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This volume presents the acomplishments of over 85 internationlly renowned scientists whose work was influenced by Professor Wasan's groundbreaking research on interfacial phenomena at The Illinois Institute of Technology, Chicago.
This book takes an interface science approach to describe and understand the behavior of the dispersions we call emulsions, microemulsions and foams. The one thing all these dispersions have in common is the presence of surface-active species (surfactants) adsorbed at the interfaces between the two fluid phases that make up the emulsions, microemulsions or foams. The interfacial layers formed by the surfactants control most of the properties of the dispersions. The book describes the properties of interfacial layers, thin films and bulk fluids used in the elaboration of the various dispersions and it explains how such properties relate to the dispersion properties of these soft matter systems: structure, rheology and stability. These dispersion properties are far from being fully understood, in particular foam and emulsion stability. In discussing the state of the art of the current knowledge, the author draws interesting parallels between emulsions, microemulsions and foams that enlighten the interpretation of previous observations and point to a deeper understanding of the behavior of these materials in the future.
Combining academic and industrial viewpoints, this is the definitive stand-alone resource for researchers, students and industrialists. With the latest on foam research, test methods and real-world applications, it provides straightforward answers to why foaming occurs, how it can be avoided, and how different degrees of antifoaming can be achieved.
Until now colloid science books have either been theoretical, or focused on specific types of dispersion, or on specific applications. This then is the first book to provide an integrated introduction to the nature, formation and occurrence, stability, propagation, and uses of the most common types of colloidal dispersion in the process-related industries. The primary focus is on the applications of the principles, paying attention to practical processes and problems. This is done both as part of the treatment of the fundamentals, where appropriate, and also in the separate sections devoted to specific kinds of industries. Throughout, the treatment is integrated, with the principles of colloid and interface science common to each dispersion type presented for each major physical property class, followed by separate treatments of features unique to emulsions, foams, or suspensions. The first half of the book introduces the fundamental principles, introducing readers to suspension formation and stability, characterization, and flow properties, emphasizing practical aspects throughout. The following chapters discuss a wide range of industrial applications and examples, serving to emphasize the different methodologies that have been successfully applied. Overall, the book shows how to approach making emulsions, foams, and suspensions with different useful properties, how to propagate them, and how to prevent their formation or destabilize them if necessary. The author assumes no prior knowledge of colloid chemistry and, with its glossary of key terms, complete cross-referencing and indexing, this is a must-have for graduate and professional scientists and engineers who may encounter or use emulsions, foams, or suspensions, or combinations thereof, whether in process design, industrial production, or in related R&D fields.
The main physicochemical aspects of foam and foam films such as preparation, structure, properties, are considered, giving a special emphasis on foam stability. It is shown that the foam and foam films are an efficient object in the study of various surface phenomena and in establishing regularities common for different interfaces, in particular, water/oil interface. The techniques and results on foam films have an independent meaning and involve the latest achievement in this field, with a focus on authors' results. The book has an expressed monographic character. It reveals joint ideas, i.e. the quantitative approach in treating foams is based on foam film behaviour and the techniques for controlling the foam liquid content, developed by the authors. A major contribution represents the independent consideration of formation and stability of foam films in theoretical and experimental aspects. No monograph published so far reveals these topics in the mentioned manner. Data and information about foams, physicochemical characterization of surfactants, phospholipids and polymers can also be found. Furthermore, the book provides information about: techniques involved in the study of foam films and foam structure and properties; foam drainage; processes of destruction in gravitational and centrifugal fields; reasons for stability of films and their role in the processes running in the foam; mechanical, rheological, optical, thermophysical, electrical properties; foam destruction upon addition of antifoams (mechanism of destruction, techniques, application); scientific principles of controlling foam properties and their application in foam separation and concentration; enhanced oil recovery; thermodynamic and non-equilibrium properties of foam films, stabilized by surfactants, phospholipids and polymers; techniques for the study of surface forces; formation and stability of foam films; black films, including bilayers; new theories of stability of amphiphile bilayer; experiments involved in this stability; application in biology and medicine.
This book describes in detail the scientific philosophy of the formation and stabilization-destabilization of foams. It presents all hierarchical steps of a foam, starting from the properties of adsorption layers formed by foaming agents, discussing the properties of foam films as the building blocks of a foam, and then describing details of real foams, including many fields of application. The information presented in the book is useful to people working on the formulation of foams or attempting to avoid or destruct foams in unwanted situations.
This is the first book to provide an integrated introduction to the nature, formation and occurrence, stability, propagation, and uses of the most common types of colloidal dispersion in the process-related industries. The primary focus is on the applications of the principles, paying attention to practical processes and problems. This is done both as part of the treatment of the fundamentals, where appropriate, and also in the separate sections devoted to specifi c kinds of industries. Throughout, the treatment is integrated, with the principles of colloid and interface science common to each dispersion type presented for each major physical property class, followed by separate treatments of features unique to emulsions, foams, or suspensions. The first half of the book introduces the fundamental principles, introducing readers to suspension formation and stability, characterization, and fl ow properties, emphasizing practical aspects throughout. The following chapters discuss a wide range of industrial applications and examples, serving to emphasize the diff erent methodologies that have been successfully applied. The author assumes no prior knowledge of colloid chemistry and, with its glossary of key terms, complete cross-referencing and indexing, this is a must-have for graduate and professional scientists and engineers who may encounter or use emulsions, foams, or suspensions, or combinations thereof, whether in process design, industrial production, or in related R&D fields.
A general and introductory survey of foams, emulsions and cellular materials. Foams and emulsions are illustrations of some fundamental concepts in statistical thermodynamics, rheology, elasticity and the physics and chemistry of divided media and interfaces. They also give rise to some of the most beautiful geometrical shapes and tilings, ordered or disordered. The chapters are grouped into sections having fairly loose boundaries. Each chapter is intelligible alone, but cross referencing means that the few concepts that may not be familiar to the reader can be found in other chapters in the book. Audience: Research students, researchers and teachers in physics, physical chemistry, materials science, mechanical engineering and geometry.
This comprehensive reference provided a systematic examination of both the theory and applications of thin liquid films - giving a critical review of major concepts and unresolved or controversial problems, as well as revealing experimental methods. It includes results previously unpublished. Combining the work of 20 leading researchers, Thin Liquid Films furnishes a fundamental overview of thermodynamics of thin liquid films. Generously illustrated with equations, tables and drawling and containing more than 2,200 citations to pertinent literature, this is an authoritative reference for physical, surface, and colloid chemists, biophysicists and physicists; chemical engineers and advanced graduate students in chemistry, chemical engineering, biophysics and physics.