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What happens to a chemical once it enters the natural environment?How do its physical and chemical properties influence itstransport, persistence, and partitioning in the biosphere? How donatural forces influence its distribution? How are the answers tothese questions useful in making toxicological and epidemiologicalforecasts? Environmental Chemodynamics, Second Edition introduces readers tothe concepts, tools, and techniques currently used to answer theseand other critical questions about the fate and transport ofchemicals in the natural environment. Like its critically acclaimedpredecessor, its main focus is on the mechanisms and rates ofmovement of chemicals across the air/soil, soil/water, andwater/air interfaces, and on how natural processes work to mobilizechemicals near and across interfaces--information vital toperforming human and ecological risk assessments. Also consistent with the first edition, EnvironmentalChemodynamics, Second Edition is organized to accommodate readersof every level of experience. The first section is devoted totheoretical underpinnings and includes discussions of mass balance,thermodynamics, transport science concepts, and more. The secondsection concentrates on practical aspects, including the movementbetween bed-sediment and water, movement between soil and air, andintraphase chemical behavior. This revised and updated edition of Louis J. Thibodeaux's 1979classic features new or expanded coverage of: * Equilibrium models for environmental compartments * Dry deposition of particles and vapors onto water and soilsurfaces * Chemical profiles in rivers and estuaries, particles and porousmedia * Fate and transport in the atmospheric boundary layer and withinsubterranean media * Chemical exchange between water column and bed-sediment * Intraphase chemical transport and fate This Second Edition of Environmental Chemodynamics also includestwice as many references and 50% more exercises and practiceproblems.
Partitioning of chemicals in the environment and its modeling is becoming an important field in environmental science and engineering. This book enables students, researchers, and interested laymen to enter the field of environmental modeling in a fast and effective way. The book contains modeling software (CemoS V 1.10), data sets and the CemoS handbook. Each chapter contains examples and exercises.
Reviews existing knowledge in the natural and engineering sciences to determine the rates, lifetimes, routes, and reservoirs of chemicals moving through the environment and to estimate the level of exposure to susceptible living and nonliving targets. Uses simple models and ideas as guides in constructing integrated environmental and ecosystem models for simulating chemical movement and fate. Coverage includes phase equilibrium and transport processes; the interphase and intraphase transport process; movement of inorganic and organic chemicals across the air-water interface; desorption of chemicals from the mud-water interface; volatilization of pesticides from air-soil surfaces; and vertical distribution of dissolved, reactive chemicals in stratified waterbodies. Includes numerous problems from current literature and appendices with chemical, physical, transport, and environmental data.
Given the presence of a wide variety of contaminants in the environment, it is important to understand what drives a contaminant from one medium to another, as well as the manner and extent to which a contaminant associates with the different media or phases within a local environmental system. Partition and Adsorption of Organic Contaminants in Environmental Systems forms a comprehensive resource on the behavioral characteristics of contaminants so that appropriate strategies can be adopted to either prevent or minimize their adverse impacts on human welfare and natural resources. Cary Chiou’s far-reaching text depicts the processes by which nonionic organic contaminants are sorbed to natural biotic and abiotic substances. This book focuses on physical principles and system parameters that affect the contaminant uptake by soil from water, air, and other media; by fish from water; and by plants from soil and water. As contaminant uptake by natural organic substances is often predominantly a partition interaction, the partition characteristics in several solvent-water model mixtures are treated in detail to elucidate the relevant physicochemical parameters. The account of contaminant sorption to soils, fish, and plants is strengthened by companion chapters on: Fundamentals of solution theory Interphase partition equations Fundamentals of adsorption theory Vapor adsorption on mineral and carbonaceous solids No other single source in the field delivers as compelling a combination of background understanding and "state-of-the-science" comprehension of current issues. Ideally suited for a graduate-level environmental course, Partition and Adsorption of Organic Contaminants in Environmental Systems also serves as a technical guide to current and future research in the field.
Based on discussions at the 2007 SETAC Europe PERAS Workshop in Coimbra, Semi-Field Methods for the Environmental Risk Assessment of Pesticides in Soil presents a timely summary of state-of-the-art higher-tier terrestrial risk assessment of plant protection products (PPPs). Influential regulators, academics, and industry scientists provide a compre
Pollution and its control are now one of the most serious problems in environmental management, affecting localized areas, regions, and, increasingly, the entire ecosphere. Chemistry and Ecotoxicology of Pollution provides a basic understanding of the chemical, toxicological, and ecological factors involved when major classes of pollutants act on natural systems. The nature and effects of these pollutants are examined from the primary level of their sources and chemical properties, through their interactions in the environment, to their ultimate ecological effects on organisms and ecosystems. Pollutants are divided into groups, with similar properties, and then the chemistry and ecotoxicology of each group is defined. More importantly, in collating and evaluating available information on pollution processes, the book develops unifying theories on the fundamental chemical and ecological nature of pollution processes. The book uses a conceptual framework to evaluate the impact of pollutants on the components and functions of natural ecosystems. It is based on the chemical and physical properties of a pollutant, its environmental behavior and fate, exposure to and toxic effects on organisms, their populations, communities, and responses of affected ecosystems. This sequence can be applied to known, potential, and emerging pollutants of concern. As government initiatives for the control of chemicals take greater effects, pollution research, particularly in ecotoxicology, will be further developed. Chemistry and Ecotoxicology of Pollution helps play an important role in determining the future direction of research activities in environmental management and pollution control on a worldwide scale. It is a basic resource for students (e.g. environmental chemistry, ecology, land and water management, environmental or public health, environmental engineering, and sustainability science), scientists, researchers, policy makers, and professionals in need of a clear understanding of the nature and effects of environmental pollution from an ecological perspective.
