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Fundamental study and industrial application of ion exchange membranes started over half a century ago. Through ongoing research and development, ion exchange membrane technology is now applied to many fields and contributes to the improvement of our standard of living. Ion Exchange Membranes, 2nd edition states the ion exchange membrane technology from the standpoint of fundamentals and applications. It discusses not only various phenomena exhibited by membranes but also their applications in many fields with economical evaluations. This second edition is updated and revised, featuring ten expanded chapters. New to this edition is a computer simulation program of ion-exchange membrane electrodialysis for water desalination that provides a guideline for designing, manufacturing and operating a practical-scale electrodialyzer. Meant to replace experiments, this program will be an important asset to those with time and monetary budgets.
Provides a comprehensive introduction to ion exchange for beginners and in-depth coverage of the latest advances for those already in the field As environmental and energy related regulations have grown, ion exchange has assumed a dominant role in offering solutions to many concurrent problems both in the developed and the developing world. Written by an internationally acknowledged leader in ion exchange research and innovation, Ion Exchange: in Environmental Processes is both a comprehensive introduction to the science behind ion exchange and an expert assessment of the latest ion exchange technologies. Its purpose is to provide a valuable reference and learning tool for virtually anyone working in ion exchange or interested in becoming involved in that incredibly fertile field. Written for beginners as well as those already working the in the field, Dr. SenGupta provides stepwise coverage, advancing from ion exchange fundamentals to trace ion exchange through the emerging area of hybrid ion exchange nanotechnology (or polymeric/inorganic ion exchangers). Other topics covered include ion exchange kinetics, sorption and desorption of metals and ligands, solid-phase and gas-phase ion exchange, and more. Connects state-of-the-art innovations in such a way as to help researchers and process scientists get a clear picture of how ion exchange fundamentals can lead to new applications Covers the design of selective or smart ion exchangers for targeted applications—an area of increasing importance—including solid and gas phase ion exchange processes Provides in-depth discussion on intraparticle diffusion controlled kinetics for selective ion exchange Features a chapter devoted to exciting developments in the areas of hybrid ion exchange nanotechnology or polymeric/inorganic ion exchangers Written for those just entering the field of ion exchange as well as those involved in developing the “next big thing” in ion exchange systems, Ion Exchange in Environmental Processes is a valuable resource for students, process engineers, and chemists working in an array of industries, including mining, microelectronics, pharmaceuticals, energy, and wastewater treatment, to name just a few.
"Ion exchange", as Dr. Robert Kunin has said, "is a unique technology since ft occupies a special place in at least three other scientific disciplines - polymer chemistry, polyelectrolytes and adsorption. " It may also lay claim to being one of the most widely used industrially. From its origins in water treatment and the sugar industry, through hydrometallurgical applications as diverse as the treatment of plating wastes and the tonnage production of uranium, to the present-day production of ultrapure water for the microelectronics industry, the recovery of valuable materials from sewage effluents and pollution control, the uses of ion exchange are legion. As a result, it is well-nigh impossible to prevent infiltration by the real world of even the most academic of conferences on the subject. It came as no surprise to the Scientific Board of the NATO Advanced Study Institute on "Mass Transfer & Kinetics of Ion Exchange" that one third of the lecturers, and one half of their advanced students, were from Industry, nor that the two round-table discussions, which specially featured industrial applications and future requirements, were well attended and enthusiastically debated.
Ion Exchange, 2nd Edition is a totally revised and updated version of the highly popular Monograph for Teachers, first published by The Royal Society of Chemistry in 1975. It covers the practical application of ion exchange and the synthesis of organic ion exchange resins, which have spanned nearly 60 years of development since the pioneering work of Adams and Holmes in 1935. This book covers the theory, development, and application in considerable detail and describes the history of development of ion exchange materials and the advances in their utilization in industrial processes. Key applications in such areas as water purification, hydrometallurgy, and chromatography are described and supported by chapters on the related scientific fundamentals governing equilibria and kinetics of ion exchange. Twenty-two experiments using inexpensive equipment are detailed, which not only complement a chapter dedicated to the characterization of organic exchangers, but also serve to illustrate several other pure and applied principles related to ion exchange phenomena. It is anticipated that the unique inclusion of experiments and the broad coverage of the whole text should appeal to a wide readership and offer particular relevance to practitioners in schools, colleges, and industry.
