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A brand-new conceptual look at dynamical thermodynamics This book merges the two universalisms of thermodynamics and dynamical systems theory in a single compendium, with the latter providing an ideal language for the former, to develop a new and unique framework for dynamical thermodynamics. In particular, the book uses system-theoretic ideas to bring coherence, clarity, and precision to an important and poorly understood classical area of science. The dynamical systems formalism captures all of the key aspects of thermodynamics, including its fundamental laws, while providing a mathematically rigorous formulation for thermodynamical systems out of equilibrium by unifying the theory of mechanics with that of classical thermodynamics. This book includes topics on nonequilibrium irreversible thermodynamics, Boltzmann thermodynamics, mass-action kinetics and chemical reactions, finite-time thermodynamics, thermodynamic critical phenomena with continuous and discontinuous phase transitions, information theory, continuum and stochastic thermodynamics, and relativistic thermodynamics. A Dynamical Systems Theory of Thermodynamics develops a postmodern theory of thermodynamics as part of mathematical dynamical systems theory. The book establishes a clear nexus between thermodynamic irreversibility, the second law of thermodynamics, and the arrow of time to further unify discreteness and continuity, indeterminism and determinism, and quantum mechanics and general relativity in the pursuit of understanding the most fundamental property of the universe—the entropic arrow of time.
Originally conceived some thirty years ago in the context ofquantum electrodynamics, renormalization methods have progressivelydeveloped into an indispensable analytical tool used in widelyvarying domains of physics and applied mathematics, such as * phase transitions and critical phenomena * dynamical systems and chaos * developed turbulence * fractal structures and complex systems * percolation * polymer physics * diffusion in disordered media * measure theory and stochastic processes. By explaining the fundamental principles of renormalization theorysuch as scale invariance and universality which lie behind all thetechnical variations, this book aims to guide the reader to a moreunified understanding of today s physics. The book is based on avery accessible main text, supplemented by several more specializedsections; it is intended for graduate students and for researcherswho are seeking an introduction to a new area of electrodynamics ora general overview of the physical phenomena to whichrenormalization methods are applied.
Thermodynamic Approaches in Engineering Systems responds to the need for a synthesizing volume that throws light upon the extensive field of thermodynamics from a chemical engineering perspective that applies basic ideas and key results from the field to chemical engineering problems. This book outlines and interprets the most valuable achievements in applied non-equilibrium thermodynamics obtained within the recent fifty years. It synthesizes nontrivial achievements of thermodynamics in important branches of chemical and biochemical engineering. Readers will gain an update on what has been achieved, what new research problems could be stated, and what kind of further studies should be developed within specialized research. - Presents clearly structured chapters beginning with an introduction, elaboration of the process, and results summarized in a conclusion - Written by a first-class expert in the field of advanced methods in thermodynamics - Provides a synthesis of recent thermodynamic developments in practical systems - Presents very elaborate literature discussions from the past fifty years
A self-contained, mathematical introduction to the driving ideas in equilibrium statistical mechanics, studying important models in detail.
International Series of Monographs in Natural Philosophy, Volume 22: Foundations of Statistical Mechanics: A Deductive Treatment presents the main approaches to the basic problems of statistical mechanics. This book examines the theory that provides explicit recognition to the limitations on one's powers of observation. Organized into six chapters, this volume begins with an overview of the main physical assumptions and their idealization in the form of postulates. This text then examines the consequences of these postulates that culminate in a derivation of the fundamental formula for calculating probabilities in terms of dynamic quantities. Other chapters provide a careful analysis of the significant notion of entropy, which shows the links between thermodynamics and statistical mechanics and also between communication theory and statistical mechanics. The final chapter deals with the thermodynamic concept of entropy. This book is intended to be suitable for students of theoretical physics. Probability theorists, statisticians, and philosophers will also find this book useful.
This series provides the chemical physics field with a forum for critical, authoritative evaluations of advances in every area of the discipline. This stand-alone special topics volume reports recent advances in electron-transfer research with significant, up-to-date chapters by internationally recognized researchers.
Robert Batterman examines a form of scientific reasoning called asymptotic reasoning, arguing that it has important consequences for our understanding of the scientific process as a whole. He maintains that asymptotic reasoning is essential for explaining what physicists call universal behavior. With clarity and rigor, he simplifies complex questions about universal behavior, demonstrating a profound understanding of the underlying structures that ground them. This book introduces a valuable new method that is certain to fill explanatory gaps across disciplines.
This book analyzes in considerable generality the quantization-dequantization integral transform scheme of Weyl and Wigner, and considers several phase operator theories. It features: a thorough treatment of quantization in polar coordinates; dequantization by a new method of “motes”; a discussion of Moyal algebras; modifications of the transform method to accommodate operator orderings; a rigorous discussion of the Dicke laser model for one mode, fully quantum, in the thermodynamic limit; analysis of quantum phase theories based on the Toeplitz operator, the coherent state operator, the quantized phase space angle, and a sequence of finite rank operators.
Reissued in the Cambridge Mathematical Library this classic book outlines the theory of thermodynamic formalism which was developed to describe the properties of certain physical systems consisting of a large number of subunits. It is aimed at mathematicians interested in ergodic theory, topological dynamics, constructive quantum field theory, the study of certain differentiable dynamical systems, notably Anosov diffeomorphisms and flows. It is also of interest to theoretical physicists concerned with the conceptual basis of equilibrium statistical mechanics. The level of the presentation is generally advanced, the objective being to provide an efficient research tool and a text for use in graduate teaching. Background material on mathematics has been collected in appendices to help the reader. Extra material is given in the form of updates of problems that were open at the original time of writing and as a new preface specially written for this new edition by the author.
This book is devoted to the application of fractional calculus in economics to describe processes with memory and non-locality. Fractional calculus is a branch of mathematics that studies the properties of differential and integral operators that are characterized by real or complex orders. Fractional calculus methods are powerful tools for describing the processes and systems with memory and nonlocality. Recently, fractional integro-differential equations have been used to describe a wide class of economical processes with power law memory and spatial nonlocality. Generalizations of basic economic concepts and notions the economic processes with memory were proposed. New mathematical models with continuous time are proposed to describe economic dynamics with long memory. This book is a collection of articles reflecting the latest mathematical and conceptual developments in mathematical economics with memory and non-locality based on applications of fractional calculus.