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Energy Aspects of Acoustic Cavitation and Sonochemistry: Fundamentals and Engineering covers topics ranging from fundamental modeling to up-scaled experiments. The book relates acoustic cavitation and its intrinsic energy balance to macroscopic physical and chemical events that are analyzed from an energetic perspective. Outcomes are directly projected into practical applications and technological assessments covering energy consumption, thermal dissipation, and energy efficiency of a diverse set of applications in mixed phase synthesis, environmental remediation and materials chemistry. Special interest is dedicated to the sonochemical production of hydrogen and its energetic dimensions. Due to the sensitive energy balance that governs this process, this is seen as a "green process" for the production of future energy carriers. - Provides a concise and detailed description of energy conversion and exchange within the single acoustic cavitation bubble and bubble population, accompanying physical and chemical effects - Features a comprehensive approach that is supported by experiments and the modeling of energy concentration within the sonochemical reactor, jointly with energy dissipation and damping phenomenon - Gives a clear definition of energy efficiency metrics of industrial sono-processes and their application to the main emergent industrial fields harnessing acoustic cavitation and sonochemistry, notably for the production of hydrogen
Sonochemistry and the Acoustic Bubble provides an introduction to the way ultrasound acts on bubbles in a liquid to cause bubbles to collapse violently, leading to localized 'hot spots' in the liquid with temperatures of 5000° celcius and under pressures of several hundred atmospheres. These extreme conditions produce events such as the emission of light, sonoluminescence, with a lifetime of less than a nanosecond, and free radicals that can initiate a host of varied chemical reactions (sonochemistry) in the liquid, all at room temperature. The physics and chemistry behind the phenomena are simply, but comprehensively presented. In addition, potential industrial and medical applications of acoustic cavitation and its chemical effects are described and reviewed. The book is suitable for graduate students working with ultrasound, and for potential chemists and chemical engineers wanting to understand the basics of how ultrasound acts in a liquid to cause chemical and physical effects.
The sonochemical process is newly advanced oxidation process (AOP) developed for hazardous pollutants destruction in aqueous effluents. This technique produces, in situ, a highly oxidative environment via the irradiation of aqueous solution using high frequency ultrasound to degrade potential contaminants. This book covers sonochemical pollutant degradation from fundamental principles, recent application, to challenges and future trends.
The Acoustic Bubble describes the interaction of acoustic fields with bubbles in liquid. The book consists of five chapters. Chapter 1 provides a basic introduction to acoustics, including some of the more esoteric phenomena that can be seen when high-frequency high-intensity underwater sound is employed. Chapter 2 discusses the nucleation of cavitation and basic fluid dynamics, while Chapter 3 draws together the acoustics and bubble dynamics to discuss the free oscillation of a bubble and acoustic emissions from such activity. The acoustic probes that are often applied to study the behavior of a bubble when an externally-applied acoustic field drives it into oscillation is deliberated in Chapter 4. The last chapter outlines a variety of effects associated with acoustically-induced bubble activity. The bubble detection, sonoluminescence, sonochemistry, and pulse enhancement are also covered. This publication is a good reference for physics and engineering students and researchers intending to acquire knowledge of the acoustic interactions of acoustic fields with bubbles.
Power ultrasound has been used for many years in two specific industrial areas: cleaning and plastic welding. Over the last ten years an increasing interest has been shown in its potential for use over a much wider range of chemistry and processing which has been grouped together under the general title of sonochemistry. Most of these uses depend on the generation of acoustic cavitation in liquid media but this text, while underlining the importance of the physics and mathematics of cavitation, mainly concentrates on applications of the technology. After an introduction to the topic and some historical background to the uses of power ultrasound the general principles of acoustic cavitation are explored including some background physics, bubble dynamics and factors which influence cavitation. The remainder of the book incorporates a series of applications of sonochemistry which illustrate the types of physical and chemical effects of ultrasonically induced cavitation which will interest chemists and engineers alike. Amongst the major topics included are chemical synthesis, environmental protection and remediation of water, sewage and soils, polymer synthesis and processing, electrochemistry including both analytical and synthetic aspects and plating. The final chapter reviews the range of ultrasonic equipment available in the laboratory and the progress made towards the scale-up of sonochemistry. The level is introductory to semi-advanced and no topic has been taken to a particularly specialist level since it is intended that this should be of general interest to readers with a scientific background.
This brief explains in detail fundamental concepts in acoustic cavitation and bubble dynamics, and describes derivations of the fundamental equations of bubble dynamics in order to support those readers just beginning research in this field. Further, it provides an in-depth understanding of the physical basis of the phenomena. With regard to sonochemistry, the brief presents the results of numerical simulations of chemical reactions inside a bubble under ultrasound, especially for a single-bubble system and including unsolved problems. Written so as to be accessible both with and without prior knowledge of fundamental fluid dynamics, the brief offers a valuable resource for students and researchers alike, especially those who are unfamiliar with this field. A grasp of fundamental undergraduate mathematics such as partial derivative and fundamental integration is advantageous; however, even without any background in mathematics, readers can skip the equations and still understand the fundamental physics of the phenomena using the book’s wealth of illustrations and figures. As such, it is also suitable as an introduction to the field.
The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Despite the fact that chemical applications of ultrasound are now widely acknowledged, a detailed presentation of inorganic systems covering nano-particles, catalysis, aqueous chemistry of metallic solutions and their redox characteristics, both from a theoretical and experimental perspective has eluded researchers of this field. Theoretical and Experimental Sonochemistry Involving Inorganic Systems fills this gap and presents a concise and thorough review of this fascinating area of Sonochemistry in a single volume.
This book provides readers with a comprehensive overview of the processes and technologies utilized for producing hydrogen from renewable sources. It discusses common methods like gasification, pyrolysis, and liquefaction, along with novel methods like water thermochemical splitting, biophotolysis, biological water‐gas shift reaction, and fermentation processing. The application of various renewable sources, including wind, solar, and geothermal energy, is covered in detail. Introduces water splitting conversion processes for hydrogen production in detail Uniquely provides different pyrolysis, gasification, and liquefaction processes for hydrogen generation Covers different biomass and waste sources for producing hydrogen Discusses biochemical methods for converting biomass to hydrogen Provides the application of renewable energy sources in hydrogen production Part of the multivolume Handbook of Hydrogen Production and Applications, this standalone book guides researchers and academics in chemical, environmental, energy, and related areas of engineering interested in the development and implementation of hydrogen production technologies.