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Functionalized polymers are macromolecules to which chemically bound functional groups are attached which can be used as catalysts, reagents, protective groups, etc. Functionalized polymers have low cost, ease of processing and attractive features for functional organic molecules. Chemical reactions for the introduction of functional groups in polymers and the conversion of functional groups in polymers depend on different properties. Such properties are of great importance for functionalization reactions for possible applications of reactive polymers. This book deals with the synthesis and design of various functional polymers, the modification of preformed polymer backbones and their various applications.
This new book covers the synthetic as well application aspects of functional polymers. It highlights modern trends in the field and showcases the recent characterization techniques that are being employed in the field of polymer science. The chapters are written by top-notch scientists who are internationally recognized in the field. The chapters will highlight the modern trend in the field.
In modern polymer science a variety of polymerization methods for the direct synthesis of polymers bearing functional groups are known. However, there is still a large number of functional groups that may either completely prevent polymerization or lead to side reactions. Post-polymerization modification, also known as polymer-analogous modification, is an alternative approach to overcome these limitations. It is based on the polymerization of monomers with functional groups that are inert towards the polymerization conditions but allow a quantitative conversion in a subsequent reaction step yielding a broad range of other functional groups. Thus, diverse libraries of functional polymers with identical average degrees of polymerization but variable side chain functionality may easily be generated. Filling the gap for a book dealing with synthetic strategies and recent developments, this volume provides a comprehensive and up-to-date overview of the field of post-polymerization modification. As such, the international team of expert authors covers a wide range of topics, including new synthetic techniques utilizing different reactive groups for post-polymerization modifications with examples ranging from modification of biomimetic and biological polymers to modification of surfaces. With its guidelines this is an indispensable and interdisciplinary reference for scientists working in both academic and industrial polymer research.
This monograph contains manuscripts, poster abstracts and summary statements representing the contributions of a group of scientists who participated in the sixth annual Texas A&M Industry-University Cooperative Chemistry Program (IUCCP) at Texas A&M University in College Station, Texas, March 22-24, 1988. This symposium on "Functional Polymers" was organized by a university-industrial steering committee consisting of Dr. D. Keene, Hoechst Celanese; Dr. D. E. McLemore, Dow Chemical Company; Dr. B. Frushour, Monsanto Company; Dr. S. Corley, Shell Development; Dr. F. Hoffstadt, BPAmerica; Dr. D. E. Bergbreiter, Texas A&M University; Dr. C. A. J. Hoeve, Texas A&M University; Dr. C. R. Martin, Texas A&M University; Dr. A. Clearfield, Texas A&M University; and Dr. A. E. Martell, Texas A&M University. The symposium itself was generously supported by the industrial companies participating in the IUCCP program. These sponsoring chemical companies include; Shell Development Company, Dow Chemical Company, BPAmerica, Monsato Company and Hoechst Celanese. The choice of "Functional Polymers" as the subject for this symposium reflects the rapid developments occurring in the broad field of polymer science and the potential for using polymeric derivatives in many new exciting and potentially profitable applications. The invited papers and submitted posters reflect the diversity of this field and include many different topics ranging from biomedical applications of polymers to conducting polymers to use of polymers as lithographic masks and recording media. General topics included in the symposium were: photoresponsive polymers, polymer blends, electronically conductive polymers, polymers catalysts, biomedical polymers and membrane transport and permeability.
Advances in Functionalized Polymer Nanocomposites: From Synthesis to Applications presents a detailed review on the synthesis, fundamental chemistry, properties, and applications of these high-performance materials. The introductory chapter provides a brief overview of the various types of organic and inorganic nanofillers used for the synthesis of polymer nanocomposites. Emphasis is placed on their fundamental chemistry, processing methods, functionalization and/or surface modification strategies. The dispersion state and their specific interaction with polymer matrices is also discussed in detail, as well as characterization techniques for functionalized nanofillers and functionalized polymer nanocomposites, and their properties, and applications. The book will be a valuable reference source for scientists, engineers, and postgraduate students, working in the field of polymer science and technology, materials science and engineering, composites, and nanocomposites. - Covers fabrication, processing, characterization, and properties of various functionalized polymer nanocomposites - Explores usage in energy storage systems, biomedical fields, environmental remediation, catalysis, gas sensing, biosensing, and electromagnetic interference (EMI) shielding - Provides information on lifecycle assessment and environmental and health impacts of these materials
The text focuses on the basic issues and also the literature of the past decade. The book provides a broad overview of functional synthetic polymers. Special issues in the text are: Surface functionalization supramolecular polymers, shape memory polymers, foldable polymers, functionalized biopolymers, supercapacitors, photovoltaic issues, lithography, cleaning methods, such as recovery of gold ions olefin/paraffin, separation by polymeric membranes, ultrafiltration membranes, and other related topics.
Advanced Functional Polymers for Biomedical Applications presents novel techniques for the preparation and characterization of functionalized polymers, enabling researchers, scientists and engineers to understand and utilize their enhanced functionality in a range of cutting-edge biomedical applications. - Provides systematic coverage of the major types of functional polymers, discussing their properties, preparation techniques and potential applications - Presents new synthetic approaches alongside the very latest polymer processing and characterization methods - Unlocks the potential of functional polymers to support ground-breaking techniques for drug and gene delivery, diagnostics, tissue engineering and regenerative medicine
This book provides an overview of the development and selection of functional polymers and nanomaterials for membrane development and their applications. It covers the definition, classification, and preparation of various functional polymers and nanocomposites, and highlights potential applications of functional polymers and nanomaterials in membrane technology. Details the selection of structural and functional materials, as well as material synthesis, modification, and characterization techniques Describes emerging applications of functional materials in wastewater treatment, desalination, energy, and bioremediation Includes numerous industrial case studies, practical examples and questions, providing a comprehensive introduction to the topic Discusses industrial potential, implementation, and limitations By combining aspects of both science and technology, this book serves as a useful resource for scientists and engineers working on membrane applications of materials.
Reactive and functional polymers are manufactured with the aim of improving the performance of unmodified polymers or providing functionality for different applications. These polymers are created mainly through chemical reactions, but there are other important modifications that can be carried out by physical alterations in order to obtain reactive and functional polymers. This volume presents a comprehensive analysis of these reactive and functional polymers. Reactive and Functional Polymers Volume Two considers the coupling, crosslinking and grafting reactions to improve the compatibility of reactive and functional polymer blends. In this book, world-renowned researchers have participated, including Dr. Sabu Thomas (Editor-in-chief for the journal ‘Nano-Structures & Nano-Objects’). With its comprehensive scope and up-to-date coverage of issues and trends in Reactive and Functional Polymers, this is an outstanding book for students, professors, researchers and industrialists working in the field of polymers and plastic materials.
Adaptive polymers include those which are responsive to different stimuli — namely physical, mechanical, chemical and biological — with controlled and/or predicable behavior. Many technological breakthroughs and scientific advances have been made in the last few decades and this volume aims to cover the most up-to-date studies and achievements in some adaptive polymers, in terms of principles of adaptiveness, properties, structure design and characterization with an emphasis on their applications, particularly in textiles, skin care, medicine and other related areas. Some versatile functional polymers, such as Chitosan, cylodextrin and dendrimer,and hyper-branched polymers are also introduced in order to provide a source for people in different professions when searching for knowledge and inspiration in the field of adaptive and functional polymers. One of the key features of this book is the fact that it is multi-disciplinary in nature, and so accessible to a wide variety of readers.