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Several long-term trends in technology evolution have become apparent since these symposia began in 1989. Earlier presenters more frequently discussed treatment methods involving harsh and extensive human intervention. As the symposia have continued, the number of presentations describing extremely harsh and expensive treatment technologies have gradually been supplanted by more subtle and gentler methods. Such methods include subsurface-engineered barriers, phytoremediation, and bioremediation. Nineteen manuscripts were selected for inclusion in this volume, based upon peer review, scientific merit, the editors' perceptions of lasting value or innovative features, and the general applicability of either the technology itself or the scientific methods and scholarly details provided by the authors. General topics include: soil treatment, groundwater treatment, and radioactive waste treatment.
TheI&ECSYMPOSIUMfromwhichthisvolumewasderivedfeatured519presen tationsat88technicalsessionsduringathree-daymeetingonSeptember17-20, 1996in Birmingham,Alabamawith580registrants. Thefinalselectionsforthechaptersincluded hereinwerebasedonpeerreview,scientificmerit,theeditors'perceptionsoflastingvalue orinnovativefeatures, andthegeneralapplicabilityofeitherthetechnologyitselforthe scientificmethodsandscholarlydetailsprovidedbytheauthors. Thevolume isacontinuationofathemeinitiatedin 1990. Itspredecessors,Emerg ing Technologies in Hazardous Waste Management, ACS Symposium Series No. 422 (1990), EmergingTechnologiesinHazardous WasteManagementII,ACSSymposiumSe ries No. 468 (1991), Emerging Technologies in Hazardous WasteManagement III, ACS SymposiumSeriesNo. 518(1993), EmergingTechnologiesinHazardous WasteManage mentIV, ACSSymposium Series No. 554 (1994),Emerging Technologies in Hazardous WasteManagement V. ACSSymposiumSeriesNo. 607(1995), andEmergingTechnolo gies in Hazardous Waste Management VI, American AcademyofEnvironmental Engi neersPublication (1996), arerelatedcontributionsonhazardouswastemanagement,but eachvolumeisessentiallydifferent. Byinspection,thereadermayquicklyrecognizethis diversity,andalsoconcludethatnosinglevolumecandojusticetothebreadthanddepth oftechnologiesbeingdevelopedandappliedinpractice. Thecontributionspresented in thisvolumearedivided intofourseparatebutcom plementary sections, including: (1) Chemical and Thermal Treatment; (2) Biochemical Treatment;(3)SeparationTechnologies;and(4)RadioactiveWasteTreatment. D. WilliamTedder FrederickG. Pohland GeorgiaInstituteofTechnology UniversityofPittsburgh Atlanta, Georgia30332-0100 Pittsburgh,Pennsylvania15261-2294 v ACKNOWLEDGMENTS The Industrial & Engineering Chemistry (I&EC) Division ofACS organized and sponsored the symposium. ACS Corporate Associates was a majorfinancial cosponsor; theAmericanInstituteofChemicalEngineers(AIChE)EnvironmentalSciencesDivision, theAIChECenterforWasteReductionTechnologies,theAmericanAcademyofEnviron mental Engineers,andtheJointAssociationfor theAdvancementsofSupercriticalFluid Technologywerenominalcosponsors;andEnviroExpocositedanexhibition. Thisgener osity was essential to the overall successofthe symposium and is gratefully acknow ledged. vii CONTENTS I. EmergingTechnologiesinHazardousWasteManagementVII:AnOverview. . . FrederickG. PohlandandD. WilliamTedder ChemicalandThermalMethods 2. GranularIronOxideasaCatalystinChemicalOxidationofOrganic Contaminants. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 MiratD. Gurol,Shu-SungLin,andNileshBhat 3. AnElectronBeamGeneratedPlasmaReactorforDecompositionof HalogenatedVOCs 23 S. A. Vitale, K. Hadidi,D. R. Cohn, L. Bromberg,andP. Falkos 4. IncinerationandThermalTreatmentofChemicalAgentsandChemicalWeapons 33 F. C. GouldinandE. M. Fisher 5. PredictingStabilityConstantsofVariousChelatingAgentsUsingQSAR Technology 49 R. W. Okey,S. Lin,andP. K. A. Hong 6. MineralizationofHazardousChemicalsbyHemeReaction . . . . . . . . . . . . . . . . . 