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This issue of ECS Transactions includes some of the key contributions made to the symposium, entitled 'Electrode Processes Relevant to Fuel Cell Technology¿, held during the 217th meeting of The Electrochemical Society, in Vancouver, Canada, from April 25 to 30, 2010. Some of the key topics that were addressed include fundamental kinetics and mechanisms of multi-step reactions, especially the oxygen reduction reaction; kinetics and mechanisms of poisoning and other electrode degradation processes; modeling, simulation, and evaluation of electrode microstructure/performance relationships and related phenomena; computational modeling of fuel cell reaction mechanisms and kinetics at the molecular level; interfacial aspects; novel electrode materials; and new techniques to probe fuel cell electrode reactions.
High temperature solid oxide fuel cell (SOFC) technology is a promising power generation option that features high electrical efficiency and low emissions of environmentally polluting gases such as CO2, NOox and SOx. It is ideal for distributed stationary power generation applications where both high-efficiency electricity and high-quality heat are in strong demand. For the past few decades, SOFC technology has attracted intense worldwide R&D effort and, along with polymer electrolyte membrane fuel cell (PEMFC) technology, has undergone extensive commercialization development. This book presents a systematic and in-depth narrative of the technology from the perspective of fundamentals, providing comprehensive theoretical analysis and innovative characterization techniques for SOFC technology. The book initially deals with the basics and development of SOFC technology from cell materials to fundamental thermodynamics, electronic properties of solids and charged particle transport. This coverage is extended with a thorough analysis of such operational features as current flow and energy balance, and on to voltage losses and electrical efficiency. Furthermore, the book also covers the important issues of fuel cell stability and durability with chapters on performance characterization, fuel processing, and electrode poisoning. Finally, the book provides a comprehensive review for SOFC materials and fabrication techniques. A series of useful scientific appendices rounds off the book. Solid oxide fuel cell technology is a standard reference for all those researching this important field as well as those working in the power industry. Provides a comprehensive review of solid oxide fuel cells from history and design to chemistry and materials development Presents analysis of operational features including current flow, energy balance, voltage losses and electrical efficiency Explores fuel cell stability and durability with specific chapters examining performance characterization, fuel processing and electrode poisoning
Fuel cells are expected to play a major role in the future power supply that will transform to renewable, decentralized and fluctuating primary energies. At the same time the share of electric power will continually increase at the expense of thermal and mechanical energy not just in transportation, but also in households. Hydrogen as a perfect fuel for fuel cells and an outstanding and efficient means of bulk storage for renewable energy will spearhead this development together with fuel cells. Moreover, small fuel cells hold great potential for portable devices such as gadgets and medical applications such as pacemakers. This handbook will explore specific fuel cells within and beyond the mainstream development and focuses on materials and production processes for both SOFC and lowtemperature fuel cells, analytics and diagnostics for fuel cells, modeling and simulation as well as balance of plant design and components. As fuel cells are getting increasingly sophisticated and industrially developed the issues of quality assurance and methodology of development are included in this handbook. The contributions to this book come from an international panel of experts from academia, industry, institutions and government. This handbook is oriented toward people looking for detailed information on specific fuel cell types, their materials, production processes, modeling and analytics. Overview information on the contrary on mainstream fuel cells and applications are provided in the book 'Hydrogen and Fuel Cells', published in 2010.
This concise sourcebook of the electrochemical, engineering and economic principles involved in the development and commercialization of fuel cells offers a thorough review of applications and techno-economic assessment of fuel cell technologies, plus in-depth discussion of conventional and novel approaches for generating energy. Parts I and II explain basic and applied electrochemistry relevant to an understanding of fuel cells. Part III covers engineering and technology aspects. The book is useful for undergraduate and graduate students and scientists interested in fuel cells. Unlike any other current book on fuel cells, each chapter includes problems based on the discussions in the text.
