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Rodd’s Chemistry of Carbon Compounds, Second Edition, Volume 1: Aliphatic Compounds, Part B: Monohydric Alcohols, their Ethers and Esters, Sulphur Analogues, Nitrogen Derivatives, Organometallic Compounds describes the classification and nomenclature of singly-linked, mono-substituted, aliphatic hydrocarbons. This volume is composed of four chapters, and begins with a discussion on the nomenclature, preparations, and analysis halogeno- and nitro-alkanols. These topics are followed by the classification, nomenclature, preparation, and reactions of other aliphatic compound derivatives, including nitrogen derivatives and sulfur analogues. The concluding chapter focuses on the chemistry of aliphatic organometallic and organometalloidal compounds. Organic chemists and researchers will find this book invaluable.
Crown Ethers and Cryptands introduces the broad and basic principles of crown ether and cryptand chemistry at the advanced undergraduate, graduate and working professional level. The book provides a brief introduction, outlining the history of the field and goes on to cover syntheses, complexation of cations and molecules, complex structures, applications and recent developments. It aims to acquaint readers with the scope and principles of the field, providing a bibliography of reviews and books as reference to further reading and citations of the original literature.
Ethers—Advances in Research and Application: 2013 Edition is a ScholarlyBrief™ that delivers timely, authoritative, comprehensive, and specialized information about Cyclic Ethers in a concise format. The editors have built Ethers—Advances in Research and Application: 2013 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Cyclic Ethers in this book to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Ethers—Advances in Research and Application: 2013 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.
Since the discovery of crown ethers by Pedersen in 1967, several thousands of crown ethers and analogous compounds have been synthesized. Their specific characteristics have been investigated and a variety of applications developed. These developments have led to new fields of chemistry called host-guest chemistry and supramolecular chemistry. This book presents the state-of-the-art of the chemistry of crown ethers and analogous compounds. The first chapter provides an orientation in the new fields of chemistry. Chapter 2 reviews advances in synthetic procedures for crown ethers and analogous compounds including azacrown ethers, thiacrown ethers, functionalized crown ethers, cryptands and others. The focus of chapter 3 is on the concept and synthetic strategies for the molecular design of new crown compounds. Chapters 4-7 are concerned with noteworthy topics in the applications of crown compounds. Chapter 4 deals with the application to ion-selective electrodes and liquid chromatography, both of which are the most important targets in the analytical application of crown compounds. One major application of crown ethers is the design and syntheses of artificial molecules which can catalyze a useful synthetic reaction in an enzyme-mimetic reaction manner, through novel non-covalent complexes. The strategies for enzymatic modelling with crown ethers are covered in chapter 5, while chapter 6 presents the principle of amine-selective colour complexation and its application. In chapter 7 switched-on crown ethers that can respond to environmental stimuli are reviewed. The final chapter is devoted to a wide-ranging discussion of developments in macrocyclic polyamine chemistry. Unlike crown ethers, macrocyclic polyamines, bearing nitrogen donor atoms which belong to a soft base, form complexes with ions of transition metals and heavy metals which are classified as soft acids. Therefore, macrocyclic polyamines are expected to have very versatile applications. Scientists in chemistry, biochemistry, physical organic chemistry, pharmaceutical chemistry and industrial chemistry will find this book a helpful summary and a stimulating contribution to research in this specialized field of crown compounds.
The spectra from 15 to 35 microns of 45 ketones, 30 ethers and 12 alcohols were analyzed and correlated. For identification purposes the data in this spectral region were shown to be useful as a supplement to data obtained in the 2-15 micron region. The spectra of ketones in the 15-35 micron region are very informative of their detailed structural features, and distinguish between aliphatic methyl ketones with and without alpha branching, aromatic methyl ketones and cyclic ketones. Tentatively, the ring size of cyclic ketones may also be determined. Study of these spectra indicates that the previous assignment of acetone is in error and a new assignment is proposed. The spectra of ethers and alcohols in the 15-35 micron region are less informative. Aliphatic ethers possess one fair group frequency, at 1/480-1/520 cm. The broad absorption by alcohols 1/650 cm was confirmed. (Author).
Cyclic Ethers: Advances in Research and Application: 2011 Edition is a ScholarlyBrief™ that delivers timely, authoritative, comprehensive, and specialized information about Cyclic Ethers in a concise format. The editors have built Cyclic Ethers: Advances in Research and Application: 2011 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Cyclic Ethers in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Cyclic Ethers: Advances in Research and Application: 2011 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.
Ether Lipids: Biochemical and Biomedical Aspects is a 21-chapter text that explores the procedures for the analysis, synthesis, and biomedical application of ether lipids. This book surveys first the chromatographic analysis of ether lipids and their characterization by mass spectrometry. The following chapter describes the chemical synthesis of lipids containing alkyl or 1-alkenyl chains. Three chapters are devoted to the biosynthesis of ether lipids, and four others cover unusual ether lipids. Significant chapters focus on biologically active ether lipids, including the naturally occurring platelet-activating factor and synthetic alkyl analogs of lysophosphatidylcholines, which exhibit cancerostatic properties. This text further discusses the application of these and related substances in biomedical research as well as in clinical diagnosis and therapy. The remaining chapters highlight the use of ether lipids in studies aimed at elucidating the structure of membranes and their functions. Organic chemists, biochemists, and researchers in the biomedical field will find this book invaluable.
Over the years, the uses and applications of various non-conventional solvents such as ionic liquids, deep eutectic solvents, crown ethers, fluorinated solvents, glycols, glycerol etc diversified in various fields. This book consists of nine chapters, which present recent advances and outlook on various non-conventional solvents in organic transformations. Comparison between traditional solvents and non-conventional solvents are also highlighted in this book.