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Carbon Capture and Storage is a key technology for a sustainable and low carbon economy. This book unites top academic and industry researchers in search for commercial concepts for CCS at coal power ploants. This reference focuses on power plant technology and ways to improve efficiency. It details the three principal ways of capturing the CO2 produced in power plants: oxyfuel combustion, postcombustion and precombustion, with the main part concentrating on the different approaches to removing carbon dioxide. Wtih an eye on safety, the authors explain how the three parts of the CCS chain work - capture, transport and storage - and how they can be performed safely. The result is specific insights for process engineers, chemists, physicists and materials engineers in their relevant fields, as well as a sufficiently broad scope to be able to understand the opportunities and implications of the other disciples.
To achieve goals for climate and economic growth, "negative emissions technologies" (NETs) that remove and sequester carbon dioxide from the air will need to play a significant role in mitigating climate change. Unlike carbon capture and storage technologies that remove carbon dioxide emissions directly from large point sources such as coal power plants, NETs remove carbon dioxide directly from the atmosphere or enhance natural carbon sinks. Storing the carbon dioxide from NETs has the same impact on the atmosphere and climate as simultaneously preventing an equal amount of carbon dioxide from being emitted. Recent analyses found that deploying NETs may be less expensive and less disruptive than reducing some emissions, such as a substantial portion of agricultural and land-use emissions and some transportation emissions. In 2015, the National Academies published Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration, which described and initially assessed NETs and sequestration technologies. This report acknowledged the relative paucity of research on NETs and recommended development of a research agenda that covers all aspects of NETs from fundamental science to full-scale deployment. To address this need, Negative Emissions Technologies and Reliable Sequestration: A Research Agenda assesses the benefits, risks, and "sustainable scale potential" for NETs and sequestration. This report also defines the essential components of a research and development program, including its estimated costs and potential impact.
Coal power plants generate about half of the United States' electricity and are expected to remain a key energy source. Coal power plants also account for about one-third of the nation's emissions of carbon dioxide (CO2 ), the primary greenhouse gas that experts believe contributes to climate change. Current regulatory efforts and proposed legislation that seek to reduce CO2 emissions could affect coal power plants. Two key technologies show potential for reducing CO2 emissions: (1) carbon capture and storage (CCS), which involves capturing and storing CO2 in geologic formations, and (2) plant efficiency improvements that allow plants to use less coal. The Department of Energy (DOE) plays a key role in accelerating the commercial availability of these technologies and devoted more than $600 million to them in fiscal year 2009. Congress asked GAO to examine (1) the maturity of these technologies; (2) their potential for commercial use, and any challenges to their use; and (3) possible implications of deploying these technologies. To conduct this work, GAO reviewed reports and interviewed stakeholders with expertise in coal technologies. DOE does not systematically assess the maturity of key coal technologies, but GAO found consensus among stakeholders that CCS is less mature than efficiency technologies. Specifically, DOE does not use a standard set of benchmarks or terms to describe the maturity of technologies, limiting its ability to provide key information to Congress, utilities, and other stakeholders. This lack of information limits congressional oversight of DOE's expenditures on these efforts, and it hampers policymakers' efforts to gauge the maturity of these technologies as they consider climate change policies. In the absence of this information from DOE, GAO interviewed stakeholders with expertise in CCS or efficiency technologies to identify their views on the maturity of these technologies. Stakeholders told GAO that while components of CCS have been used commercially in other industries, their application remains at a small scale in coal power plants, with only one fully integrated CCS project operating at a coal plant. Efficiency technologies, on the other hand, are in wider commercial use. Use of both technologies is, however, contingent on overcoming a variety of economic, technical, and legal challenges. In particular, with respect to CCS, stakeholders highlighted the large costs to install and operate current CCS technologies, the fact that large scale demonstration of CCS is needed in coal plants, and the lack of a national carbon policy to reduce CO2 emissions or a legal framework to govern liability for the permanent storage of large amounts of CO2. With respect to efficiency improvements, stakeholders highlighted the high cost to build or upgrade such coal plants, the fact that some upgrades require highly technical materials, and plant operators' concerns that changes to the existing fleet of coal power plants could trigger additional regulatory requirements. CCS technologies offer more potential to reduce CO2 emissions than efficiency improvements alone, and both could raise electricity costs and have other effects. Most stakeholders told GAO that CCS would increase electricity costs, and some reports estimate that current CCS technologies would increase electricity costs by about 30 to 80 percent at plants using these technologies. DOE has also reported that CCS could increase water consumption at power plants. Efficiency improvements offer more potential for near term reductions in CO2 emissions, but they cannot reduce CO2 emissions from a coal plant to the same extent as CCS. GAO recommends that DOE develop a standard set of benchmarks to gauge and report to Congress on the maturity of key technologies. In commenting on a draft of this report, DOE concurred with our recommendation.
Carbon capture and storage (CCS) is among the advanced energy technologies suggested to make the conventional fossil fuel sources environmentally sustainable. It is of particular importance to coal-based economies. This book deals at length with the various aspects of carbon dioxide capture, its utilization and takes a closer look at the earth processes in carbon dioxide storage. It discusses potential of Carbon Capture, Storage, and Utilization as innovative energy technology towards a sustainable energy future. Various techniques of carbon dioxide recovery from power plants by physical, chemical, and biological means as well as challenges and prospects in biomimetic carbon sequestration are described. Carbon fixation potential in coal mines and in saline aquifers is also discussed. Please note: This volume is Co-published with The Energy and Resources Institute Press, New Delhi. Taylor & Francis does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka
1. 1. Greenhouse gas emissions and climate change . . . . . . . . . . . . . . 3 1. 1. 1. Emissions and concentrations of greenhouse gases 3 1. 1. 2. Impact of increasing greenhouse gases concentration 4 1. 2. Options to reduce carbon dioxide emissions 5 1. 2. 1. Carbon dioxide removal 8 1. 3. Scope of the thesis 10 1. 4. Outline of the thesis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 1. 4. 1. General evaluation method. . . . . . . . . . . . . . . . . . . . . . . 12 1. 4. 2. Some notes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 II. Simulation and optimization of carbon dioxide recovery from the flue gases of a coal-fired power plant using amines 14 Abstract 19 2. 1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 2. 2. The chemical absorption process. . . . . . . . . . . . . . . . . . . . . . . . 22 2. 2. 1. General process description. . . . . . . . . . . . . . . . . . . . . . . 22 2. 2. 2. Types of absorbent 23 2. 2. 3. Effects of flue gas contaminants 24 2. 3. Simulation of the scrubber in ASPEN PLUS . . . . . . . . . . . . . . . . . 25 2. 3. 1. ASPEN PLUS for flow sheet simulation 26 2. 3. 2. Simulation of the performance for the base-case design . . 26 the scrubber . . . . . . . . . . . . . . . . . . . . . . 29 2. 3. 3. Optimization of 2. 3. 4. Design and results 32 2. 3. 5. Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 2. 4. