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A survey of elementary processes and mechanisms, presenting useful and relatively simple methods of approximation for calculating the effective cross sections, giving a number of approximate formulas. Extensive tables list cross sections and rate coefficients for various atoms and elementary processes. For this second edition several sections and formulas have been substantially revised, the tables recalculated using the updated version of ATOM and recent progress in the field has been added.
A survey of elementary processes and mechanisms, presenting useful and relatively simple methods of approximation for calculating the effective cross sections, giving a number of approximate formulas. Extensive tables list cross sections and rate coefficients for various atoms and elementary processes. For this second edition several sections and formulas have been substantially revised, the tables recalculated using the updated version of ATOM and recent progress in the field has been added.
New applications of atomic spectroscopy in laser physics, laser spectrosco py, laser frequency and wavelength measurements, plasma physics, astrophysics, and some other related problems have been developed very intensively in the last years. As a result, the approximate methods of calculation of the transition probabilities and cross sections necessary for all these applications have become of vastly increased importance. At the same time, some new problems have arisen in the theory of spectral line broadening such as the shape of nonlinear resonances in the spectra of gas lasers, interference effects, and some other problems connected with various spectroscopic methods of plasma diagnostics. This book is devoted to the systematic treatment of the theory of the elementary processes responsible for the excitation of atomic spectra and the theory of spectral line broadening. The choice of problems is significantly different from that traditional for books on the theory of atomic collisions. The main goal of the book is to present the most efficient and useful of comparatively simple approximate methods for the calcula tion and estimation of cross sections. Numerous tables containing the results of approximate cross section calculations for the most important elementary processes are included in the book. Comprehensive presenta tion of the theory of atomic collisions is out of the scope of this book and can be found elsewhere. However, the fundamentals of the general theory of collisions which are necessary for formulation of approximate methods are given in Chapter 2.
Introduction to the Theory of Atomic Spectra is a systematic presentation of the theory of atomic spectra based on the modern system of the theory of angular momentum. Many questions which are of interest from the point of view of using spectroscopic methods for investigating various physical phenomena, including continuous spectrum radiation, excitation of atoms, and spectral line broadening, are discussed. This volume consists of 11 chapters organized into three sections. After a summary of elementary information on atomic spectra, including the hydrogen spectrum and the spectra of multi-electron atoms, the reader is methodically introduced to angular momentum, systematics of the levels of multi-electron atoms, and hyperfine structure of spectral lines. Relativistic corrections are also given consideration, with particular reference to the use of the Dirac equation to determine the stationary states of an electron in an arbitrary electromagnetic field. In addition, the book explores the Stark effect and the Zeeman effect, the interaction between atoms and an electromagnetic field, and broadening of spectral lines. The final chapter is devoted to the problem of atomic excitation by collisions. This book is intended for advanced-course university students, postgraduate students and scientists working on spectroscopy and spectral analysis, and also in the field of theoretical physics.
The broadest source of information on analytical ICP spectrometry available in a coherent, single volume. Renowned contributors define theory, diagnostics, models, instrumentation and applications. They also discuss atomic emission, atomic fluorescence and mass spectrometries based on ICP sources for atomization, excitation and ionization. 'This book is HIGHLY RECOMMENDED.' Analytical Chemistry '... a handy reference for anyone attempting to understand the theory of ICPs and how they work. The detailed discussions of the various types of instrumentation and methods will be quite helpful to students and researchers in the field who want to broaden their understanding of analytical atomic spectroscopy.' Applied Spectroscopy '...Everyone involved in elemental analysis using ICP should have this book. It is useful for both experienced and novice ICP spectroscopists.' Spectroscopy
There have been two major review articles on the iodine laser in the last ll seven years, liThe Photochemical Iodine Laser by K. Hohla and K. Kompa (Handbook of Chemical Lasers, edited by R. Gross and J. Bott, Wi 1 ey, New York,1976) and a SANDIA report (No. 78-1071, 1978) entitled liThe Atomic Iodine Laserll. Since then, a large body of new material has been published, and practical experience has been gained with large iodine laser systems in Garchi ng (ASTERIX II I) and in the USSR. These 1 asers have now become very reliable tools, especially in fusion-oriented plasma experiments, which represent their main field of application. They can deliver powers in excess of many terawatts per beam and are thus also suited for use in other areas such as X-ray lasers, incoherent X-ray sources, compression of matter and its behaviour at very high densities. The physics of the iodine laser is now rather well understood, and its technology has reached a standard adequate for the construction of large scale systems in the multi-hundred kJ range. In view of this new situation, we thought it useful to document the present state of the art ina book. Its contents and the literature cited therein have been chosen to cover those areas which are of main concern in the design and operation of pulsed high-power iodine lasers.
The purpose of this book is to discuss certain aspects of the theory of the formation and analysis of the line spectrum of a hot gas. The underlying motivation for most of the studies discussed here lies in a desire to develop a physically sound procedure for interpreting the line spectrum of a stellar atmosphere ; correspondingly, the major emphasis is given to problems encountered in astrophysics.
This book describes selected problems in contemporary spectroscopy in the context of quantum mechanics and statistical physics. It focuses on elementary radiative processes involving atomic particles (atoms, molecules, ions), which include radiative transitions between discrete atomic states, the photoionization of atoms, photorecombination of electrons and ions, bremsstrahlung, photodissociation of molecules, and photoattachment of electrons to atoms. In addition to these processes, the transport of resonant radiation in atomic gases and propagation of infrared radiation in molecular gases are also considered. The book subsequently addresses applied problems such as optical pumping, cooling of gases via laser resonance radiation, light-induced drift of gas atoms, photoresonant plasma, reflection of radio waves from the ionosphere, and detection of submillimeter radiation using Rydberg atoms. Lastly, topical examples in atmospheric and climate change science are presented, such as lightning channel glowing, emission of the solar photosphere, and the greenhouse phenomenon in the atmospheres of the Earth and Venus. Along with researchers, both graduate and undergraduate students in atomic, molecular and atmospheric physics will find this book a useful and timely guide.