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Natural Gas Hydrates, Fourth Edition, provides a critical reference for engineers who are new to the field. Covering the fundamental properties, thermodynamics and behavior of hydrates in multiphase systems, this reference explains the basics before advancing to more practical applications, the latest developments and models. Updated sections include a new hydrate toolbox, updated correlations and computer methods. Rounding out with new case study examples, this new edition gives engineers an important tool to continue to control and mitigate hydrates in a safe and effective manner. Presents an updated reference with structured comparisons on hydrate calculation methods that are supported by practical case studies and a current list of inhibitor patents Provides a comprehensive understanding of new hydrate management strategies, particularly for multiphase pipeline operations Covers future challenges, such as carbon sequestration with simultaneous production of methane from hydrates
This is the most exhaustive study to date on natural gas hydrates. In spite of their importance, hydrates are misunderstood, and misconceptions abound. This book provides an accurate review of what hydrates are and under what conditions they will form, and it provides the engineer with the methods to predict the occurrences of hydrates.The petroleum industry spends millions every year to combat the formation of hydrates, the solid, crystalline compounds that form from water and small molecules, damaging equipment and plugging transmission lines. Understanding how, when, and where they form and using this knowledge to apply remedies in practical applications are crucial. * The most comprehensive study of natural gas hydrates* A manual for the engineer or textbook for the student* Contains cutting-edge solutions to natural gas hydrate problems
Natural Gas Hydrates, Fourth Edition, provides a critical reference for engineers who are new to the field. Covering the fundamental properties, thermodynamics and behavior of hydrates in multiphase systems, this reference explains the basics before advancing to more practical applications, the latest developments and models. Updated sections include a new hydrate toolbox, updated correlations and computer methods. Rounding out with new case study examples, this new edition gives engineers an important tool to continue to control and mitigate hydrates in a safe and effective manner. Presents an updated reference with structured comparisons on hydrate calculation methods that are supported by practical case studies and a current list of inhibitor patents Provides a comprehensive understanding of new hydrate management strategies, particularly for multiphase pipeline operations Covers future challenges, such as carbon sequestration with simultaneous production of methane from hydrates
The petroleum industry spends millions of dollars every year to combat the formation of hydrates-the solid, crystalline compounds that form from water and small molecules-that cause problems by plugging transmission lines and damaging equipment. They are a problem in the production, transmission and processing of natural gas, and it is even possible for them to form in the reservoir itself if the conditions are favorable. Natural Gas Hydrates is written for the field engineer working in the natural gas industry. This book explains how, when and where hydrates form, while providing the knowledge necessary to apply remedies in practical applications. New to the second edition, the use of new inhibitors: Kinetic Inhibitors and Anticoagulants and the topic of kinetics of hydrates. How fast do they form? How fast do they melt? New chapters on Hydrates in Nature, hydrates on the seafloor and a new section has also been added regarding the misconceptions about water dew points. Chapters on Hydrate Types and Formers, Computer Methods, Inhibiting Hydrate Formation with Chemicals, Dehydration of Natural Gas and Phase Diagrams Hydrate Dehydration of Natural Gas and Phase Diagrams have been expanded and updated along with the companion website. Understand what gas hydrates are, how they form and what can be done to combat their formation Avoid the same problems BP experienced with clogged pipelines Presents the four most common approaches to evaluate hydrates: heat, depressurization, inhibitor chemicals, and dehydration
With millions of kilometres of onshore and offshore oil and gas pipelines in service around the world, pipelines are the life’s blood of the world. Notorious for disrupting natural gas production or transmission, the formation of natural gas hydrates can cost a company hundreds of millions and lead to catastrophic equipment breakdowns and safety and health hazards. Written by an international group of experts, Natural Gas Hydrates in Flow Assurance provide an expert overview of the practice and theory in natural gas hydrates, with applications primarily in flow assurance. Compact and easy to use, the book provides readers with a wealth of materials which include the key lessons learned in the industry over the last 20 years. Packed with field case studies, the book is designed to provide hands-on training and practice in calculating hydrate phase equilibria and plug dissociation. In addition readers receive executable programs to calculate hydrate thermodynamics. Case studies of hydrates in flow assurance The key concepts underlying the practical applications An overview of the state of the art flow assurance industrial developments
Gas hydrates are ice-like crystalline substances that form a rigid cage of water molecules and entrap hydrocarbon and non-hydrocarbon gas by hydrogen bonding. Natural gas hydrate is primarily composed of water and methane. These are solid, crystalline, ice-like substances found in permafrost areas and deepwater basins around the world. They naturally occur in the pore space of marine sediments, where appropriate high pressure and low temperature conditions exist in an adequate supply of gas (mainly methane). Gas hydrates are considered as a potential non conventional energy resource. Methane hydrates are also recognized as, an influence on offshore platform stability, a major factor in climate change contributing to global warming and a significant contribution to the ocean carbon cycle. The proposed book treats various geophysical techniques in order to quantify the gas hydrate reserves and their impact on environment. The primary goal of this book is to provide the state of art for gas hydrate exploration. The target audiences for this book are non-specialist from different branches of science, graduate students and researchers.
