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One of the greatest revolutions in materials science in recent years has been the literal renaissance of age-old materials in new and unexpected guises and possessing correspondingly astounding properties. There was once a time, for instance, when textbooks declared that only metals could offer any progress in superconduction. Since then, familiar perovskites – and even humble magnesium boride – have been recognised as being so-called ‘room-temperature’ superconductors. Carbon in particular has benefited from this revolution and has now found application as routinely deposited diamond coatings and as C60 ‘buckyballs’. The most recent innovation has been the discovery and preparation of graphene; single-monolayer carbon having a remarkable strength. This success has naturally led researchers to ask whether other materials might also be prepared in an analogous monolayer form and offer similarly amazing properties. The present monograph summarizes all of the work carried out on such monolayer materials up to the beginning of 2017, with attention being restricted to those, like graphene, being composed of a single element. Most of the work done so far on these ‘elemental graphene analogues’ has been theoretical, but the existing experimental data suggest that they may well become as useful as graphene.
Graphene’s nickname ‘miracle material’ normally means the material superior properties. However, all these characteristics are only the outward manifestation of the wonderful nature of graphene. The real miracle of graphene is that the specie is a union of two entities: a physical - and a chemical one, each of which is unique in its own way. The book concerns a very close interrelationship between graphene physics and chemistry as expressed via typical spin effects of a chemical physics origin. Based on quantum-chemical computations, the book is nevertheless addressed to the reflection of physical reality and it is aimed at an understanding of what constitutes graphene as an object of material science – sci graphene – on the one hand, and as a working material- high tech graphene - for a variety of attractive applications largely discussed and debated in the press, on the other. The book is written by a user of quantum chemistry, sufficiently experienced in material science, and the chemical physics of graphene is presented as the user view based on results of extended computational experiments in tight connection with their relevance to physical and chemical realities. The experiments have been carried out at the same theoretical platform, which allows considering different sides of the graphene life at the same level in light of its chemical peculiarity.
Monoelemental 2D materials called Xenes have a graphene-like structure, intra-layer covalent bond, and weak van der Waals forces between layers. Materials composed of different groups of elements have different structures and rich properties, making Xenes materials a potential candidate for the next generation of 2D materials. 2D Monoelemental Materials (Xenes) and Related Technologies: Beyond Graphene describes the structure, properties, and applications of Xenes by classification and section. The first section covers the structure and classification of single-element 2D materials, according to the different main groups of monoelemental materials of different components and includes the properties and applications with detailed description. The second section discusses the structure, properties, and applications of advanced 2D Xenes materials, which are composed of heterogeneous structures, produced by defects, and regulated by the field. Features include: Systematically detailed single element materials according to the main groups of the constituent elements Classification of the most effective and widely studied 2D Xenes materials Expounding upon changes in properties and improvements in applications by different regulation mechanisms Discussion of the significance of 2D single-element materials where structural characteristics are closely combined with different preparation methods and the relevant theoretical properties complement each other with practical applications Aimed at researchers and advanced students in materials science and engineering, this book offers a broad view of current knowledge in the emerging and promising field of 2D monoelemental materials.
This book highlights all newly reported carbon nanostructures including graphene and its derivatives, carbon nanotubes, metal organic frameworks, fullerenes, nanorods, nanospheres, nano onions, porous nanoparticles, nanohorns, nanofibers and nanoribbons, nanodiamonds, graphitic carbon nitrides, carbon aerogels and hydrogels, graphdiyne and graphenylene. It presents the historical development of carbon nanostructures technologies, different types and classifications, and different fabrication and functionalization techniques, including outer/inner surface functionalization and covalent and noncovalent functionalization. This Handbook discusses the unique properties of functionalized carbon nanostructures that can be obtained by modifying their structures, composition, and surface. It gives the reader an in-depth look at the current achievements of research and practice while pointing you ahead to new possibilities in functionalizing and using carbon nanomaterials. Finally, it covers the various applications of functionalized carbon nanostructures including adsorbents, additives, active materials in energy accumulating systems (batteries, hydrogen storage systems, and supercapacitors), filtering media, catalysts or supports for catalysts, sensors or substrates for sensors, additives for polymers, ceramic composites, metal and carbon alloys, glasses, digital textiles, and composite materials.
This book offers a timely and complete overview on chemical vapour deposition (CVD) and its variants for the processing of nanoparticles, nanowires, nanotubes, nanocomposite coatings, thin and thick films, and composites. Chapters discuss key aspects, from processing, material structure and properties to practical use, cost considerations, versatility, and sustainability. The author presents a comprehensive overview of CVD and its potential in producing high performance, cost-effective nanomaterials and thin and thick films. Features Provides an up-to-date introduction to CVD technology for the fabrication of nanomaterials, nanostructured films, and composite coatings Discusses processing, structure, functionalization, properties, and use in clean energy, engineering, and biomedical grand challenges Covers thin and thick films and composites Compares CVD with other processing techniques in terms of structure/properties, cost, versatility, and sustainability Kwang-Leong Choy is the Director of the UCL Centre for Materials Discovery and Professor of Materials Discovery in the Institute for Materials Discovery at the University College London. She earned her D.Phil. from the University of Oxford, and is the recipient of numerous honors including the Hetherington Prize, Oxford Metallurgical Society Award, and Grunfeld Medal and Prize from the Institute of Materials (UK). She is an elected fellow of the Institute of Materials, Minerals and Mining, and the Royal Society of Chemistry.
