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The use of plastic materials has seen a massive increase in recent years, and generation of plastic wastes has grown proportionately. Recycling of these wastes to reduce landfill disposal is problematic due to the wide variation in properties and chemical composition among the different types of plastics. Feedstock recycling is one of the alternatives available for consideration, and Feedstock Recycling of Plastic Wastes looks at the conversion of plastic wastes into valuable chemicals useful as fuels or raw materials. Looking at both scientific and technical aspects of the recycling developments, this book describes the alternatives available. Areas include chemical depolymerization, thermal processes, oxidation and hydrogenation. Besides conventional treatments, new technological approaches for the degradation of plastics, such as conversion under supercritical conditions and coprocessing with coal are discussed. This book is essential reading for those involved in plastic recycling, whether from an academic or industrial perspective. Consultants and government agencies will also find it immensely useful.
Pyrolysis is a recycling technique converting plastic waste into fuels, monomers, or other valuable materials by thermal and catalytic cracking processes. It allows the treatment of mixed, unwashed plastic wastes. For many years research has been carried out on thermally converting waste plastics into useful hydrocarbons liquids such as crude oil and diesel fuel. Recently the technology has matured to the point where commercial plants are now available. Pyrolysis recycling of mixed waste plastics into generator and transportation fuels is seen as the answer for recovering value from unwashed, mixed plastics and achieving their desired diversion from landfill. This book provides an overview of the science and technology of pyrolysis of waste plastics. It describes the types of plastics that are suitable for pyrolysis recycling, the mechanism of pyrolytic degradation of various plastics, characterization of the pyrolysis products and details of commercially mature pyrolysis technologies. This book also covers co-pyrolysis technology, including: waste plastic/waste oil, waste plastics/coal, and waste plastics/rubber.
Provides an overview of the family of polyester polymers which comprise an important group of plastics that span the range of commodity polymers to engineering resins. It describes the preparation, properties and applications of polyesters. Readers will also find details on polyester-based elastomers, biodegradable aliphatic polyester, liquid crystal polyesters and unsaturated polyesters for glass-reinforced composites. Presents an overview of the most recent developments. Explores synthesis, catalysts, processes, properties and applications. Looks at emerging polyester materials as well as existing ones. Written by foremost experts from both academia and industry, ensuring that both fundamentals and practical applications are covered.
This book describes how man-made litter, primarily plastic, has spread into the remotest parts of the oceans and covers all aspects of this pollution problem from the impacts on wildlife and human health to socio-economic and political issues. Marine litter is a prime threat to marine wildlife, habitats and food webs worldwide. The book illustrates how advanced technologies from deep-sea research, microbiology and mathematic modelling as well as classic beach litter counts by volunteers contributed to the broad awareness of marine litter as a problem of global significance. The authors summarise more than five decades of marine litter research, which receives growing attention after the recent discovery of great oceanic garbage patches and the ubiquity of microscopic plastic particles in marine organisms and habitats. In 16 chapters, authors from all over the world have created a universal view on the diverse field of marine litter pollution, the biological impacts, dedicated research activities, and the various national and international legislative efforts to combat this environmental problem. They recommend future research directions necessary for a comprehensive understanding of this environmental issue and the development of efficient management strategies. This book addresses scientists, and it provides a solid knowledge base for policy makers, NGOs, and the broader public.
In chemical processes, the progressive deactivation of solid catalysts is a major economic concern and mastering their stability has become as essential as controlling their activity and selectivity. For these reasons, there is a strong motivation to understand the mechanisms leading to any loss in activity and/or selectivity and to find out the efficient preventive measures and regenerative solutions that open the way towards cheaper and cleaner processes. This book covers in a comprehensive way both the fundamental and applied aspects of solid catalyst deactivation and encompasses the state-of-the-art in the field of reactions catalyzed by zeolites. This particular choice is justified by the widespread use of molecular sieves in refining, petrochemicals and organic chemicals synthesis processes, by the large variety in the nature of their active sites (acid, base, acid-base, redox, bifunctional) and especially by their peculiar features, in terms of crystallinity, structural order and textural properties, which make them ideal models for heterogeneous catalysis. The aim of this book is to be a critical review in the field of zeolite deactivation and regeneration, by collecting a series of contributions by experts in the field which describe the factors, explain the techniques to study the causes and suggest methods to prevent (or limit) catalyst deactivation. At the same time, an anthology of commercial processes and exemplar cases provides the reader with theoretical insights and practical hints on the deactivation mechanisms and draws attention to the key role played by the loss of activity on process design and industrial practice.
This book provides a systematic and comprehensive account of the recent developments in the recycling of plastic waste material. It presents state-of-the-art procedures for recycling of plastics from different sources and various characterization methods adopted in analyzing their properties. In addition, it looks into properties, processing, and applications of recycled plastic products as one of the drivers for sustainable recycling plastics especially in developing countries. This book proves a useful reference source for both engineers and researchers working in composite materials science as well as the students attending materials science, physics, chemistry, and engineering courses.
The world is literally awash with plastics and this book practically provides a broad overview of plastic recycling procedures and waste management. With the huge amount of plastics floating in the oceans, fish and other sea creatures are directly suffering the consequences. On land, city leaders and planners are banning one-use plastics as well as plastic bags from grocery stores in an effort to stem the use. Many countries have made official announcements and warnings concerning the pollution caused from plastic wastes. These urgent developments have stimulated the author to study the problem and write Polymer Waste Management. Plastic recycling refers to a method that retrieves the original plastic material. However, there are many sophisticated methods available for the treatment and management of waste plastics such as basic primary recycling, where the materials are sorted and collected individually. In chemical recycling, the monomers and related compounds are processed by special chemical treatments. Other methods, such as pyrolysis, can produce fuels from waste plastics. These methods and others are treated comprehensively in the book. This groundbreaking book also discusses: General aspects, such as amount of plastics production, types of waste plastics, analysis procedures for identification of waste plastic types, standards for waste treatment, contaminants in recycled plastics. Environmental aspects, such as pollution in the marine environment and landfills. The advantages of the use of bio-based plastics. Recycling methods for individual plastic types and special catalysts.
Chemistry and Material Sciences naturally depend greatly on Synthesis as the initial stage for the existence of compounds and materials with desired behaviors, within the overall streamline of Design/Synthesis — Properties — Application/Function, and their relations. Such a general approach is of a too wide scope to be properly treated in a single set of publications, but this one on 'Synthesis and Applications in Chemistry and Materials' restricts itself by aiming to show the strength and international character of the current research in synthetic chemistry that is being developed in Portugal or abroad by teams that cooperate with this country. Hence, it gathers representative contributions of main Portuguese research groups and foreign collaborating ones. Nevertheless, the topic should be understood in a wide sense, being open to types of studies with significance on sustainable synthesis and applications in chemistry, materials and/or related sciences.
Polymers, main components of plastics and rubbers, are being discarded in increasing quantities. But this waste can also be considered as `plastic gold'. Public concern, coupled with the inherent value of the material, means that recycling is imperative. The present book presents a survey of current knowledge in the form of case studies, including current legal and educational issues. Topics covered also include regulation and practice in NATO countries, the economics of recycling, the reprocessing of single polymers and mixtures, and future prospects and strategies. Audience: Vital reading for all polymer scientists, technicians and engineers.