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Full-Spectrum Responsive Photocatalytic Materials: From Fundamentals to Applications provides a comprehensive overview on the design, synthesis concepts, mechanisms, characterization techniques, and advances and limitations in applications of full-spectrum responsive photocatalytic materials. The book starts with the fundamentals of full-spectrum responsive materials. It then discusses the problems of most semiconductors that are not active in the whole solar spectrum and explains the benefits of utilizing full-spectrum responsive photocatalysts. Other sections describe examples of full-spectrum responsive photocatalysts classified by material types and provide the design principles and characterization protocols for these promising materials. Photocatalysis technology based on semiconductor materials holds great promise in various fields due to its potential advantages in energy-saving, cost and environmental impact. Maximizing the utilization of solar energy is always the target of pursuits in the areas of photocatalysis, and understanding and constructing appropriate full-spectrum (UV-VIS-NIR) responsive photocatalytic materials offer ways to better realize the practical utilization of photocatalysis. - Provides new insights into full-spectrum (UV-VIS-NIR) responsive photocatalysts and successful approaches for developing these materials - Assists readers working to develop more efficient catalysts and establish a solid structure–activity correlation - Suggests possibilities for the alteration of conventional photocatalysts to utilize the full spectrum of solar light
Photocatalytic materials can improve the efficiency and sustainability of processes and offer novel ways to address issues across a wide range of fields—from sustainable chemistry and energy production to environmental remediation. Current Developments in Photocatalysis and Photocatalytic Materials provides an overview of the latest advances in this field, offering insight into the chemistry and activity of the latest generation of photocatalytic materials.After an introduction to photocatalysis and photocatalytic materials, this book goes on to outline a wide selection of photocatalytic materials, not only covering typical metal oxide photocatalysts such as TiO2 but also exploring newly developed organic semiconducting photocatalysts, such as g-C3N4.Drawing on the experience of an expert team of contributors, Current Developments in Photocatalysis and Photocatalytic Materials highlights the new horizons of photocatalysis, in which photocatalytic materials will come to play an important role in our day-to-day lives. - Reviews developments in both organic- and inorganic-based materials for use in photocatalysis - Presents the fundamental chemistry and activity of a broad range of key photocatalytic materials, including both typical and novel materials - Highlights the role photocatalytic materials can play in sustainable applications
This book presents a comprehensive review of the recent progress in exploring various functional nanomaterials for the applications in photocatalysis and solar cells. This book is an essential source of reference for scientists with research fields in energy, physics, chemistry and materials. It is also suitable reading for graduate students.
This book comprises a detailed overview on the role of photocatalysts for environmental remediation, hydrogen production and carbon dioxide reduction. Effective ways to enhance the photocatalytic activity of the material via doping, hybrid material, laser light and nanocomposites have been discussed in this book. The book also further elaborates the role of metal nanoparticles, rare earth doping, sensitizers, surface oxygen vacancy, interface engineering and band gap engineering for enhancing the photocatalytic activity. An approach to recover the photocatalytic material via immobilization is also presented. This book brings to light much of the recent research in the development of such semiconductor photocatalytic systems. The book will thus be of relevance to researchers in the field of: material science, environmental science & technology, photocatalytic applications, newer methods of energy generation & conversion and industrial applications.
Nitrification and denitrification are essential processes for the aquatic ecological system and vital for human health. While ammonia is applied for disinfection together with chlorine to produce chloramine, excessive ammonia may cause nitrification and bacteria growth in the water transmission pipeline. Since excessive discharge may cause eutrophication and deterioration of the aquatic system, nitrate is regulated for wastewater discharge in sensitive areas. Further, nitrate needs to be monitored and controlled in drinking water treatment to protect against methemoglobinemia in bottle-fed infants. Various conventional technologies exist, such as adsorption, ion exchange, photocatalytic oxidation, air stripping, biological nitrification and denitrification, and so on, to remove nitrogenous compounds from water. Since ammonia and nitrate are important constituents in fertilizers besides phosphorus (P) and potassium (K), nutrient recovery is drawing attention to maintaining the supply of reliable and sustainable fertilizers. This book provides a comprehensive overview of nitrification and denitrification.
This book is a concise and up-to-date introduction to the topic of photocatalysis. It covers the fundamentals of photocatalysis, design of photoreactors and modelling and simulations for photoreaction. Also, industrial applications such as hydrogen production, water disinfection, degradation of air pollutants, pesticides and pharmaceuticals are described.
This book demonstrates the basic and fundamental aspects of nanotechnology and potential application as a photocatalysis in multiple application especially in environment and energy harvesting. This book also contains methods of preparation and characterization of unique nanostructured photocatalysts, and details about their catalytic action. The book consists of seven chapters, including the principles and fundamentals of heterogeneous photocatalysis; the mechanisms and dynamics of surface photocatalysis; research on pure and composites based materials with unique nanostructures; the latest developments and advances in exploiting photocatalyst alternatives to WO3; and photocatalytic materials for applications other than the traditional degradation of pollutants, such as carbon dioxide reduction, water oxidation, a complete spectrum of selective organic transformations and water splitting by photocatalytic reduction. This book will appeal to a wide readership of the academic and industrial researchers and it can also be used in the classroom for undergraduate and graduate students focusing on heterogeneous photocatalysis, sustainable chemistry, energy conversion and storage, nanotechnology, chemical engineering, environmental protection, optoelectronics, sensors, and surface and interface science.
Modern techniques to produce nanoparticles, nanomaterials, and nanocomposites are based on approaches that frequently involve high costs, inefficiencies, and negative environmental impacts. As such, there has been a real drive to develop and apply approaches that are more efficient and benign. The Handbook of Greener Synthesis of Nanomaterials and Compounds provides a comprehensive review of developments in this field, combining foundational green and nano-chemistry with the key information researchers need to assess, select and apply the most appropriate green synthesis approaches to their own work. Volume 2: Synthesis at the Macroscale and Nanoscale explores synthesis at different scales. Beginning with a selection of chapters discussing a range of macroscale topics, the book goes on to explore such important areas as metal nanoparticle synthesis, biogenic synthesis, and synthesis of enzymes. Further chapters explore the role of Metal Organic Frameworks in greener synthesis, synthesis from renewable sources, and impacts of nanomaterials synthesized by greener methods. - Discusses the synthesis of widely different groups of chemical compounds and distinct materials - Reviews synthesis at both the macro and nanoscales, including information on metal-organic frameworks, carbon dots and ionic liquids - Provides examples of applications to support learning and guide implementation of theory in practice
This critical volume examines the different methods used for the synthesis of a great number of photocatalysts, including TiO2, ZnO and other modified semiconductors, as well as characterization techniques used for determining the optical, structural and morphological properties of the semiconducting materials. Additionally, the authors discuss photoelectrochemical methods for determining the light activity of the photocatalytic semiconductors by means of measurement of properties such as band gap energy, flat band potential and kinetics of hole and electron transfer. Photocatalytic Semiconductors: Synthesis, Characterization and Environmental Applications provide an overview of the semiconductor materials from first- to third-generation photocatalysts and their applications in wastewater treatment and water disinfection. The book further presents economic and toxicological aspects in the production and application of photocatalytic materials.