A comprehensive account of the state of the science of environmental mass transport Edited by Louis J. Thibodeaux and Donald Mackay, renowned experts in this field, the Handbook of Chemical Mass Transport in the Environment covers those processes which are critically important for assessing chemical fate, exposure, and risk. In a comprehensive and authoritative format, this unique handbook provides environmental chemists, geoscientists, engineers, and modelers with the essential capabilities to understand and quantify transport. In addition, it offers a one-stop resource on environmental mass transfer and mass transport coefficient estimation methods for all genres. The book begins by discussing mass transport fundamentals from an environmental perspective. It introduces the concept of mobility — key to environmental fate, since transport must occur prior to any reaction or partitioning within the natural multimedia compartments. The fugacity approach to environmental mass transfer and the conventional approach are examined. This is followed by a description of the individual mass transport processes and the appropriate flux equations required for a quantitative expression. The editors have identified 41 individual processes believed to be the most environmentally significant, which form the basis for the remainder of the book Using a consistent format for easy reference, each chapter: Introduces the specific processes Provides a detailed qualitative description Presents key theoretical mathematical formulations Describes field or laboratory measurements of transport parameters Gives data tables and algorithms for numerical estimates Offers a guide for users familiar with the process who are seeking a direct pathway to obtain the numerical coefficients Presents computed example problems, case studies and/or exercises with worked-through solutions and answers The final chapter presents the editors’ insight into future needs and emerging priorities. Accessible and relevant to a broad range of science and engineering users, this volume captures the state of the transport science and practice in this critical area.
The basics of environmental chemistry and a toolbox for solving problems Elements of Environmental Chemistry uses real-world examples to help readers master the quantitative aspects of environmental chemistry. Complex environmental issues are presented in simple terms to help readers grasp the basics and solve relevant problems. Topics covered include: steady- and non-steady-state modeling, chemical kinetics, stratospheric ozone, photochemical smog, the greenhouse effect, carbonate equilibria, the application of partition coefficients, pesticides, and toxic metals. Numerous sample problems help readers apply their skills. An interactive textbook for students, this is also a great refresher course for practitioners. A solutions manual is available for Academic Adopters. Please click the solutions manual link on the top left side of this page to request the manual.
A comprehensive, thoroughly modern approach to environmental quality assessment The only textbook to combine engineering transport fundamentals and equilibrium aquatic chemistry, Environmental Modeling brings a uniquely contemporary perspective to the assessment of environmental quality. Addressing key questions about fate, transport, and long-term effects of chemical pollutants in the environment, this inherently practical text gives readers the important tools they need to develop and solve their own mathematical models. Contains detailed examples from a wide range of crucial water quality areas-conventional pollutants in rivers, eutrophication of lakes, and toxic organic chemicals and heavy metals in both surface and groundwaters Examines current global issues, including atmospheric deposition, hazardous wastes, soil pollution, global change, and more Features over 200 high-quality illustrations, plus skill-building problems in every chapter Fresh in approach and broad in scope, Environmental Modeling is must reading for today's graduate and advanced undergraduate students in environmental sciences and engineering-a rich, invaluable, and superlative new resource.
There is need in environmental research for a book on fresh waters including rivers and lakes. Compared with other books on the topic, this book has a unique outline in that it follows pollution from sources to impact. Included in the text is the treatment of various tracers, ranging from pathogens to stable isotopes of elements and providing a comprehensive discussion which is lacking in many other books on pollution control of natural waters. Geophysical processes are discussed emphasizing mixing of water, interaction between water and the atmosphere, and sedimentation processes. Important geochemistry processes occurring in natural waters are described as are the processes specific to nutrients, organic pollutants, metals, and pathogens in subsequent chapters. Each of these chapters includes an introduction on the selected groups, followed by the physicochemical properties which are the most relevant to their behavior in natural waters, and the theories and models to describe their speciation, transport and transformation. The book also includes the most up to date information including a discussion on emerging pollutants such as brominated and phosphate flame retardants, perflurochemicals, and pharmaceutical and personal care products. Due to its importance an ecotoxicology chapter has been included featuring molecular biological methods, nanoparticles, and comparison of the basis of biotic ligand model with the Weibull dose-response model. Finally, the last chapter briefly summarizes the regulations on ambient water quality.