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This text covers a host of fullerene applications, including nanotubes, compounds of fullerenes with other elements and structures and polymerized fullerenes. It discusses properties of photoexcited states of fullerenes, neutral and charged states, nonlinear optical response (NLO) and electron-electron interactions.
At the interface between chemistry, biology, and physics, fullerenes were one of the first objects to be dissected, scanned, and studied by the modern multi-specialty biotech community and are currently thriving in both research and practical application. Other members of the sp2 nanocarbon family, such as nanotubes and graphene, are currently bein
In September 1985, in an attempt to simulate the chemistry in a carbon star, Harry Kroto, Bob Curl and Richard Smalley set up a mass spectrometry experiment to study the plasma produced by focusing a pulsed laser on solid graphite. Serendipitously, a dominant 720 amu mass peak corresponding to a C60 species was revealed in the time-of-flight mass spectrum of the resulting carbon clusters. It was proposed that this C60 cluster had the closed cage structure of a truncated icosahedron (a soccerball) and was named Buckminsterfullerene because geodesic dome concepts, pioneered by the architect Buckminster Fuller, played an important part in arriving at this solution. The signal for a C70 species (840 amu) , proposed to have the ellipsoidal shape of a rugbyball, was also prominent in the early experiments. Five years later, the seminal work of the Sussex! Rice collaboration was triumphantly confirmed as Wolfgang Krlitschmer and Donald Huffman succeeded in producing, and separating, bulk crystalline samples of fullerene material from arc-processed (in an inert gas atmosphere) carbon deposits. From then onwards, fullerene research continued, and still proceeds, at an exhilarating pace. The materials excited the imagination of many diverse classes of scientists, resulting in a truly interdisciplinary field. Many of our old, seemingly well-founded, preconceptions in carbon science had to be radically altered or totally abandoned, as a new round world of chemistry, physics and materials science began to unfold.
Fullerenes: From Synthesis to Optoelectronic Properties covers a host of topics in organic synthesis, photo- / radiation-chemistry, electron donor-acceptor interaction, supramolecular chemistry, and photovoltaics. The book reviews the state-of-the-art discoveries in these areas of "Fullerene Research" and presents selected examples to prove the potential of fullerenes as multifunctional moieties in well-ordered multicomponent composites. Fullerenes: From Synthesis to Optoelectronic Properties appeals to upper-level undergraduates, graduates, researchers, and professionals in the fields of condensed matter physicists; materials scientists; electrochemists; biochemists; solid-state, physical, organic, inorganic, and theoretical chemists; chemical, electrical, and optical engineers.
During the last ten years, the International Winterschools on Electronic Properties of New Materials (IWEPNM) have developed into a well-established institution and the alumni form a very active interdisciplinary community which spreads all over the world. Past schools of this series have treated such topics as conducting polymers and high temperature superconductors. The present volume contains the proceedings of the fourth school on fullerenes and fullerene derivatives. Soccer-ball molecules, like C₆₀, C₇₀, etc., have been discovered in the late 1980's and are now regarded as the third allotrope of carbon (in addition to the classic allotropes graphite and diamond). By now, more than ten thousand original papers on fullerene have been published, and the present proceedings give a snap-shot of the development of the field and the state of the art, as reflected by research papers, overviews, and tutorial lectures. Highlights are contributions on fullerene polymers, magnetic properties of fullerene complexes, endohedral compounds, fullerenes with incorporated heteroatoms, and on fullerene nanotubes (single-walled, multi-walled, with open cores or metal-filled), as well as prospects of technological applications (field emission electron guns for flat video displays, fullerene plasma for vapour deposited diamond and SiC film, etc.).
This in-depth experimental and theoretical account explores polymers and composites whose unusual properties (such as photophysical phenomena, electrical transport, phase transitions, and magnetic properties) stem from the incorporation of C60 in the material. Introductory chapters on the fundamental properties of fullerenes (C60, C70) and photophysical phenomena in fullerenes and polymers are also included.
In the period of rapid and intensive development of general electronics, this book entitled Fullerenes and Relative Materials - Properties and Applications is quite systematic and useful. It considers some aspects on synthesis, structural, vibrational, tribology, and optical properties of the fullerenes and relative materials. Some parts of the book present the specific area of the applications of the studied nanostructures. The book contains eight chapters. The special approach and interesting results on the unique properties of the materials studied as well as the different areas of their applications in general optoelectronics, solar energy and gas storage, laser and display, and biomedicine are shown. It is important for education process and for the civil and special device operations.