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Solid state batteries with a lithium metal electrode are considered the next generation of high energy battery technology. Unfortunately, lithium metal is prone to harmful protrusion or dendrite growth which causes dangerous cell failure. Within this work the problem of protrusion growth is tackled by deriving a novel electro-chemo-mechanical theory tailored for binary solid state batteries which is then used to discuss the impact of mechanics on interface stability by numerical studies.
A lithium-ion battery comprises essentially three components: two intercalation compounds as positive and negative electrodes, separated by an ionic-electronic electrolyte. Each component is discussed in sufficient detail to give the practising engineer an understanding of the subject, providing guidance on the selection of suitable materials in actual applications. Each topic covered is written by an expert, reflecting many years of experience in research and applications. Each topic is provided with an extensive list of references, allowing easy access to further information. Readership: Research students and engineers seeking an expert review. Graduate courses in electrical drives can also be designed around the book by selecting sections for discussion. The coverage and treatment make the book indispensable for the lithium battery community.
Materials Thermochemistry, the 6th Edition of Metallurgical Thermochemistry, aims to demonstrate the central role of thermochemistry in the understanding and designing of materials and materials processes. Extensively revised and up-dated, the 6th Edition of this classic work includes all the latest developments in experimental methods, new methods for estimating thermochemical data for both pure and alloy substances, new practical applications of thermochemical calculations, and up-dated tables of critically evaluated thermochemical data for inorganic substances and binary alloy systems. The basic principles of chemical thermodynamics are presented in a straightforward way with many examples of the use of thermochemical calculations in solving a variety of materials' problems. Although thermodynamics is an established field, this 6th Edition presents the newest experimental methods and calculations of complex equilibria associated with the most recent materials and environmental considerations (e.g. environmental pollution). This text is suitable for graduates and undergraduates alike and provides basic information necessary for researchers to apply thermochemical principles and data to the optimization of materials and materials processes.
Transition Metal Oxides for Electrochemical Energy Storage Explore this authoritative handbook on transition metal oxides for energy storage Metal oxides have become one of the most important classes of materials in energy storage and conversion. They continue to have tremendous potential for research into new materials and devices in a wide variety of fields. Transition Metal Oxides for Electrochemical Energy Storage delivers an insightful, concise, and focused exploration of the science and applications of metal oxides in intercalation-based batteries, solid electrolytes for ionic conduction, pseudocapacitive charge storage, transport and 3D architectures and interfacial phenomena and defects. The book serves as a one-stop reference for materials researchers seeking foundational and applied knowledge of the titled material classes. Transition Metal Oxides offers readers in-depth information covering electrochemistry, morphology, and both in situ and in operando characterization. It also provides novel approaches to transition metal oxide-enabled energy storage, like interface engineering and three-dimensional nanoarchitectures. Readers will also benefit from the inclusion of: A thorough introduction to the landscape and solid-state chemistry of transition metal oxides for energy storage An exploration of electrochemical energy storage mechanisms in transition metal oxides, including intercalation, pseudocapacitance, and conversion Practical discussions of the electrochemistry of transition metal oxides, including oxide/electrolyte interfaces and energy storage in aqueous electrolytes An examination of the characterization of transition metal oxides for energy storage Perfect for materials scientists, electrochemists, inorganic chemists, and applied physicists, Transition Metal Oxides for Electrochemical Energy Storage will also earn a place in the libraries of engineers in power technology and professions working in the electrotechnical industry seeking a one-stop reference on transition metal oxides for energy storage.
This Data Handbook is a updated and largely extended new edition of the book "Semiconductors: Basic Data". The data of the former edition have been updated and a complete representation of all relevant basic data is now given for all known groups of semiconducting materials.
The handbook focuses on a complete outline of lithium-ion batteries. Just before starting with an exposition of the fundamentals of this system, the book gives a short explanation of the newest cell generation. The most important elements are described as negative / positive electrode materials, electrolytes, seals and separators. The battery disconnect unit and the battery management system are important parts of modern lithium-ion batteries. An economical, faultless and efficient battery production is a must today and is represented with one chapter in the handbook. Cross-cutting issues like electrical, chemical, functional safety are further topics. Last but not least standards and transportation themes are the final chapters of the handbook. The different topics of the handbook provide a good knowledge base not only for those working daily on electrochemical energy storage, but also to scientists, engineers and students concerned in modern battery systems.
This book offers a comprehensive analysis of novel design strategies in higher energy solid-state lithium batteries. It describes synthesis and experimental techniques to characterize the physical, chemical and electrochemical properties of the electrode and electrolytes. The book reports on electrochemical measurements of conductivity and related parameters in solid electrolytes and its interfaces. It also presents various technologies that have been used for the fabrication of all-solid-state lithium-ion batteries such as thin-film, 3D printing (additive manufacturing) and atomic layer deposition. A large part of the text focus on the description on the complete functioning and challenges with the electrochemistry of the electrodes and solid electrolyte interfaces. The book also supplies valuable insight into potential growth opportunities in this exciting market and cost-effective design tactics in solid-state assemblies.
The main motivation for the organization of the Advanced Research Workshop in Belgirate was the promotion of discussions on the most recent issues and the future perspectives in the field of Solid State lonics. The location was chosen on purpose since Belgirate was the place were twenty years ago, also then under the sponsorship of NATO, the very first international meeting on this important and interdisciplinary field took place. That meeting was named "Fast Ion Transport in Solids" and gathered virtually everybody at that time having been active in any aspect of motion of ions in solids. The original Belgirate Meeting made for the first time visible the technological potential related to the phenomenon of the fast ionic transport in solids and, accordingly, the field was given the name "Solid State lonics". This field is now expanded to cover a wide range of technologies which includes chemical sensors for environmental and process control, electrochromic windows, mirrors and displays, fuel cells, high performance rechargeable batteries for stationary applications and electrotraction, chemotronics, semiconductor ionics, water electrolysis cells for hydrogen economy and other applications. The main idea for holding an anniversary meeting was that of discussing the most recent issues and the future perspectives of Solid State lonics just twenty years after it has started at the same location on the lake Maggiore in North Italy.