena and serves as a valuable reference for professionals in materials science, solid state physics, and any industry engaged in metals production and the heat treatment of metals and alloys.
First published in 1997. Routledge is an imprint of Taylor & Francis, an informa company.
The choice of a material for a certain application is made taking into account its properties. If, for example one would like to produce a table, a hard material is needed to guarantee the stability of the product, but the material should not be too hard so that manufacturing is still as easy as possible - in this simple example wood might be the material of choice. When coming to more advanced applications the required properties are becoming more complex and the manufacturer`s desire is to tailor the properties of the material to fit the needs. To let this dream come true, insights into the microstructure of materials is crucial to finally control the properties of the materials because the microstructure determines its properties. Written by leading scientists in the field of microstructural design of engineering materials, this book focuses on the evolution and behavior of granular microstructures of various advanced materials during plastic deformation and treatment at elevated temperatures. These topics provide essential background and practical information for materials scientists, metallurgists and solid state physicists.
This book summarizes the most recent aspects of polycrystalline semiconductors as presented at the conference Polycrystalline Semiconductors - Grain Boundaries and Interfaces. It contains 12 review articles on selected topics written by experts in their fields and 41 complementary contributed papers. The structure, chemistry and physics of grain boundaries and other interfaces are experimentally and theoretically studied. Aspects of the technologically important polycrystalline silicon are discussed in detail. Also covered are other polycrystalline semiconductors, germanium and compound semiconductors, that are currently of interest in fundamental research and in the technology of solar cells and thin film devices. Anyone interested in polycrystalline semiconductors will be able to use this comprehensive collection to advantage. It also suggests directions for new research and development.
Microstructure and Texture in Steels and Other Materials comprises a collection of articles pertaining to experimental and theoretical aspects of the evolution of crystallographic texture and microstructure during processing of steels and some other materials. Among the topics covered is the processing-microstructure-texture-property relationship in various kinds of steels, including the latest grade. Special emphasis has been given to introduce recent advances in the characterization of texture and microstructure, as well as modeling. The papers included are written by well-known experts from academia and industrial R and D, which will provide the reader with state-of-the-art, in-depth knowledge of the subject. With these attributes, Microstructure and Texture in Steels and Other Materials is expected to serve the cause of creating awareness of current developments in microstructural science and materials engineering among academic and R and D personnel working in the field.
Perovskite Photovoltaics and Optoelectronics Discover a one-of-a-kind treatment of perovskite photovoltaics In less than a decade, the photovoltaics of organic-inorganic halide perovskite materials has surpassed the efficiency of semiconductor compounds like CdTe and CIGS in solar cells. In Perovskite Photovoltaics and Optoelectronics: From Fundamentals to Advanced Applications, distinguished engineer Dr. Tsutomu Miyasaka delivers a comprehensive exploration of foundational and advanced topics regarding halide perovskites. It summarizes the latest information and discussion in the field, from fundamental theory and materials to critical device applications. With contributions by top scientists working in the perovskite community, the accomplished editor has compiled a resource of central importance for researchers working on perovskite related materials and devices. This edited volume includes coverage of new materials and their commercial and market potential in areas like perovskite solar cells, perovskite light-emitting diodes (LEDs), and perovskite-based photodetectors. It also includes: A thorough introduction to halide perovskite materials, their synthesis, and dimension control Comprehensive explorations of the photovoltaics of halide perovskites and their historical background Practical discussions of solid-state photophysics and carrier transfer mechanisms in halide perovskite semiconductors In-depth examinations of multi-cation anion-based high efficiency perovskite solar cells Perfect for materials scientists, crystallization physicists, surface chemists, and solid-state physicists, Perovskite Photovoltaics and Optoelectronics: From Fundamentals to Advanced Applications is also an indispensable resource for solid state chemists and device/electronics engineers.
The annealing of deformed materials is of both technological importance and scientific interest. The phenomena have been most widely studied in metals, although they occur in all crystalline materials such as the natural deformation of rocks and the processing of technical ceramics. Research is mainly driven by the requirements of industry, and where appropriate, the book discusses the extent to which we are able to formulate quantitative, physically-based models which can be applied to metal-forming processes.The subjects treated in this book are all active research areas, and form a major part of at least four regular international conference series. However, there have only been two monographs published in recent times on the subject of recrystallization, the latest nearly 20 years ago. Since that time, considerable advances have been made, both in our understanding of the subject and in the techniques available to the researcher.The book covers recovery, recrystallization and grain growth in depth including specific chapters on ordered materials, two-phase alloys, annealing textures and annealing during and after hot working. Also contained are treatments of the deformed state and the structure and mobility of grain boundaries, technologically important examples and a chapter on computer simulation and modelling. The book provides a scientific treatment of the subject for researchers or students in Materials Science, Metallurgy and related disciplines, who require a more detailed coverage than is found in textbooks on physical metallurgy, and a more coherent treatment than will be found in the many conference proceedings and review articles.