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Fluorine Chemistry, Volume V focuses on the compositions, reactions, properties, and functions of fluorine compounds. The book first discusses the general chemistry of fluorine compounds and the physical chemistry of fluorocarbons. Vapor pressures; details of interaction of polyatomic molecules; coefficients and equations of state for gases; liquid compressibility; and compressibilities of liquid mixtures are discussed. The text looks at the radiochemistry and radiation chemistry of fluorine. Isotopes of fluorine; useful methods for producing F18 and F20; radiochemical properties and counting of F20; fluorine activities in nuclear reactors; and analytical determinations are described. The selection also provides numerical analysis and tabulated representations. The book also focuses on the industrial and utilitarian features of fluorine chemistry. Historical and economic factors; properties of fluorocarbons; refrigerants and propellants; gaseous dielectrics; fire extinguishing agents; and fluorocarbon surfactants are discussed. The text is a vital source of data for readers wanting to study fluorine compounds.
Fluorine Chemistry, Volume II focuses on studies on fluorocarbons and fluorocarbon derivatives. Composed of various literature, the book first discusses fluorine-containing complex salts and acids. The complex fluorides of alkali metals, beryllium, boron, carbon, silicon, germanium, tin, and lead are described. The text also looks at research on halogen fluorides. The physical properties of chlorine, bromine, and iodine fluorides; halogen fluorides as ionizing solvents; and acids and bases in iodine pentafluoride and chlorine trifluoride are discussed. The book discusses analytical chemistry of fluorine and fluorine-containing compounds. Analysis of gaseous samples; separation and isolation of fluorine; qualitative detection and identification of fluorine; and determination of fluorine in specific materials are described. The text also focuses on organic compounds containing fluorine. Alcohols, acids and their derivatives, polymer containing fluorines, amines, amino acids, drugs, dyes, and pesticides are discussed as well. The book further looks at metallic compounds containing fluorocarbon radicals and organometallic compounds containing fluorine, fluorocarbon chemistry, and the infrared spectra of fluorocarbons and related compounds. The text is a vital source of information for readers wanting to study fluorocarbons and fluorocarbon derivatives.
Fluorine Chemistry, Volume IV provides an extensive survey and discussion on the physiological properties of fluoride ion and substances capable of producing it in aqueous solution. This book elaborates the detrimental effects of excessive fluoride ingestion, through the beneficial effects of optimal amounts, to recognized detrimental effects, such as dental caries accompanied by suboptimal fluoride intake. Fluoride metabolism is discussed in detail, including the capacity for storage of fluoride by the bones and rates of excretion of fluoride from the body. This text also covers the relation of fluoride ion to the health of teeth and bones. This publication is a good source for chemists and clinicians intending to acquire knowledge of the biological effects of fluoride.
The Chemistry of Fluorine and Its Compounds is an expanded and updated treatment of the material presented in a series of five lectures given by Professor Emeleus while in residence at the Polytechnic Institute of Brooklyn in November and December, 1966. This book is one of a series of monographs made possible by a Science Center Development Grant from the National Science Foundation that enabled the Institute's Department of Chemistry to establish a Distinguished Visiting Lectureship that is held successively by a number of eminent chemists, each of whom has played a leading part in the development of some important area of chemical research. The book opens with an introductory chapter on the chemistry of fluorine. This is followed by separate chapters on halogen fluorides, oxygen fluorides, hypofluorites, fluorides of Group III, carbon fluorides; and perfluoro organometallic compounds fluorides of silicon, germanium, tin, and lead. Subsequent chapters deal with fluorides of nitrogen and related compounds; fluorides of phosphorus, arsenic, antimony, and bismuth; and fluorides of sulfur, selenium, and tellurium.
This book deals with selected aspects of structural chemistry, concentrating particularly on molecular and Raman spectroscopy. The authors of the various chapters were chosen from friends, colleagues and past students of Len Woodward. It is our hope that the book will prove useful both to honours students and to research workers. We would like to thank all our contributors for their willing cooperation in this endeavour. We are also grateful to all those who have given permission for the reproduction of copyright material from other publica tions; specific acknowledgments are made in each chapter. We are par ticularly indebted to the Principal and Fellows of Jesus College, Oxford, and the artist, H. A. Freeth, R.A., for permission to reproduce the portrait of Len Woodward which forms the frontispiece. Our thanks are also due to Mrs. J. Stevenson, who undertook a great deal of the secretarial work associated with the organization of this volume, and to Mr. P. Espe who photographed the portrait. The royalties from the sale of this book will, in the first instance, go to Jesus College, Oxford, and will be used for the establishment of a prize to be associated with Len Woodward's name.