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This book describes the origin, use, and limitations of electrochemical phase diagrams, testing schemes for active, passive, and localized corrosion, the development and electrochemical characterization of passivity, and methods in process alteration, failure prediction, and materials selection. It offers useful guidelines for assessing the efficac
Workers in the field of corrosion and their students are most fortunate that a happy set of circumstances brought Dr. Marcel Pourbaix into their field in 1949. First, he was invited, while in the USA, to demonstrate at a two week visit to the National Bureau of Standards the usefulness of his electro chemical concepts to the study of corrosion. Secondly, also around the same time, Prof. H. H. Uhlig made a speech before the United Nations which pointed out the tremendous economic consequences of corrosion. Because of these circumstances, Dr. Pourbaix has reminisced, he chose to devote most of his efforts to corrosion rather than to electrolysis, batteries, geology, or any of the other fields where, one might add, they were equally valuable. This decision resulted in his establishing CEBELCOR (Centre BeIge d'Etude de la Corrosion) and in his development of a course at the Free University of Brussels entitled "Lectures on Electrochemical Corrosion." This book is the collection of these lectures translated into English.
Electrochemistry plays an important role in preserving our cultural heritage. For the first time this has been documented in the present volume. Coverage includes both electrochemical processes such as corrosion and electroanalytical techniques allowing to analyse micro- and nanosamples from works of art or archaeological finds. While this volume is primarily aimed at electrochemists and analytical chemists, it also contains relevant information for conservators, restorers, and archaeologists.
Electrochemistry and Corrosion Science is a graduate level text/professional reference that describes the types of corrosion on metallic materials. The focus will be on modeling and engineering approximation schemes that describe the thermodynamics and kinetics of electrochemical systems. The principles of corrosion behavior and metal recovery are succinctly described with the aid of pictures, figures, graphs and schematic models, followed by derivation of equations to quantify relevant parameters. Example problems are included to illustrate the application of electrochemical concepts and mathematics for solving complex corrosion problems. This book differs from others in that the subject matter is organized around the modeling and predicating approaches that are used to determine detrimental and beneficial electrochemical events. Thus, this book will take a more practical approach and make it especially useful as a basic text and reference for professional engineers.
This book summarizes the electrochemical routes of nanostructure preparation in a systematic and didactic manner. It provides a comprehensive overview of electrodeposition, anodization, carbon nanotube preparation and other methods of nanostructure fabrication, combining essential information on the physical background of electrochemistry with materials science aspects of the field. The book includes a brief introduction to general electrochemistry with an emphasis on physico-chemical aspects, followed by a description of the sample preparation methods. In each chapter, an overview of the particular method is accompanied by a discussion of the relevant physical or chemical properties of the materials, including magnetic, mechanical, optical, catalytic, sensoric and other features. While some preparation methods are discussed in connection with the theories of physical electrochemistry (e.g. electrodeposition), the book also covers methods that are more heuristic but nonetheless utilize electric current (e.g. anodization of porous alumina or synthesis of carbon nanotubes by means of electric arc discharge).
Proceedings of the 4th International Symposium on Electrochemical Methods in Corrosion Research (EMCR IV), Espoo, Finland, July 1991
Covering the essential aspects of the corrosion behavior of metals in aqueous environments, this book is designed with the flexibility needed for use in courses for upper-level undergraduate and graduate students, for concentrated courses in industry, for individual study, and as a reference book.
Das führende Werk auf seinem Gebiet - jetzt durchgängig auf den neuesten Stand gebracht! Die theoretischen Grundlagen der Elektrochemie, erweitert um die aktuellsten Erkenntnisse in der Theorie des Elektronentransfers, werden hier ebenso besprochen wie alle wichtigen Anwendungen, darunter modernste Verfahren (Ultramikroelektroden, modifizierte Elektroden, LCEC, Impedanzspektrometrie, neue Varianten der Pulsvoltammetrie und andere). In erster Linie als Lehrbuch gedacht, läßt sich das Werk aber auch hervorragend zum Selbststudium und zur Auffrischung des Wissensstandes verwenden. Lediglich elementare Grundkenntnisse der physikalischen Chemie werden vorausgesetzt.
Proceedings of the 2nd International Symposium on Electrochemical Methods in Corrosion Research (EMCR II), Toulouse, France, 1985