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The production of useful materials and the removal of polluting substances are fundamental to chemical technology, and in this respect catalytic and separation processes play essential roles. In order to cope with increasing demands to find solutions for the shortage of natural resources and global environmental pollution, rapid and significant progress in the technology is required.This book results from the successful seminar on Selective Reactions and Separation, held at Oiso, Japan, in February 1988. The seminar was organised by ASPRONC (the Association for the Progress of New Chemistry) as the fourth in a series of seminars on Frontier Technology. ASPRONC was inaugurated in 1986 and its membership comprises major companies in the chemical industry and various other sectors interested in chemistry. The aim of this seminar was to explore the frontiers of catalytic and separation technology and to discuss the requirements for its future development. The many interesting lectures and active discussions which resulted stimulated the editors to prepare this book. Each lecturer has written a chapter which represents a significantly revised and extended version of his original lecture.The book will appeal to many readers and will undoubtedly help to make a positive contribution to the future development of chemical technology.
The impact of catalysis on the nation's economy is evidenced by the fact that catalytic technologies generate U.S. sales in excess of $400 billion per year and a net positive balance of trade of $16 billion annually. This book outlines recent accomplishments in the science and technology of catalysis and summarizes important likely challenges and opportunities on the near horizon. It also presents recommendations for investment of financial and human resources by industry, academe, national laboratories, and relevant federal agencies if the nation is to maintain continuing leadership in this fieldâ€"one that is critical to the chemical and petroleum processing industries, essential for energy-efficient means for environmental protection, and vital for the production of a broad range of pharmaceuticals.
Novel Catalytic and Separation Process Based on Ionic Liquids presents the latest progress on the use of ionic liquids (ILs) in catalytic and separation processes. The book discusses the preparation of ILs, the characterization of IL catalysts by spectroscopic techniques, catalytic reactions over IL catalysts, separation science and technology of ILs, applications in biomass utilization, and synthesis of fine chemicals. Scientists, engineers, graduate students, managers, decision-makers, and others interested in ionic liquids will find this information very useful. The book can be used as a springboard for more advanced work in this area as it contains both theory and recent applications, research conducted, and developments in separation techniques and catalysis using ionic liquids. - Presents new preparation and advanced characterization of ionic liquids catalysts - Outlines catalytic reactions using ionic liquid, thus showing higher yields and selectivity - Presents novel separation science and technology based on ionic liquids and non-thermal processes
Separation science plays a critical role in maintaining our standard of living and quality of life. Many industrial processes and general necessities such as chemicals, medicines, clean water, safe food, and energy sources rely on chemical separations. However, the process of chemical separations is often overlooked during product development and this has led to inefficiency, unnecessary waste, and lack of consensus among chemists and engineers. A reevaluation of system design, establishment of standards, and an increased focus on the advancement of separation science are imperative in supporting increased efficiency, continued U.S. manufacturing competitiveness, and public welfare. A Research Agenda for Transforming Separation Science explores developments in the industry since the 1987 National Academies report, Separation and Purification: Critical Needs and Opportunities. Many needs stated in the original report remain today, in addition to a variety of new challenges due to improved detection limits, advances in medicine, and a recent emphasis on sustainability and environmental stewardship. This report examines emerging chemical separation technologies, relevant developments in intersecting disciplines, and gaps in existing research, and provides recommendations for the application of improved separation science technologies and processes. This research serves as a foundation for transforming separation science, which could reduce global energy use, improve human and environmental health, and advance more efficient practices in various industries.
The proceedings of the 11th Zeolite Conference has been published in three volumes, containing 5 plenary lectures and 274 full papers. Part A comprises Synthesis and Characterization (99 papers), Part B Catalysis and Environment (102 papers) and Part C Adsorption and Diffusion, Modifications, Novel Materials and Theory (78 papers). Zeolite science and technology has been and continues to be an area receiving great attention. Increasing interest in the synthesis and the characterization of zeolite and microporous materials is reflected in the large number of contributions. Other areas gaining recognition include novel materials, adsorption, theory and modeling.
