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Die Grundlagen der klassischen und der statistischen Thermodynamik werden hier in solider Weise anhand sorgfältig durchdachter Argumentationen eingeführt, ergänzt durch zahlreiche Beispiele und Anwendungen. Systematisch werden die Grundbegriffe der Atomtheorie erarbeitet. Gestützt auf diese Kenntnisse kann der Leser dann die Beschreibung und Vorhersage der Eigenschaften makroskopischer Systeme erlernen.
Both a comprehensive overview and a treatment at the appropriate level of detail, this textbook explains thermodynamics and generalizes the subject so it can be applied to small nano- or biosystems, arbitrarily far from or close to equilibrium. In addition, nonequilibrium free energy theorems are covered with a rigorous exposition of each one. Throughout, the authors stress the physical concepts along with the mathematical derivations. For researchers and students in physics, chemistry, materials science and molecular biology, this is a useful text for postgraduate courses in statistical mechanics, thermodynamics and molecular simulations, while equally serving as a reference for university teachers and researchers in these fields.
Both a comprehensive overview and a treatment at the appropriate level of detail, this textbook explains thermodynamics and generalizes the subject so it can be applied to small nano- or biosystems, arbitrarily far from or close to equilibrium. In addition, nonequilibrium free energy theorems are covered with a rigorous exposition of each one. Throughout, the authors stress the physical concepts along with the mathematical derivations. For researchers and students in physics, chemistry, materials science and molecular biology, this is a useful text for postgraduate courses in statistical mechanics, thermodynamics and molecular simulations, while equally serving as a reference for university teachers and researchers in these fields.
Die Grundlagen der klassischen und der statistischen Thermodynamik werden hier in solider Weise anhand sorgfältig durchdachter Argumentationen eingeführt, ergänzt durch zahlreiche Beispiele und Anwendungen. Systematisch werden die Grundbegriffe der Atomtheorie erarbeitet. Gestützt auf diese Kenntnisse kann der Leser dann die Beschreibung und Vorhersage der Eigenschaften makroskopischer Systeme erlernen.
This textbook facilitates students’ ability to apply fundamental principles and concepts in classical thermodynamics to solve challenging problems relevant to industry and everyday life. It also introduces the reader to the fundamentals of statistical mechanics, including understanding how the microscopic properties of atoms and molecules, and their associated intermolecular interactions, can be accounted for to calculate various average properties of macroscopic systems. The author emphasizes application of the fundamental principles outlined above to the calculation of a variety of thermodynamic properties, to the estimation of conversion efficiencies for work production by heat interactions, and to the solution of practical thermodynamic problems related to the behavior of non-ideal pure fluids and fluid mixtures, including phase equilibria and chemical reaction equilibria. The book contains detailed solutions to many challenging sample problems in classical thermodynamics and statistical mechanics that will help the reader crystallize the material taught. Class-tested and perfected over 30 years of use by nine-time Best Teaching Award recipient Professor Daniel Blankschtein of the Department of Chemical Engineering at MIT, the book is ideal for students of Chemical and Mechanical Engineering, Chemistry, and Materials Science, who will benefit greatly from in-depth discussions and pedagogical explanations of key concepts. Distills critical concepts, methods, and applications from leading full-length textbooks, along with the author’s own deep understanding of the material taught, into a concise yet rigorous graduate and advanced undergraduate text; Enriches the standard curriculum with succinct, problem-based learning strategies derived from the content of 50 lectures given over the years in the Department of Chemical Engineering at MIT; Reinforces concepts covered with detailed solutions to illuminating and challenging homework problems.
This 2006 textbook discusses the fundamentals and applications of statistical thermodynamics for beginning graduate students in the physical and engineering sciences. Building on the prototypical Maxwell–Boltzmann method and maintaining a step-by-step development of the subject, this book assumes the reader has no previous exposure to statistics, quantum mechanics or spectroscopy. The book begins with the essentials of statistical thermodynamics, pauses to recover needed knowledge from quantum mechanics and spectroscopy, and then moves on to applications involving ideal gases, the solid state and radiation. A full introduction to kinetic theory is provided, including its applications to transport phenomena and chemical kinetics. A highlight of the textbook is its discussion of modern applications, such as laser-based diagnostics. The book concludes with a thorough presentation of the ensemble method, featuring its use for real gases. Numerous examples and prompted homework problems enrich the text.
This book is based on many years of teaching statistical and thermal physics. It assumes no previous knowledge of thermodynamics, kinetic theory, or probability---the only prerequisites are an elementary knowledge of classical and modern physics, and of multivariable calculus. The first half of the book introduces the subject inductively but rigorously, proceeding from the concrete and specific to the abstract and general. In clear physical language the book explains the key concepts, such as temperature, heat, entropy, free energy, chemical potential, and distributions, both classical and quantum. The second half of the book applies these concepts to a wide variety of phenomena, including perfect gases, heat engines, and transport processes. Each chapter contains fully worked examples and real-world problems drawn from physics, astronomy, biology, chemistry, electronics, and mechanical engineering.
This is the definitive treatise on the fundamentals of statistical mechanics. A concise exposition of classical statistical mechanics is followed by a thorough elucidation of quantum statistical mechanics: postulates, theorems, statistical ensembles, changes in quantum mechanical systems with time, and more. The final two chapters discuss applications of statistical mechanics to thermodynamic behavior. 1930 edition.