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This book represents a revision and expansion of an earlier set of diagrams for tempera 0 0 tures from 25 to 300 C along the equilibrium vapor-liquid curve for H 0 (Helgeson, Brown, 2 and Leeper, 1969). The activity diagrams summarized in the following pages were generated over a six year period from 1977 to 1983 in the Laboratory of Theoretical Geochemistry (oth erwise known as Prediction Centra!) at the University of California, Berkeley. They represent the culmination of research efforts to generate a comprehensive and internally consistent set of thermodynamic data and equations for minerals, gases, and aqueous solutions at high pres sures and temperatures. Among the many who contributed to the successful completion of this book, we are especially indebted to David Kirkham, John Walther, and George Flowers, who wrote program SUPCRT, Tom Brown, who created program DIAGRAM, and Eli Mess inger, who generated the Tektronix plot routine to construct the diagrams. Ken Jackson and Terri Bowers both devoted an enormous amount of time and effort over the past six years to produce the diagrams in the following pages; some of which went through many stages of revision. Consequently, they appear as senior authors of this volume. It should be mentioned in this regard that their equal dedication to the project made it necessary to determine their order of authorship by flipping a coin.
This book represents a revision and expansion of an earlier set of diagrams for tempera 0 0 tures from 25 to 300 C along the equilibrium vapor-liquid curve for H 0 (Helgeson, Brown, 2 and Leeper, 1969). The activity diagrams summarized in the following pages were generated over a six year period from 1977 to 1983 in the Laboratory of Theoretical Geochemistry (oth erwise known as Prediction Centra!) at the University of California, Berkeley. They represent the culmination of research efforts to generate a comprehensive and internally consistent set of thermodynamic data and equations for minerals, gases, and aqueous solutions at high pres sures and temperatures. Among the many who contributed to the successful completion of this book, we are especially indebted to David Kirkham, John Walther, and George Flowers, who wrote program SUPCRT, Tom Brown, who created program DIAGRAM, and Eli Mess inger, who generated the Tektronix plot routine to construct the diagrams. Ken Jackson and Terri Bowers both devoted an enormous amount of time and effort over the past six years to produce the diagrams in the following pages; some of which went through many stages of revision. Consequently, they appear as senior authors of this volume. It should be mentioned in this regard that their equal dedication to the project made it necessary to determine their order of authorship by flipping a coin.
Traditionally the study of chemical principles as they relate to soil has been limited to the field of agronomics. Soil and Water Chemistry: An Integrative Approach, stands alone because it balances agricultural and environmental perspectives in its analysis of the chemical properties and processes that affect organic and inorganic soil subs
Phase Equilibria in Chemical Engineering is devoted to the thermodynamic basis and practical aspects of the calculation of equilibrium conditions of multiple phases that are pertinent to chemical engineering processes. Efforts have been made throughout the book to provide guidance to adequate theory and practice. The book begins with a long chapter on equations of state, since it is intimately bound up with the development of thermodynamics. Following material on basic thermodynamics and nonidealities in terms of fugacities and activities, individual chapters are devoted to equilibria primarily between pairs of phases. A few topics that do not fit into these categories and for which the state of the art is not yet developed quantitatively have been relegated to a separate chapter. The chapter on chemical equilibria is pertinent since many processes involve simultaneous chemical and phase equilibria. Also included are chapters on the evaluation of enthalpy and entropy changes of nonideal substances and mixtures, and on experimental methods. This book is intended as a reference and self-study as well as a textbook either for full courses in phase equilibria or as a supplement to related courses in the chemical engineering curriculum. Practicing engineers concerned with separation technology and process design also may find the book useful.
Provides comprehensive coverage of the chemical interactions among organic and inorganic solids, air, water, microorganisms, and the plant roots in soil This book focuses on the species and reaction processes of chemicals in soils, with applications to environmental and agricultural issues. Topics range from discussion of fundamental chemical processes to review of properties and reactions of chemicals in the environment. This new edition contains more examples, more illustrations, more details of calculations, and reorganized material within the chapters, including nearly 100 new equations and 51 new figures. Each section also ends with an important concepts overview as well as new questions for readers to answer. Starting with an introduction to the subject, Soil Chemistry, 5th Edition offers in-depth coverage of properties of elements and molecules; characteristics of chemicals in soils; soil water chemistry; redox reactions in soils; mineralogy and weathering processes in soils; and chemistry of soil clays. The book also provides chapters that examine production and chemistry of soil organic matter; surface properties of soil colloids; adsorption processes in soils; measuring and predicting sorption processes in soils; soil acidity; and salt-affected soils. Provides a basic description of important research and fundamental knowledge in the field of soil chemistry Contains more than 200 references provided in figure and table captions and at the end of the chapters Extensively revised with updated figures and tables Soil Chemistry, 5th Edition is an excellent text for senior-level soil chemistry students.
Based on a university course, this book provides an exposition of a large spectrum of geological, geochemical and geophysical problems that are amenable to thermodynamic analysis. It also includes selected problems in planetary sciences, relationships between thermodynamics and microscopic properties, particle size effects, methods of approximation of thermodynamic properties of minerals, and some kinetic ramifications of entropy production. The textbook will enable graduate students and researchers alike to develop an appreciation of the fundamental principles of thermodynamics, and their wide ranging applications to natural processes and systems.