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The discovery of fullerenes (also known as buckyballs) has generated tremendous excitement and opened up a new field of carbon chemistry. As the first book available on this topic, this volume will be a landmark reference in the field. Because buckyballs are essentially closed hollow cages made up of carbon atoms, they can be manipulated in a variety of ways to yield never-before-seen materials. The balls can, for instance, be doped with atoms or pulled out into tubules and filled with lead to provide properties of high-temperature superconductivity. Researchers can now create their own buckyballs in a process that is almost as simple as making soot, making this research as inexpensive as it is exotic (which has doubtless contributed to its popularity). Researchers anticipate that fullerenes will offer boundless opportunities in the development of new products, drugs and materials.Science of Fullerenes and Carbon Nanotubes introduces materials scientists, chemists, and solid state physicists to the field of fullerenes, and discusses the unique properties and applications. both current and future, of all classes of fullerenes.Key Features* First comprehensive resource on fullerenes and their applications* Provides an introduction to the topic* Presents an extensive discussion of current and future applications of Fullerenes* Covers all classes of fullerenes
Until recently, the element carbon was believed to exhibit only two main allotropic forms, diamond and graphite. Research in the US and Europe has now confirmed the existence of a third previously unknown form - buckminsterfullerene (C60) and its relatives, the fullerenes (C24, C28, C32, C70 etc). The story of fullerene chemistry, physics and materials science began in 1985, almost twenty years after the existence of a spherical carbon cluster was first considered. In September 1985 a joint Sussex/Rice Universities team including Kroto, Heath, O'Brien, Curl and Smalley used a powerful mass spectrometric technique to identify the C+60 species, and proposed a spherical structure and the name buckminsterfullerene. It was not, however, until Krätschmer and Huffman reported the isolation of crystals of C60 in 1990 that the closed cage structure of C60 could be confirmed. The Fullerenes documents the work leading up to 1990 and more recent developments in the field of fullerene research and will serve as an indispensible reference tool for all workers in this area.
In this handbook, the leading experts in the field presents important and fundamental aspects of the organic and organometallic chemistry of fullerenes. Naturally they also cover the applications in material and medicinal science for these fascinating molecules. Completely self-contained, the book is logically arranged such that information is easy to retrieve, and the style lends itself to effortless reading and to learning more about the chemical properties of this family of molecules. A definitive "must" for everyone working in this ever-expanding sphere.
This book is the first of its kind to reflect upon the intense and rapidly growing interest in open geodesic polyaromatic molecules, specifically focusing on their synthesis and reactivity in metal binding reactions. The book broadly covers all aspects related to the fullerene fragment chemistry: current synthetic techniques, description of the available members of this new family (which has grown to more than two dozens members, with none being available commercially), molecular geometry and trends in the solid state packing, as well as extensions into physical properties and new buckybowl-based molecules and materials. It covers fundamental research related to a new class of hydrocarbons, namely open geodesic polyarenes that map onto the surfaces of fullerenes (and referred to as fullerene fragments or buckybowls.
This book is a review of the science and technology of the element carbon and its allotropes: graphite, diamond and the fullerenes. This field has expanded greatly in the last three decades stimulated by many major discoveries such as carbon fibers, low-pressure diamond, and the fullerenes. The need for such a book has been felt for some time. These carbon materials are very different in structure and properties. Some are very old (charcoal), others brand new (the fullerenes). They have different applications and markets and are produced by different segments of the industry.Few studies are available that attempt to review the entire field of carbon as a whole discipline. Moreover these studies were written several decades ago and a generally outdated since the development of the technology is moving very rapidly and scope of applications is constantly expanding and reaching into new fields such as aerospace, automotive, semiconductors, optics, and electronics. In this book the author provides a valuable, up-to-date account of both the newer and traditional forms of carbon, both naturally occurring and man-made. This volume will be a valuable resource for both specialists in, and occasional users of carbon materials.
An introduction to the current state of theory in a new and lively field, this volume offers both students and researchers a practical guide. It features a comprehensive set of pictures of fullerene structures and tabulates their properties. In addition, it lists a computer program that will extend the tables as needed. Seven chapters of descriptive material precede over 200 pages of tables with corresponding diagrams and serve as a self-contained introduction. Topics include fullerene cages, electronic structure, steric strain, symmetry and spectroscopy, fullerene isomerization, and carbon gain and loss. Each chapter concludes with references and notes.
Fullerene, molekulare "Fu?balle" aus 60 oder mehr Kohlenstoffatomen, sind eine Substanzklasse mit vielversprechenden Zukunftsaussichten, beispielsweise als Halbleiter, als Basis pharmazeutischer Wirkstoffe oder Polymerwerkstoffe. Dieses Buch bietet Ihnen einen aktuellen Uberblick uber das dynamische Forschungsgebiet. Zur Sprache kommen modernste Themen wie Metallofullerene, Nanorohren und organisch funktionalisierte Fullerenverbindungen. (06/00)
At the interface between chemistry, biology, and physics, fullerenes were one of the first objects to be dissected, scanned, and studied by the modern multi-specialty biotech community and are currently thriving in both research and practical application. Other members of the sp2 nanocarbon family, such as nanotubes and graphene, are currently bein
Fullerenes and nanotubes are two classes of carbon structures or allotropes, which were discovered about 17 years ago. Since that time, many chemical derivatives have been synthesized using fullerenes and nanotubes as building blocks. Particularly promising was the theory that the chemical properties of fullerenes, and certain derivatives, made them likely candidates for anticancer drugs, inhibitors of viruses such as HIV, or even as anti-bacterials. Their cyctotoxicity can also be controlled by specific circumstances. In addition, the funtionalization of nanotubes has not only produced relatively simple derivatives, but also complex hybrids with biological macromolecules, which show unique supramolecular architecture and which are promising in many medical applications. The application of fullerenes and nanotubes in medicine is at the frontier of our knowledge, thus the work in this field represents the basis for future novel developments.
The discovery of fullerenes, a new allotropic modification of carbon, is a prominent achievement of the late 20th century in chemistry. In this book, the authors present topical research in the study of the synthesis, properties and applications of fullerene. Topics discussed include phase equilibria in the fullerene-containing system; ionic compounds of fullerenes obtained by synthesis in solution; symmetrical features of fullerene structures in the fundamental domains theory of point symmetry groups; the biomedical application of fullerene; metal complex catalysts in the chemistry of fullerenes; functionalised nanofullerenes for hydrogen storage; self-assembly properties of fullerenes; and, the radiation induced phenomena in fullerenes.