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Electrodissolution Processes: Fundamentals and Applications discusses the basic principles involved in high-rate anodic dissolution processes and their application in advanced machining, micromachining, and finishing operations. The fundamentals section of the book discusses the anodic dissolution behavior of different classes of metals and the influence of mass transport, current distribution, and surface film properties on the metal removal rate and surface finishing. The applications section of the book presents essential elements of electrochemical and assisted techniques for precision machining, micromachining, and polishing of advanced materials, including hard-to-machine conducting ceramic materials. Features A first-of-its-kind book that provides updated scientific and engineering information related to high-rate anodic dissolution processes Highlights the importance of the understanding of basic principles required for designing and optimizing ECM/EMM/EP processes Gives equal emphasis to the fundamentals and applications of electrodissolution processes Discusses the high-rate anodic dissolution of two broad classes of materials, namely, engineering and refractory materials Presents case studies to demonstrate the capabilities of different electrochemical and assisted machining, micromachining, and finishing operations Presents a dedicated chapter on electrochemical planarization of copper interconnects Madhav Datta is the Chairman of Amrita Center for Industrial Research and Innovation and a Distinguished Professor in the Department of Chemical Engineering and Materials Science, Amrita University, Coimbatore, India.
Sheds new light on the significance of electrode inhomogeneity and electrochemical heterogeneity A major contribution to the field of electrochemistry, this book—based on a thorough review of the literature and author Yongjun Tan's twenty years of pioneering research—examines electrochemical heterogeneity and its effects on non-uniform electrode processes. The book focuses on localized corrosion, uneven electrodeposition, and non-uniform electrodissolution. Readers will learn all the core fundamentals, experimental methods, and engineering aspects of localized corrosion and other important heterogeneous electrode processes. In particular, readers will learn core methods to quickly calculate corrosion rates and study electrode inhomogeneity and electrochemical heterogeneity. Heterogeneous Electrode Processes and Localized Corrosion begins with a review of homogeneous electrode models and uniform corrosion measurements and then explores probing electrode inhomogeneity, electrochemical heterogeneity, and localized corrosion. Next, the book examines: Visualizing localized corrosion using electrochemically integrated multi-electrode arrays Measuring thermodynamic and kinetic parameters of localized corrosion processes Characterizing inhomogeneity and localized corrosion on coated electrode surfaces Designing experiments to study localized corrosion and its inhibition in inhomogeneous media Sensing localized electrodeposition and electrodissolution Exploring versatile heterogeneous electrode processes Throughout the book, there are case studies with maps that illustrate key aspects of heterogeneous electrode processes. In addition, the author provides plenty of examples that enable readers to fully grasp core concepts of electrochemical heterogeneity and its relationship to non-uniform electrode processes. Reviewing the experimental findings presented in this book, electrochemists will gain a better appreciation and understanding of the fundamental significance of electrode inhomogeneity and electrochemical heterogeneity.
This is the first of two volumes offering the very first comprehensive treatise of self-organization and non-linear dynamics in electrochemical systems. The second volume covers spatiotemporal patterns and the control of chaos. The content of both volumes is organized so that each description of a particular electrochemical system is preceded by an introduction to basic concepts of nonlinear dynamics, in order to help the reader unfamiliar with this discipline to understand at least fundamental concepts and the methods of stability analysis. The presentation of the systems is not limited to laboratory models but stretches out to real-life objects and processes, including systems of biological importance, such as neurons in living matter. Marek Orlik presents a comprehensive and consistent survey of the field.
Esta primera parte del libro "Trends in Electrochemistry and Corrosion at the beginning of the 21st century", dedicado al Prof. Josep M. Costa en ocasión de su 70 aniversario, reúne un total de 33 artículos y revisiones originales, tanto científicas como tecnológicas, correspondientes al campo de la Electroquímica. Estos trabajos están escritos en español e inglés por unos 110 investigadores de todo el mundo, y son exponentes representativos del gran nivel alcanzado por la investigación internacional en diversas materias de gran interés en la Electroquímica de principios de este siglo XXI. Los trabajos se han agrupado en 5 capítulos generales relativos a los campos de Electroquímica Molecular, Electrodeposición, Electrodos Modificados, Descontaminación Electroquímica, y Sensores y Electroanálisis....This first part of the book "Trends in Electrochemistry and Corrosion at the beginning of the 21st century", dedicated to Professor Josep M. Costa in occasion of his 70th birthday, collects 33 original papers and reviews, both scientific and technologic, corresponding to the field of Electrochemistry. These works are written in English and Spanish by about 110 researchers of all around the world, and are representative exponents of the high level reached by the international research in several topics of great interest in Electrochemistry at the beginning of the 21st Century. The works have been distributed into five general chapters related to the fields of Molecular Electrochemistry, Electrodeposition, Modified Electrodes, Electrochemical Depollution, and Sensors and Electroanalysis.
This is the second of two volumes offering the very first comprehensive treatise of self-organization and non-linear dynamics in electrochemical systems. The first volume covers general principles of self-organization as well as temporal instabilities. The content of both volumes is organized so that each description of a particular electrochemical system is preceded by an introduction to basic concepts of nonlinear dynamics, in order to help the reader unfamiliar with this discipline to understand at least fundamental concepts and the methods of stability analysis. The presentation of the systems is not limited to laboratory models but stretches out to real-life objects and processes, including systems of biological importance, such as neurons in living matter. Marek Orlik presents a comprehensive and consistent survey of the field.
Taking into account that corrosion is costly and dangerous phenomenon, it becomes obvious that people engaged in the design and the maintenance of structures and equipment, should have a basic understanding of localized corrosion processes. The Editor hopes that this book will be helpful for researchers in conducting investigations in the field of localized corrosion, as well as for engineers encountering pitting and crevice corrosion, by providing some basic information concerning the causes, prevention, and control of pitting corrosion.
This second edition of the highly successful dictionary offers more than 300 new or revised terms. A distinguished panel of electrochemists provides up-to-date, broad and authoritative coverage of 3000 terms most used in electrochemistry and energy research as well as related fields, including relevant areas of physics and engineering. Each entry supplies a clear and precise explanation of the term and provides references to the most useful reviews, books and original papers to enable readers to pursue a deeper understanding if so desired. Almost 600 figures and illustrations elaborate the textual definitions. The “Electrochemical Dictionary” also contains biographical entries of people who have substantially contributed to electrochemistry. From reviews of the first edition: ‘the creators of the Electrochemical Dictionary have done a laudable job to ensure that each definition included here has been defined in precise terms in a clear and readily accessible style’ (The Electric Review) ‘It is a must for any scientific library, and a personal purchase can be strongly suggested to anybody interested in electrochemistry’ (Journal of Solid State Electrochemistry) ‘The text is readable, intelligible and very well written’ (Reference Reviews)