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Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.
Modification of Lipid Metabolism is a collection of proceedings presented at the Symposium on Modification of Lipid Metabolism, held during the American Chemical Society meeting in Atlantic City, New Jersey, on September 10-11, 1974. The symposium provided a forum for discussing advances in the modification of lipid metabolism and tackled topics ranging from the effect of dietary rapeseed oil on cardiac tissue to inborn errors of lipid metabolism and lysosomal storage disorders. Comprised of 10 chapters, this book begins with an overview of advances in the composition, structure, and functions of lipids in metabolic pathways, followed by a discussion on the effect of dietary rapeseed oil on cardiac tissue. The reader is then introduced to genetic lipid storage diseases, along with their diagnosis and treatment. Viral modification of cell surface glycosphingolipids as an important factor in contact inhibition of cell growth and division is also examined. Subsequent chapters deal with different approaches to the problem of obesity, dietary regulation of lipid storage and the use of a metabolic inhibitor to reduce lipid storage; the importance of perinatal nutrition; factors in the environment that may effect tissue lipids and their metabolism; and phase transitions in membranes and the effect of temperature changes on changes in lipids and proteins of membranes. This monograph should be of interest to practitioners in the fields of biology, biochemistry, and food science and nutrition.
Polymer Syntheses, Volume I presents detailed laboratory instructions for the preparation of polymers by different functional group classes. This book provides the laboratory procedures for the preparation of polymers containing phosphorus in various oxidation states. Organized into 15 chapters, this volume begins with an overview of some selected preparative methods for carrying out the major methods of polymerization in the laboratory. This text then examines the synthesis of phosphonitrilic polymers. Other chapters consider the synthesis of peroxide and hydroperoxide free radical initiators. This book discusses as well the principles involved in the preparation of emulsion polymers, which are applicable to the preparation of polymers of a wide variety of vinyl monomers and many copolymerizations. The final chapter deals with the chemistry of organometallic and organometalloid peroxides. This book is a valuable resource for chemists involved in the designing of phosphorus polymers to meet fire retardant requirements of various products.
The well respected and ever popular Fieser and Fieser series on reagents for organic synthesis provides concise descriptions, good structural formulas and selected examples of applications. Provides references to new reagents as well as to reagents included in previous volumes Thousands of entries abstract the most important information on commonly used and new reagents, including preparation, uses, sources of supply, critical comments, references and more Reagents are considered in alphabetical order by common usage names.
High Temperature Vapors: Science and Technology focuses on the relationship of the basic science of high-temperature vapors to some areas of discernible practical importance in modern science and technology. The major high-temperature problem areas selected for discussion include chemical vapor transport and deposition; the vapor phase aspects of corrosion, combustion, and energy systems; and extraterrestrial high-temperature species. This book is comprised of seven chapters and begins with an introduction to the nature of the high-temperature vapor state, the scope and literature of high-temperature vapor-phase chemistry, and the role of high-temperature vapors in materials science. The discussion then turns to gas-solid reactions with vapor products; chemical vapor transport and deposition; vapor-phase aspects of corrosion at high temperature; and flames and combustion. High-temperature vapor-phase processes associated with gas turbine systems are also considered. The final chapter is devoted to the chemistry of high-temperature species in space. This monograph should serve as a valuable reference for undergraduate and graduate students, as well as scientists in fields such as chemistry, physics, materials science, and metallurgy.
In 1974, as we approached the National Bicentennial and the Centenary of the American Chemical Society, Professor Otto Vogl, then Chairman of the Division of Polymer Chemistry, arranged a very special symposium dedicated to a review of the history of the Divi sion. It was an extraordinary occasion which included remarks by Professors Herman Mark, Charles Marvel, William Bailey, and Charles Overberger, all past Chairmen of the Division. The Executive Committee of the Division of Polymer Chemistry felt that 1976 deserved even more attention since it was to be also the 25th, the Silver Anniversary, of the Division of Polymer Chemis try. This year would be a most appropriate one not only to review milestones in our discipline, but also to look to the future. It was decided to undertake this volume and Dr. R. D. Ulrich agreed to serve as editor in assembling the collected papers. It is the hope of the officers of the Division that this volume will serve many purposes - a reference text, a record, and a source of perspective. F. E. Bailey Chairman (1976) Division of Polymer Chemistry American Chemical Society vii Contents R. D. Ulrich - The History of the ACS Division 1 of Polymer Chemistry, Inc. Bovey F. A. 31 F. R. Eirich 53 J. D. Ferry 63 P. J. Flory 69 Huggins M. L. 99 L. Mandelkern 113 123 H. F. Mark • C. S. Marvel 133 B. Maxwell 143 .
Elementary radical reactions are described in terms of fundamental knowledge of organic chemistry and chemical physics in this valuable reference text. The complex radical processes of nonchain and chain mechanisms, such as dimerization, alkylation, polymerization, telomerization, halogenation pyrolysis, oxidation and combustion, are complemented by reactions in chemical lasers and in the cosmos, as well as by reactions in biological objects under normal or pathological metabolism. The text also provides the synthesis of facts from various fields of research and involves mechanisms where free radicals appear either as main or side intermediates in one of the several alternatives of the reaction pathway. Highlights include 38 tables and 39 figures.