This book reviews the current state-of-the art of single layer silicene up to thicker silicon nanosheets, and their structure, properties and potential applications. Silicene is a newly discovered material that is one atomic layer think. It is a two-dimensional (2D) nanomaterial that is classified as a nanosheet, which has large lateral dimensions up to micrometres, but thicknesses of only nanometres or less. Silicon nanosheets are currently a very ‘hot’ area of research. The unique properties and morphology of such materials make them ideal for a variety of applications, including electronic devices, batteries and sensors. 2D nanosheets of silicon can be considered as analogues of graphene. As silicon is already the major component of electronic devices, the significance of nanosheets composed of silicon is that they can be more easily integrated into existing electronic devices. Furthermore, if 2D nanostructured Si can be implemented into such devices, then their size could be reduced into the nano-regime, providing unique properties different from bulk Si that is currently employed. The book is written for researchers and graduate students.
Introduction to Graphene: Chemical and Biochemical Applications addresses a broad range of graphene research, including the prehistory and background of graphene, synthetic approaches, characterization techniques, composites/derivatives, inorganic graphene analogues, and applications of graphene. The book's special emphasis on solution chemistry and graphene sets it apart from less practical titles in that its concepts are immediately implementable in the laboratories of chemists and biochemists. The book presents a variety of experimental approaches from the authors' research laboratories and others around the world for graphene preparation in the solution phase, especially under aqueous conditions or in animal serum—the most practical kind of graphene for chemists and biochemists. The book is ideally suited for a broad range of readers, including advanced undergraduates, graduate research students and professionals in state-of-the-art research labs who want to use graphene to develop novel applications. - Features reviews of the most recent advances in graphene research across chemistry and biochemistry - Emphasizes chemical and biological applications for specialists, aiding more multi-disciplinary research - Presents a variety of experimental approaches for graphene preparation in the solution phase, especially under aqueous conditions or even in animal serum
Nanoelectronic Devices for Hardware and Software Security has comprehensive coverage of the principles, basic concepts, structure, modeling, practices, and circuit applications of nanoelectronics in hardware/software security. It also covers the future research directions in this domain. In this evolving era, nanotechnology is converting semiconductor devices dimensions from micron technology to nanotechnology. Nanoelectronics would be the key enabler for innovation in nanoscale devices, circuits, and systems. The motive for this research book is to provide relevant theoretical frameworks that include device physics, modeling, circuit design, and the latest developments in experimental fabrication in the field of nanotechnology for hardware/software security. There are numerous challenges in the development of models for nanoscale devices (e.g., FinFET, gate-all-around devices, TFET, etc.), short channel effects, fringing effects, high leakage current, and power dissipation, among others. This book will help to identify areas where there are challenges and apply nanodevice and circuit techniques to address hardware/software security issues.
Synthetic Polymeric Membranes for Advanced Water Treatment, Gas Separation, and Energy Sustainability is a cutting-edge guide that focuses on advanced water treatment applications, covering oily wastewater treatment, desalination, removal of dyes and pigments, photodegradation of organic hazardous materials, heavy metal removal, removal and recovery of nutrients, and volatile organic compounds. Other sections examine the area of gas separation, including acidic gas removal, oxygen enrichment, gas and vapor separation, hydrogen separation, and gas sensing. Final sections cover applications for sustainable energy usage, including the use of synthetic polymer membranes in proton exchange membrane fuel cells (PEMFCs), and more. This is a highly valuable guide for researchers, scientists, and advanced students, working with polymer membranes and films, and across polymer science, polymer chemistry, materials science, chemical e - Explains the design, preparation and characterization of synthetic polymer-based membranes for advanced applications - Provides a clear picture of the state-of-the-art in the field, including novel fabrication approaches and the latest advances in physico-chemical characterizations - Supports the development and implementation of innovative, sustainable solutions to water treatment, gas separation and energy devices
Fundamentals and Sensing Applications of 2D Materials provides a comprehensive understanding of a wide range of 2D materials. Examples of fundamental topics include: defect and vacancy engineering, doping and advantages of 2D materials for sensing, 2D materials and composites for sensing, and 2D materials in biosystems. A wide range of applications are addressed, such as gas sensors based on 2D materials, electrochemical glucose sensors, biosensors (enzymatic and non-enzymatic), and printed, stretchable, wearable and flexible biosensors. Due to their sub-nanometer thickness, 2D materials have a high packing density, thus making them suitable for the fabrication of thin film based sensor devices. Benefiting from their unique physical and chemical properties (e.g. strong mechanical strength, high surface area, unparalleled thermal conductivity, remarkable biocompatibility and ease of functionalization), 2D layered nanomaterials have shown great potential in designing high performance sensor devices. - Provides a comprehensive overview of 2D materials systems that are relevant to sensing, including transition metal dichalcogenides, metal oxides, graphene and other 2D materials system - Includes information on potential applications, such as flexible sensors, biosensors, optical sensors, electrochemical sensors, and more - Discusses graphene in terms of the lessons learned from this material for sensing applications and how these lessons can be applied to other 2D materials