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Microbiologically influenced corrosion (MIC) is a difficult degradation mechanism to diagnose in pipeline systems due to the complex interaction between biotic (i.e., microbial) and abiotic (e.g., fluid chemistry, pipe/vessel metallurgy/corrosion, and operating conditions) factors. This complexity often makes it difficult to accurately assess pipeline failures due to MIC. However, even with available data, failure investigators often face a number of challenges in diagnosing MIC such as how to properly integrate the available datasets, questions regarding data accuracy (e.g., confidence in the sampling and/or analysis method used) and lack of available information from operators (e.g., missing data). As a result, practical MIC failure assessments are most often performed by experts or specialists with significant knowledge and working experience in this topic. Based on these issues, the objectives of this thesis are three-fold: 1) to quantify the actual prevalence of MIC related pipeline failures in Alberta's oil and gas sector, 2) to perform a gap analysis of failure investigation methods used to assess these pipeline failures, and 3) to develop a novel expert system based on machine learning to assist both experts and non-experts in assessing potential MIC related pipeline failures. The first part of this study highlights a review and analysis of MIC related pipeline incidents in the province of Alberta, Canada over a three-year period (2017-2019). This review was used to quantify the occurrence of MIC failures relative to other corrosion mechanisms, and to conduct a gap analysis of MIC failure investigation techniques being used relative to the current state of the art. Over this three-year period, MIC was found to be responsible for 13.6% and 4.8% of all pipeline leak incidents due to internal and external corrosion, respectively (either as the main failure mechanism or as a contributing factor). Most of these failures were seen to occur in small diameter upstream pipelines (with less than or equal to 220.3 mm outside diameter) carrying mainly multiphase fluids (oil-water emulsions) or produced water. In terms of the failure investigation methods currently being used, it was noted that there was some inconsistency among reports and a number of important gaps were identified. Various assessments lacked microbiological test data, in particular, tests which specifically identify microbial functional groups or speciation, which is critical to confirm observed corrosion mechanisms. Furthermore, a number of these assessments identified MIC primarily on the basis of corrosion morphology, which has been shown to be an incorrect assumption and approach without additional evidence. Details related to sampling methods were also lacking in these assessments, which created some uncertainty as to the quality of data obtained. Overall, most assessments did a reasonable job in characterizing and including chemical (solids, fluids, and corrosion products), metallurgical/ corrosion, and operating data. However, the integration of these various layers of evidence (i.e., connecting corrosion to microbiological activity, and eliminating possible abiotic corrosion mechanisms) was missing in many reports. The second part of this study highlights the modeling of an expert system for the classification of internal microbiologically influenced corrosion (MIC) failures related to pipelines in the upstream oil and gas industry. The model is based on machine learning (artificial neural network) and involves the participation of 15 MIC subject matter experts (SMEs). Each expert evaluated a number of model case studies representative of both MIC and non-MIC related upstream pipeline failures. The model accounts for variations in microbiological testing methods, microbiological sample types, degradation morphology, among others, and also incorporates cases with select missing datasets which is commonly found in actual failure assessments. The output classifications comprised elements of both potential for MIC and confidence in the data available. The results were contrasted for 5- and 3-output classification models (5OC and 3OC, respectively). The 5OC model had an overall accuracy of 62.0% while the simpler 3OC model had a better accuracy of 74.8%. This modelling exercise has demonstrated that knowledge from subject matter experts can be captured in a reasonably effective model to screen for possible MIC failures. It is hoped that this study contributes to a better understanding of the prevalence of MIC in the oil and gas sector, and highlights the key areas necessary to improve the diagnosis of MIC failures in the future.
Failure Analysis of Microbiologically Influenced Corrosion serves as a complete guide to corrosion failure analysis with an emphasis on the diagnosis of microbiologically influenced corrosion (MIC). By applying the principles of chemistry, microbiology, and metallurgy, readers will be able to reliably determine the mechanistic cause of corrosion damage and failures and select the appropriate methods for mitigating future corrosion incidents. FEATURES Provides background information on the forensic process, types of data or evidence needed to perform the analysis, industrial case studies, details on the MIC failure analysis process, and protocols for field and lab use Presents up-to-date advances in molecular technologies and their application to corrosion failure investigations Offers specific guidelines for conducting MIC failure analyses and case studies to illustrate their application Examines state-of-the-art information on MIC analytical tools and methods With authors with expertise in microbiology, corrosion, materials, and failure investigation, this book provides tools for engineers, scientists, and technologists to successfully combat MIC issues.