Ion exchange materials are extremely effective absorbents generally containing some functional groups with insoluble structures, which have high affinity capacities towards the targets among a series of structurally similar ions or ion groups. In recent decades, the various methods used to preparing the absorbents for contaminant removal and resource recycle from environment have been extensively studied under the backgrounds of environment pollution and resource shortages. Molecular imprinting technology (MIT) was developed rapidly as a research hot topic to prepare ion exchange materials with shape memory effects. In consideration of the advantages of molecular imprinted polymers (MIPs), including high adsorption capacities, high selectivity, easy recycle etc., their applications in the separation and concentration of target molecules or ions have been widely explored. This book briefly narrates the fundamentals and preparations of MIPs, and particularly focus on the research advances relevant to human-living environment including water, atmosphere and soil. An overview of the most important applications of the ion exchange method in the treatment of industrial wastewaters which contain heavy metal ions, and the main environmental benefits of this method are highlighted. The most important ion exchangers used in environment remediation processes, including their classification and environmental utilisations, are presented as well. The influence of operating conditions on the ion exchange process is discussed, both from efficiency and mechanism perspectives. Also, the opportunities and challenges, which make that the ion exchange method to be still an important research issue at international level, are reviewed. Other chapters familiarise the reader with innovative practices to develop sustainable water treatment methods; review the use of adsorption materials, including raw biomasses, and ion exchange resins for the treatment of olive mill wastewater; various examples of selective removal of heavy metal ions discharged in an effluent from electroplating plants, metal finishing operations, as well as mining and electronics industries through ion exchange are presented and finally; the principal mechanisms and specific features of the copper ion exchange in alkali silicate glasses is explored.
This book provides broad coverage of ion exchange and its applications. Different chapters focus on the importance of ion exchange applications such as strengtening dental porcelains, gradient changes in glass refraction, and resins as effective sorbents. Each chapter includes a brief historical overview of ion exchange and its applications. The authors also give a brief overview of these applications as well as review current experimental data on the subject.
Ion Exchange Materials: Properties and Applications fills a "two-dimensional" gap in books currently available on the subject. Firstly, there is a lack of modern comprehensive publications on the chemistry of ion exchange materials and on the relationships between their properties and practical applications. Secondly, there are few books on ion exchange chemistry that are targeted to industrial R&D specialists and research students who (i) do not work with ion exchange on a daily basis, (ii) need to develop competence in this area, and (iii) find it difficult to start studying the subject from primary scientific publications. The book bridges these gaps by describing classical and modern theoretical concepts, as well as practical approaches for using ion exchange materials. Ion exchange materials combine properties of homogeneous and heterogeneous materials. Besides being an interesting subject for investigation, they are essential in a wide variety of industrial technologies: in the chemical and biochemical industries, pharmacy, medicine, microelectronics, the nuclear industry, food production, waste treatment, and many other areas. Ion exchange is a powerful tool in chemical analysis and scientific research. The main focus in this book is on ion exchange polymers: ion exchange resins, chelating resins, imprinted (templated), and other functional polymers. It provides an in-depth study of ion exchange materials, suitable for postgraduate students and R&D industrial specialists in chemistry, chemical and biochemical technology. - Comprehensively covers the subject - Provides links between theoretical concepts, material properties, practical applications, and technical solutions - Easy to understand - requires only ground knowledge of university-level chemistry and can be read without an in-depth knowledge of mathematics - Supported with an interactive website
Ion-exchange Technology I: Theory and Materials describes the theoretical principles of ion-exchange processes. More specifically, this volume focuses on the synthesis, characterization, and modelling of ion-exchange materials and their associated kinetics and equilibria. This title is a highly valuable source not only to postgraduate students and researchers but also to industrial R&D specialists in chemistry, chemical, and biochemical technology as well as to engineers and industrialists.
Environmental Ion Exchange: Principles and Design contains the most important ion exchange-related design and application issues. Using tables, graphs, and conversion tables, this book teaches you the basics, giving you the knowledge to use ion exchange to reuse, recover, and recycle. This hands-on guide explains how to apply ion exchange to reuse wastewaters, recover valuable chemicals, and recycle industrial waters. For anyone who is designing unconventional ion exchange systems, or who needs a fundamental knowledge of ion exchange, this is the perfect working reference. Experts in environmental engineering, the authors hold nine patents related to ion exchange. In this book they share their expertise, taking you through the entire design process. Each chapter stands on its own, allowing rapid access to each topic of interest. Examples are abundant throughout, and most chapters provide reference sections for further reference and research. With Environmental Ion Exchange: Principles and Design, you will learn innovative, cost-effective solutions to water and wastewater problems.
The Principles of Ion Exchange Technology covers the fundamental properties of ion exchange resins and the chemical engineering principles of plant design to aid process and equipment evaluation, choice and design. This text is composed of 12 chapters and begins with a discussion of the equilibrium concept and the calculation of diffusion coefficients and mass transfer coefficients, as well as the rate constants in ion exchange. The succeeding chapters deal with the kinetics of ion exchange in solution and in resin beads. These topics are followed by reviews of axial mixing, flow abnormalities, design equations, fixed bed performance calculation, and multi-component ion exchange. The final chapters explore the choices of continuous and countercurrent design techniques and the practical procedures for packed beds. This book is of great value to chemical engineers.