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Gas hydrates are ice-like crystalline substances that form a rigid cage of water molecules and entrap hydrocarbon and non-hydrocarbon gas by hydrogen bonding. Natural gas hydrate is primarily composed of water and methane. These are solid, crystalline, ice-like substances found in permafrost areas and deepwater basins around the world. They naturally occur in the pore space of marine sediments, where appropriate high pressure and low temperature conditions exist in an adequate supply of gas (mainly methane). Gas hydrates are considered as a potential non conventional energy resource. Methane hydrates are also recognized as, an influence on offshore platform stability, a major factor in climate change contributing to global warming and a significant contribution to the ocean carbon cycle. The proposed book treats various geophysical techniques in order to quantify the gas hydrate reserves and their impact on environment. The primary goal of this book is to provide the state of art for gas hydrate exploration. The target audiences for this book are non-specialist from different branches of science, graduate students and researchers.
The occurrence of gas hydrates in large quantities worldwide, and their immense energy potential have prompted concerted efforts into their exploration and understanding over the last many years. During this time, geophysical characterization of natural gas hydrate occurrences by seismic and other methods have gained prominence, and such studies have been reported from time to time. However, no compilation of such studies was ever attempted. This SEG publication, Geophysical Characterization of Gas Hydrates (Geophysical Developments No. 14), is the first book on the topic that focuses on documenting various types of geophysical studies that are carried out for the detection and mapping of gas hydrates.
Gas hydrates in their natural environment and for potential industrial applications (Volume 2).
Gas hydrates, or clathrate hydrates, are crystalline solids resembling ice, in which small (guest) molecules, typically gases, are trapped inside cavities formed by hydrogen-bonded water (host) molecules. They form and remain stable under low temperatures – often well below ambient conditions – and high pressures ranging from a few bar to hundreds of bar, depending on the guest molecule. Their presence is ubiquitous on Earth, in deep-marine sediments and in permafrost regions, as well as in outer space, on planets or comets. In addition to water, they can be synthesized with organic species as host molecules, resulting in milder stability conditions: these are referred to as semi-clathrate hydrates. Clathrate and semi-clathrate hydrates are being considered for applications as diverse as gas storage and separation, cold storage and transport and water treatment. This book is the first of two edited volumes, with chapters on the experimental and modeling tools used for characterizing and predicting the unique molecular, thermodynamic and kinetic properties of gas hydrates (Volume 1) and on gas hydrates in their natural environment and for potential industrial applications (Volume 2).
The first comprehensive presentation of methods and algorithms used in basin modeling, this text provides geoscientists and geophysicists with an in-depth view of the underlying theory and includes advanced topics such as probabilistic risk assessment methods.
Natural gas hydrate, a solid form of natural gas and water, occurs in nature in association with deep permafrost and in offshore environments adjacent to continental margins. This report presents results of a gas hydrate research well project located at the north-eastern edge of the Mackenzie Delta. The project brought together researchers from North America and Japan to undertake the first investigation of a natural gas hydrate occurrence beneath permafrost that included extensive dedicated coring and associated engineering and scientific studies. The report compiles papers from the project in the following categories: an overview of the project, including drilling operations; a regional overview of gas hydrate occurrences, permafrost conditions, and geology in the project area; geology and biostratigraphy of the drilled cores; physical properties and geochemistry of the cores; characteristics of the gas hydrate, including chemical and physical analyses; downhole geophysics; and regional gas hydrate occurrences, production, and climate change considerations. Includes author index.
From a geological perspective, gas hydrates are an important feature of the shallow geosphere. If current estimates are correct, gas hydrates contain more potential fossil fuel energy than is present in conventional oil, gas and coal deposits, although it is uncertain how much of this can be exploited. They are also geological agents that affect the physical, geophysical and geochemical properties of sediments. Oceanic gas hydrates are increasingly recognized as a major potential hazard for the stability of offshore structures in various deep-water hydrocarbon provinces. The possibility also exists that a large release of methane from gas hydrates may have a significant impact on the radiative properties of the atmosphere and thus influence global climate: past, present and future. Following an introduction and overviews, this book covers analysis and modelling of hydrate formation; exploration strategy and reservoir evaluation; regional case studies; relevance to margin stability and climate change. Hydrate research informatiloln is presented from the USA, Russia, South Asia and the European Union.
1. THE BEGINNINGS OF HYDRATE RESEARCH Until very recently, our understanding of hydrate in the natural environment and its impact on seafloor stability, its importance as a sequester of methane, and its potential as an important mechanism in the Earth's climate change system, was masked by our lack of appreciation of the vastness of the hydrate resource. Only a few publications on naturally occurring hydrate existed prior to 1975. The first published reference to oceanic gas hydrate (Bryan and Markl, 1966) and the first publication in the scientific literature (Stoll, et a1., 1971) show how recently it has been since the topic of naturally occurring hydrate has been raised. Recently, however, the number of hydrate publications has increased substantially, reflecting increased research into hydrate topics and the initiation of funding to support the researchers. Awareness of the existence of naturally occurring gas hydrate now has spread beyond the few scientific enthusiasts who pursued knowledge about the elusive hydrate because of simple interest and lurking suspicions that hydrate would prove to be an important topic. The first national conference on gas hydrate in the U.S. was held as recently as April, 1991 at the U.S. National Center of the U.s. Geological Survey in Reston Virginia (Max et al., 1991). The meeting was co-hosted by the U.s. Geological Survey, the Naval Research Laboratory, and the U.S.
Scientists and engineers use computer simulations to study relationships between a model's input parameters and its outputs. However, thorough parameter studies are challenging, if not impossible, when the simulation is expensive and the model has several inputs. To enable studies in these instances, the engineer may attempt to reduce the dimension of the model's input parameter space. Active subspaces are an emerging set of dimension reduction tools that identify important directions in the parameter space. This book describes techniques for discovering a model's active subspace and proposes methods for exploiting the reduced dimension to enable otherwise infeasible parameter studies. Readers will find new ideas for dimension reduction, easy-to-implement algorithms, and several examples of active subspaces in action.