69 GuyoungKang,JimoJung,KapsongPark,andDavidK. Stevens BiochemicalTreatment 7. AnaerobicTransformationsofCarbonTetrachloride:CombinedBacterialand AbioticProcesses 81 FlynnW. Picardal,SanggooKim,AnnaRadue,andDeberaBackhus 8. BiorecoveryofMetalsfromAcidMineDrainage. . . . . . . . . . . . . . . . . . . . . . . . . 91 RakeshGovind,UmaKumar,RamaPuligadda,JimmyAntia,and HenryTabak ix x Contents 9. BiotreatmentofMinewater-ContainingCyanidesbyUsingImmobilizedCell Technology 103 Onguri K. Vijaya,G. R. V. Babu,JackAdams,JamesH. Wolfram,and KiritD. Chapatwala 10. Augmentationofin-SituSubsoilRemediationUsingColloidalGasDispersions 113 P. G. Chaphalkar,K. T. Valsaraj,D. Roy, W. D. Constant,andP. Lee 11. EffectofSorptionontheMicrobialReductiveDechlorinationofSoil-Bound Chloroalkenes 127 SpyrosG. PavlostathisandPingZhuang SeparationTechnologies 12. TheRemovalofVOCsfromExhaustAirandVapourCondensatesby MembraneProcesses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Proceedings of the I&EC Division of the ACS Symposium held in Birmingham, Alabama, September 17-20, 1996
Most industrial and hazardous waste management resources cover the major industries and provide conventional in-plant pollution control strategies. Until now however, no book or series of books has provided coverage that includes the latest developments in innovative and alternative environmental technology, design criteria, managerial decision met
Historically, the development of civilization has upset much of the earth’s ecosystem leading to air, land, and water pollution. The author defines pollution as the introduction of a foreign substance into an ecosystem via air, land or water. This book delves into issues that effect the everyday lives of people who come in contact with these hazards. By examining these issues, this body of work aims to stimulate debate and offer solutions to the ever-growing threat to the environment and humanity. Includes problems with each chapter, Explores issues such as control of gaseous emissions, waste recycling and waste disposal, Explains physical and thermal methods of waste management, Provides definitions and resources for future reference, Discusses the history of environmental technology.
Hazardous Waste Management: An Overview of Advanced and Cost-Effective Solutions includes the latest practical knowledge and theoretical concepts for the treatment of hazardous wastes. The book covers five major themes, namely, ecological impact, waste management hierarchy, hazardous waste characteristics and regulations, hazardous wastes management, and future scope of hazardous waste management. It serves as a comprehensive and advanced reference for undergraduate students, researchers and practitioners in the field of hazardous wastes and focuses on the latest emerging research in the management of hazardous waste, the direction in which this branch is developing as well as future prospects. The book deals with all these components in-depth, however, particular attention is given to management techniques and cost-effective, economically feasible solutions for hazardous wastes released from various sources. Comprehensively explores the impact of hazardous wastes on human health and ecosystems Discusses toxicity across solid waste, aquatic food chain and airborne diseases Categorically elaborates waste treatment and management procedures with current challenges Discusses future challenges and the importance of renewing technologies
In this sequel volume to ACS Symposium Series No. 422, Emerging Technologies in Hazardous Waste Management, the editors expand their coverage of the subject with contributions on air treatment, as well as a greater examination of computer applications and modeling. Twenty-one chapters are divided into four sections covering thermal treatment and abiotic emissions control, water management, biological treatment, and solid waste management. Of special interest is a presentation on the use of internal radiant energy within a gas-fired combustion chamber to maintain high combustion temperatures, a technique that appears important for the thermal destruction of many chlorinated species.