A multi-disciplinary, multi-industry overview of microbiologically influenced corrosion, with strategies for diagnosis and control or prevention Microbiologically Influenced Corrosion helps engineers and scientists understand and combat the costly failures that occur due to microbiologically influenced corrosion (MIC). This book combines recent findings from diverse disciplines into one comprehensive reference. Complete with case histories from a variety of environments, it covers: Biofilm formation Causative organisms, relating bacteria and fungi to corrosion mechanisms for groups of metals Diagnosing and monitoring MIC Electrochemical techniques, with an overview of methods for detection of MIC The impact of alloying elements, including antimicrobial metals, and design features on MIC MIC of non-metallics Strategies for control or prevention of MIC, including engineering, chemical, and biological approaches This is a valuable, all-inclusive reference for corrosion scientists, engineers, and researchers, as well as designers, managers, and operators.
Microorganisms are ubiquitously present in petroleum reservoirs and the facilities that produce them. Pipelines, vessels, and other equipment used in upstream oil and gas operations provide a vast and predominantly anoxic environment for microorganisms to thrive. The biggest technical challenge resulting from microbial activity in these engineered environments is the impact on materials integrity. Oilfield microorganisms can affect materials integrity profoundly through a multitude of elusive (bio)chemical mechanisms, collectively referred to as microbiologically influenced corrosion (MIC). MIC is estimated to account for 20 to 30% of all corrosion-related costs in the oil and gas industry. This book is intended as a comprehensive reference for integrity engineers, production chemists, oilfield microbiologists, and scientists working in the field of petroleum microbiology or corrosion. Exhaustively researched by leaders from both industry and academia, this book discusses the latest technological and scientific advances as well as relevant case studies to convey to readers an understanding of MIC and its effective management.
Significantly extended from the first edition, this book presents the basics of microbiologically influenced corrosion (MIC) in an accessible and concise manner. It explores strategies for recognizing, understanding, mitigating and preventing this type of corrosion, and investigates this topic from the point of view of an engineer. Chapters cover issues including stress corrosion cracking and microbial corrosion, the pros and cons of biocides, the involvement of magnetic bacteria in microbial corrosion, and cathodic protection based on recent research in microbial environments. The 2nd Edition provides new material examining the following topics: *The corrosion-related bacteria clostridia *Mathematical modelling of MIC, in particular fuzzy logic *A comparison of culture-independent methods with culture-dependent methods *Further practical strategies for dealing with MIC *Natural biocidesThis book has provided course material for the author’s microbial corrosion workshops around the world, and it presents an invaluable resource to corrosion and integrity professionals working in a wide range of industries including power generation, oil and gas, marine, and mining. It is also intended for students and academics of corrosion engineering, materials science, microbiology, chemical engineering and welding.
Hydrostatic Testing, Corrosion, and Microbiologically Influenced Corrosion: A Field Manual for Control and Prevention teaches industry professionals, managers, and researchers how to combat corrosion failure associated with hydrotesting. It discusses how a test liquid must be selected, how corrosion by bacteria should be controlled, and how to eliminate the risk of leakage. Rather than teaching how hydrotests should be conducted, it helps the reader evaluate the quality of a hydrotest that’s already been conducted in terms of oxygen scavenger use, biocide testing, inhibitor addition, and water quality and explains the tasks that top and middle management must ensure are taken with respect to corrosion assessment of hydrotesting. The manual also discusses microbiologically influenced corrosion (MIC) as the main corrosion mechanism related to post-hydrotesting and offers essential knowledge on combating this corrosion process. In addition to being a manual for top and middle management on how to deal with corrosion, this book also:
Failure Modes, Effects and Causes of Microbiologically Influenced Corrosion: Advanced Perspectives and Analysis presents academic research about microbial corrosion (MIC), integrating it into engineering applications that result in a more thorough understanding of MIC and how it is recognized and treated. In addition, new concepts that will be useful in understanding integrity and corrosion management practices are explored. This book will be useful for industry professionals, particularly maintenance and operation engineers, corrosion and material engineers, and R&D personnel working in the field of corrosion protection. Focuses on the skills and knowledge necessary to understand how (Failure modes) and why (Effects and Causes) materials fail Explains why corrosion control measures, such as the use of coatings, cathodic protection and inhibitors are useful Discusses the practical side of MIC treatment in terms of fundamental concepts of time and cost of operation