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Astrochemistry, the study of chemistry in space, is a rapidly growing field in astrophysics. Molecules are found everywhere; from our solar system to high-redshift galaxies. Gas-Phase Chemistry in Space: From elementary particles to complex organic molecules addresses the physics and chemistry of astrophysical molecules with a focus on gas-phase processes. Edited by François Lique and Alexandre Faure, alongside a collection of experts in the field, this book introduces essential concepts that govern the formation, excitation and destruction of molecules at postgraduate and research levels. A broad range of topics are covered, including early universe chemistry and stellar nucleosynthesis, and the study of bimolecular reaction kinetics. Detailed descriptions of the gas-phase process are provided and recent examples of the interplay between observational and laboratory astrophysics are examined. Coinciding with the timely arrival of powerful new telescopes, this work examines numerous advances in astrochemistry and paves the way for these advances to be implemented in the future. More than 100 figures are used, alongside examples, providing both theoretical and experimental perspectives. Book jacket.
Gas-Phase Chemistry in Space is written by a collection of experts in the field of astrochemistry. The book introduces essential concepts that govern the formation, excitation and destruction of molecules at postgraduate and research levels. A broad range of topics are covered; from early universe chemistry and stellar nucleosynthesis, to the study of bimolecular reaction kinetics.
Advances in Gas Phase Ion Chemistry
This volume contains the lectures presented at the first course of the Inter national School of Space Chemistry held in Erice (Sicily) from May 10 to May 20 at the 'E. Majorana Centre for Scientific Culture'. The course was attended by 57 participants from 11 countries. The recognition by Professor A. Zichichi that space chemistry is one of the important and rapidly growing scientific disciplines with many and varied appli cations provided the stimulation to initiate this new school. Historically, the study of chemistry in space had its major origins in comets, the solar nebula and circumstellar envelopes before the interstellar medium achieved its current prominence. A remarkably rapid development in interstellar chemistry was precipitated by the discovery of formaldehyde in the late 1960's made possible by the new radio observational techniques. A four atom molecule in interstellar space was indeed a surprise considering that only a short time ear lier there were still arguments about the existence of the simplest of all molecules - the hydrogen molecule. The application of ion-molecule reactions to interstellar cloud chemistry provided a rich variety of new possibilities which were, however, continuously under pressure to keep pace with radio-astronomical discoveries of more and more complex molecules.
Dust is widespread in the galaxy. To astronomers studying stars it may be just an irritating fog, but it is becoming widely recognized that cosmic dust plays an active role in astrochemistry. Without dust, the galaxy would have evolved differently, and planetary systems like ours would not have occurred. To explore and consolidate this active area of research, Dust and Chemistry in Astronomy covers the role of dust in the formation of molecules in the interstellar medium, with the exception of dust in the solar system. Each chapter provides thorough coverage of our understanding of interstellar dust, particularly its interaction with interstellar gas. Aimed at postgraduate researchers, the book also serves as a thorough review of this significant area of astrophysics for practicing astronomers and graduate students.
Introducing astrochemistry to a wide audience, this book describes how molecules formed in chemical reactions occur in a range of environments in interstellar and circumstellar space, from shortly after the Big Bang up to the present epoch. Stressing that chemistry in these environments needs to be driven, it helps identify these drivers and the various chemical networks that operate giving rise to signature molecules that enable the physics of the region to be better understood. The book emphasises, in a non-mathematical way, the chemistry of the Milky Way Galaxy and its planet-forming regions, describes how other galaxies may have rather different chemistries and shows how chemistry was important even in the Early Universe when most of the elements had yet to be formed. This book will appeal to anyone with a general interest in chemistry, from students to professional scientists working in interdisciplinary areas and non-scientists fascinated by the evolving and exciting story of chemistry in the cosmos.
Superseding Gardiner's "Combustion Chemistry", this is an updated, comprehensive coverage of those aspects of combustion chemistry relevant to gas-phase combustion of hydrocarbons. The book includes an extended discussion of air pollutant chemistry and aspects of combustion, and reviews elementary reactions of nitrogen, sulfur and chlorine compounds that are relevant to combustion. Methods of combustion modeling and rate coefficient estimation are presented, as well as access to databases for combustion thermochemistry and modeling.
In this report we summarize the results of the work carried out in our laboratory under the project "Flow Tube Studies of Gas Phase Chemical Processes of Atmospheric Importance." Molina, Mario J. Goddard Space Flight Center
Gas Phase Ion Chemistry, Volume 1 covers papers on the advances of gas phase ion chemistry. The book discusses the advances in flow tubes and the measurement of ion-molecule rate coefficients and product distributions; the ion chemistry of the earth's atmosphere; and the classical ion-molecule collision theory. The text also describes statistical methods in reaction dynamics; the state selection by photoion-photoelectron coincidence; and the effects of temperature and pressure in the kinetics of ion-molecule reactions. The energy distribution in the unimolecular decomposition of ions, as well as the rapidity of ion-molecule reactions are also encompassed. Chemists, physicists, and people working in aeronomy laboratory and involved in space research will find the book invaluable.
Ever wondered if the chemical processes taking place in space could be related to the origins of life? The authors of this book, both experienced astrochemists, embark on a discussion to find the answers to this question and more, and include a general introduction to astrochemistry for chemistry students. They explore chemistry occurring in the universe from its very early beginnings until the present era. Based on our current understanding, astrochemistry is known to occur in interstellar gas, on dust grains and in interstellar ices, in stellar atmospheres and envelopes, in dense star- and planet-forming regions, and on planets and other bodies in planetary systems. Recent observational discoveries supported by remarkable laboratory work emphasize chemical complexity, leading to answers to the tantalizing question: can this complexity be related to the origin of life? This book provides the tools to enable chemistry students to make their own computational investigations of astrochemistry and directs study across the chemical sciences and astronomy. Concentrating on fundamental processes, this book is a useful teaching aid.