1. THE BEGINNINGS OF HYDRATE RESEARCH Until very recently, our understanding of hydrate in the natural environment and its impact on seafloor stability, its importance as a sequester of methane, and its potential as an important mechanism in the Earth's climate change system, was masked by our lack of appreciation of the vastness of the hydrate resource. Only a few publications on naturally occurring hydrate existed prior to 1975. The first published reference to oceanic gas hydrate (Bryan and Markl, 1966) and the first publication in the scientific literature (Stoll, et a1., 1971) show how recently it has been since the topic of naturally occurring hydrate has been raised. Recently, however, the number of hydrate publications has increased substantially, reflecting increased research into hydrate topics and the initiation of funding to support the researchers. Awareness of the existence of naturally occurring gas hydrate now has spread beyond the few scientific enthusiasts who pursued knowledge about the elusive hydrate because of simple interest and lurking suspicions that hydrate would prove to be an important topic. The first national conference on gas hydrate in the U.S. was held as recently as April, 1991 at the U.S. National Center of the U.s. Geological Survey in Reston Virginia (Max et al., 1991). The meeting was co-hosted by the U.s. Geological Survey, the Naval Research Laboratory, and the U.S.
Hydrate research has expanded substantially over the past decade, resulting in more than 4,000 hydrate-related publications. Collating this vast amount of information into one source, Clathrate Hydrates of Natural Gases, Third Edition presents a thoroughly updated, authoritative, and comprehensive description of all major aspects of natural gas cla
This book introduces readers to experimental techniques of general utility that can be used to practically and reliably determine nucleation rates. It also covers the basics of gas hydrates, phase equilibria, nucleation theory, crystal growth, and interfacial gaseous states. Given its scope, the book will be of interest to graduate students and researchers in the field of hydrate nucleation. The formation of gas hydrates is a first-order phase transition that begins with nucleation. Understanding nucleation is of interest to many working in the chemical and petroleum industry, since nucleation, while beneficial in many chemical processes, is also a concern in terms of flow assurance for oil and natural gas pipelines. A primary difficulty in the investigation of gas hydrate nucleation has been researchers’ inability to determine and compare the nucleation rates of gas hydrates across systems with different scales and levels of complexity, which in turn has limited their ability to study the nucleation process itself. This book introduces readers to experimental techniques that can be used to practically and reliably determine the nucleation rates of gas hydrate systems. It also covers the basics of gas hydrates, phase equilibria, nucleation theory, crystal growth, and interfacial gaseous states. Given its scope, the book will be of interest to graduate students and researchers in the field of hydrate nucleation.
The occurrence of gas hydrates in large quantities worldwide, and their immense energy potential have prompted concerted efforts into their exploration and understanding over the last many years. During this time, geophysical characterization of natural gas hydrate occurrences by seismic and other methods have gained prominence, and such studies have been reported from time to time. However, no compilation of such studies was ever attempted. This SEG publication, Geophysical Characterization of Gas Hydrates (Geophysical Developments No. 14), is the first book on the topic that focuses on documenting various types of geophysical studies that are carried out for the detection and mapping of gas hydrates.