In view of the substantial progress made in the last decade in the fields of zeolites and related materials it was decided to go for an extended 2nd Edition of "Introduction to Zeolite Science and Practice". Unfortunately - as often is the case - this process took more time than expected by the Editors.In the mean time some new texts on zeolites were issued. Nevertheless, the combination of data, discussion and dedication provided by the present book is a unique coverage of the field, in the opinion of the Editors.In the present Edition the number of chapters rose from 16-22. The contributions can be divided into three categories: updated chapters by the original authors, updated chapters by an expanded or new team of authors and completely new chapters. This 2nd Edition also contains new chapters on "Zeolite-based supramolecular assemblies" (by Dirk De Vos and Pierre Jacobs, experts in this area) and on "The use of bulky probe molecules" (by Paul Kunkeler, Roger Downing and one of the Editors).Finally, the super large pore zeolites and the fast growing area of ordered mesoporous materials are dealt with by Eelco Vogt, Charlie Kresge and and Jim Vartuli. The latter two authors belong to the discoverers of the M41S family of mesoporous materials.
Due to their unique porous properties, zeolites (also referred to as molecular sieves) are used in a variety of applications - major uses are in petrochemical cracking, ion-exchange (water softening and purification), and in the separation and removal of gases and solvents. Molecular Sieves: From Basic Research to Industrial Applications, Volume 158 A,B presents over 265 worldwide contributions on the latest developments in zeolitic research. Readers will find this book, which is divided into five sections: Synthesis, Characterization, Adsorption, Catalysis, and Novel applications, ideal for staying up to date on current research on porous materials.* Comprehensive overview of current research on porous materials* Contains experimental as well as theoretical input, reflecting the increasing overlap between theory and experiment* Contributions from the world's leading authorities
Volume I contains a brief review of adsorption history and its development for practical purposes up until now. It also presents some important information on adsorbents and catalysts as well as on the methods of their characterization. The part of this volume dealing with practical industrial applications includes chapters presenting advanced technical tools for high capacity adsorption separation of liquid and gas mixtures, development of new adsorbents for removal of hazardous contaminants from combustion flue gases and wastewaters, degasification of coal seams and fabrication of inorganic membranes and their applications. A comprehensive review is also included on contemporary utility of self-assembled monolayers, adsorption proteins and their role in modern industry, adsorption methods in technology of optical fibre glasses, sol-gel technology, solid desiccant dehumidification systems, etc. The articles give both the scientific backgrounds of the phenomena discussed and emphasize their practical aspects.The chapters give not only brief current knowledge about the studied problems, but are also a source of topical literature on the subject. A comprehensive bibliography on adsorption principles, design data and adsorbent materials for industrial applications for the period 1967-1997 concludes the book.
The Fifth International Symposium on the Characterisation of Porous Solids (COPS-V) was held at Heidelberg, Germany, from May 30 to June 2, 1999. About 220 participants from 25 countries enjoyed a very successful meeting with 32 lectures and 155 poster presentations. The Symposium started with a highly stimulating lecture by Sir John Meurig Thomas, Cambridge, highlighting the recent developments in engineering of new catalysts. The following two full sessions were devoted to theory, modelling and simulation which provide the basis for the interpretation of pore structural data of adsorbents and finely dispersed solids. Sessions 2 and 3 focused on the advances in the synthesis and characterisation of highly ordered inorganic adsorbents and carbons. Sessions 4 and 5 addressed important questions with respect to the characterisation of porous solids by sorption measurement and other related techniques. The intensive three-day programme provided a stimulating forum for the exchange of novel research findings, concepts, techniques and materials which are collected in this volume.
"Spillover and Mobility of Species and Solid Surfaces" collects the papers which were presented at the Fifth International Conference Spillover, either as oral or poster contributions, as well as the summaries of the invited lectures. This congress and its publication in the Studies on Surface Science and Catalysis series follow the tradition of previous conferences on spillover, initiated in Lyon, 1983, and continued in Leipzig, 1989, Kyoto 1993 and Dalian, 1997. For the fifth conference, held in S.L. el Escorial (Madrid), the organising committee has attempted to compile representative contributions which illustrate the advances in understanding the spillover phenomenon since 1997. Spillover is a process taking place during the interface of gas reactant molecules (mainly hydrogen and oxygen) on solid surfaces. However, different contributions to the more general area of the chemistry at surfaces, related with the mobility and migration of species, diffusion through membranes, fuel cell catalysts, etc., have also been included. In fact the title of the present volume summarizes this attempt to extend the conference topics towards dynamics at surfaces.Among the 70 contributions received, the 56 accepted papers were selected on the basis of the reports of at least two international reviewers, according to standards comparable to those applied for other specialised journals. These papers are from 21 different countries.