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Recent progress in the theory and computation of electronic structure is bringing an unprecedented level of capability for research. Many-body methods are becoming essential tools vital for quantitative calculations and understanding materials phenomena in physics, chemistry, materials science and other fields. This book provides a unified exposition of the most-used tools: many-body perturbation theory, dynamical mean field theory and quantum Monte Carlo simulations. Each topic is introduced with a less technical overview for a broad readership, followed by in-depth descriptions and mathematical formulation. Practical guidelines, illustrations and exercises are chosen to enable readers to appreciate the complementary approaches, their relationships, and the advantages and disadvantages of each method. This book is designed for graduate students and researchers who want to use and understand these advanced computational tools, get a broad overview, and acquire a basis for participating in new developments.
Both a history and a metahistory, Representing Electrons focuses on the development of various theoretical representations of electrons from the late 1890s to 1925 and the methodological problems associated with writing about unobservable scientific entities. Using the electron—or rather its representation—as a historical actor, Theodore Arabatzis illustrates the emergence and gradual consolidation of its representation in physics, its career throughout old quantum theory, and its appropriation and reinterpretation by chemists. As Arabatzis develops this novel biographical approach, he portrays scientific representations as partly autonomous agents with lives of their own. Furthermore, he argues that the considerable variance in the representation of the electron does not undermine its stable identity or existence. Raising philosophical issues of contentious debate in the history and philosophy of science—namely, scientific realism and meaning change—Arabatzis addresses the history of the electron across disciplines, integrating historical narrative with philosophical analysis in a book that will be a touchstone for historians and philosophers of science and scientists alike.
An off-beat introduction to how electricity works in practical applications.
This book deals with the physics of spin-polarized free electrons. Many aspects of this rapidly expanding field have been treated in review articles, but to date a self-contained monograph has not been available. In writing this book, I have tried to oppose the current trend in science that sees specialists writing primarily for like-minded specialists, and even physicists in closely related fields understanding each other less than they are inclined to admit. I have attempted to treat a modern field of physics in a style similar to that of a textbook. The presentation should be intelligible to readers at the graduate level, and while it may demand concentration, I hope it will not require decipher ing. If the reader feels that it occasionally dwells upon rather elementary topics, he should remember that this pedestrian excursion is meant to be reasonably self-contained. It was, for example, necessary to give a simple introduction to the Dirac theory in order to have a basis for the discussion of Mott scattering-one of the most important techniques in polarized electron studies.
Reveals the links between an atom's structure and its chemical destiny showing how an atom makes its passage through nature.
In the excitement and rapid pace of developments, writing pedagogical texts has low priority for most researchers. However, in transforming my lecture l notes into this book, I found a personal benefit: the organization of what I understand in a (hopefully simple) logical sequence. Very little in this text is my original contribution. Most of the knowledge was collected from the research literature. Some was acquired by conversations with colleagues; a kind of physics oral tradition passed between disciples of a similar faith. For many years, diagramatic perturbation theory has been the major theoretical tool for treating interactions in metals, semiconductors, itiner ant magnets, and superconductors. It is in essence a weak coupling expan sion about free quasiparticles. Many experimental discoveries during the last decade, including heavy fermions, fractional quantum Hall effect, high temperature superconductivity, and quantum spin chains, are not readily accessible from the weak coupling point of view. Therefore, recent years have seen vigorous development of alternative, nonperturbative tools for handling strong electron-electron interactions. I concentrate on two basic paradigms of strongly interacting (or con strained) quantum systems: the Hubbard model and the Heisenberg model. These models are vehicles for fundamental concepts, such as effective Ha miltonians, variational ground states, spontaneous symmetry breaking, and quantum disorder. In addition, they are used as test grounds for various nonperturbative approximation schemes that have found applications in diverse areas of theoretical physics.
An understanding of the effects of electronic correlations in quantum systems is one of the most challenging problems in physics, partly due to the relevance in modern high technology. Yet there exist hardly any books on the subject which try to give a comprehensive overview on the field covering insulators, semiconductors, as well as metals. The present book tries to fill that gap.It intends to provide graduate students and researchers a comprehensive survey of electron correlations, weak and strong, in insulators, semiconductors and metals. This topic is a central one in condensed matter and beyond that in theoretical physics. The reader will have a better understanding of the great progress which has been made in the field over the past few decades.
Low-energy electrons are ubiquitous in nature and play an important role in natural phenomena as well as many potential and current industrial processes. Authored by 16 active researchers, this book describes the fundamental characteristics of low-energy electron–molecule interactions and their role in different fields of science and technology, including plasma processing, nanotechnology, and health care, as well as astro- and atmospheric physics and chemistry. The book is packed with illustrative examples, from both fundamental and application sides, features about 130 figures, and lists over 800 references. It may serve as an advanced graduate-level study course material where selected chapters can be used either individually or in combination as a basis to highlight and study specific aspects of low-energy electron–molecule interactions. It is also directed at researchers in the fields of plasma physics, nanotechnology, and radiation damage to biologically relevant material (such as in cancer therapy), especially those with an interest in high-energy-radiation-induced processes, from both an experimental and a theoretical point of view.
Electrons, Atoms, and Molecules in Inorganic Chemistry: A Worked Examples Approach builds from fundamental units into molecules, to provide the reader with a full understanding of inorganic chemistry concepts through worked examples and full color illustrations. The book uniquely discusses failures as well as research success stories. Worked problems include a variety of types of chemical and physical data, illustrating the interdependence of issues. This text contains a bibliography providing access to important review articles and papers of relevance, as well as summaries of leading articles and reviews at the end of each chapter so interested readers can readily consult the original literature. Suitable as a professional reference for researchers in a variety of fields, as well as course use and self-study. The book offers valuable information to fill an important gap in the field. Incorporates questions and answers to assist readers in understanding a variety of problem types Includes detailed explanations and developed practical approaches for solving real chemical problems Includes a range of example levels, from classic and simple for basic concepts to complex questions for more sophisticated topics Covers the full range of topics in inorganic chemistry: electrons and wave-particle duality, electrons in atoms, chemical binding, molecular symmetry, theories of bonding, valence bond theory, VSEPR theory, orbital hybridization, molecular orbital theory, crystal field theory, ligand field theory, electronic spectroscopy, vibrational and rotational spectroscopy