A complete, up-to-date, introductory guide to fuel cell technology and application Fuel Cell Fundamentals provides a thorough introduction to the principles and practicalities behind fuel cell technology. Beginning with the underlying concepts, the discussion explores fuel cell thermodynamics, kinetics, transport, and modeling before moving into the application side with guidance on system types and design, performance, costs, and environmental impact. This new third edition has been updated with the latest technological advances and relevant calculations, and enhanced chapters on advanced fuel cell design and electrochemical and hydrogen energy systems. Worked problems, illustrations, and application examples throughout lend a real-world perspective, and end-of chapter review questions and mathematical problems reinforce the material learned. Fuel cells produce more electricity than batteries or combustion engines, with far fewer emissions. This book is the essential introduction to the technology that makes this possible, and the physical processes behind this cost-saving and environmentally friendly energy source. Understand the basic principles of fuel cell physics Compare the applications, performance, and costs of different systems Master the calculations associated with the latest fuel cell technology Learn the considerations involved in system selection and design As more and more nations turn to fuel cell commercialization amidst advancing technology and dropping deployment costs, global stationary fuel cell revenue is expected to grow from $1.4 billion to $40.0 billion by 2022. The sector is forecasted to explode, and there will be a tremendous demand for high-level qualified workers with advanced skills and knowledge of fuel cell technology. Fuel Cell Fundamentals is the essential first step toward joining the new energy revolution.
Ammonia Fuel Cells covers all aspects of ammonia fuel cell technologies and their applications, including their theoretical analysis, modeling studies and experimental investigations. The book analyzes the role of integrated ammonia fuel cell systems within various renewable energy resources and existing energy systems. Covers the types of ammonia fuel cells that have been developed over history Features explanations of the underlying fundamentals and principles of ammonia fuel cells, along with methods to assess the performance of different types of cell Includes case studies considering different applications of ammonia fuel cells and their significance in the future of clean energy
The necessity for a better understanding of the basic processes that determine the operation of fuel cells became evident during the devel opment of practical units in the last three decades. The search for efficient electrocatalysts in low-temperature fuel cells intensified the general study of the nature and the role of the electrode material. Re search on the complex mechanisms of the anodic oxidation of different fuels and of the reduction of molecular oxygen on solid electrodes was stimulated, and the strong influence of adsorbed species on the electrode reaction in question was investigated. Suitable electrolytes had to be found for the high-temperature fuel cells. The use of electrodes with large internal surface lead to the development of models of porous electrode. structures and to the mathematical analysis of the operation of these models under certain conditions. While the chapters I to III introduce the reader to the general field offuel cells, the progress made in the understanding of the basic problems in the electrochemistry of fuel cells since the end of the second world war is reviewed in chapters IV to XVI of this monograph. In contrast, the technological aspects necessary for the development of practical units are not covered here. The open literature published as books or as papers in scientific journals has been considered up to the time of the writing of the final draft of the specific chapter, at least till the end of 1967.
A fuel cell is an electrochemical device that converts the chemical energy of a reaction (between fuel and oxidant) directly into electricity. Given their efficiency and low emissions, fuel cells provide an important alternative to power produced from fossil fuels. A major challenge in their use is the need for better materials to make fuel cells cost-effective and more durable. This important book reviews developments in materials to fulfil the potential of fuel cells as a major power source. After introductory chapters on the key issues in fuel cell materials research, the book reviews the major types of fuel cell. These include alkaline fuel cells, polymer electrolyte fuel cells, direct methanol fuel cells, phosphoric acid fuel cells, molten carbonate fuel cells, solid oxide fuel cells and regenerative fuel cells. The book concludes with reviews of novel fuel cell materials, ways of analysing performance and issues affecting recyclability and life cycle assessment. With its distinguished editor and international team of contributors, Materials for fuel cells is a valuable reference for all those researching, manufacturing and using fuel cells in such areas as automotive engineering. Examines the key issues in fuel cell materials research Reviews the major types of fuel cells such as direct methanol and regenerative fuel cells Further chapters explore ways of analysing performance and issues affecting recyclability and life cycle assessment
Fuel Cells and Hydrogen: From Fundamentals to Applied Research provides an overview of the basic principles of fuel cell and hydrogen technology, which subsequently allows the reader to delve more deeply into applied research. In addition to covering the basic principles of fuel cells and hydrogen technologies, the book examines the principles and methods to develop and test fuel cells, the evaluation of the performance and lifetime of fuel cells and the concepts of hydrogen production. Fuel Cells and Hydrogen: From Fundamentals to Applied Research acts as an invaluable reference book for fuel cell developers and students, researchers in industry entering the area of fuel cells and lecturers teaching fuel cells and hydrogen technology. Includes laboratory methods for fuel cell characterization and manufacture Outlines approaches in modelling components, cells and stacks Covers practical and theoretical methods for hydrogen production and storage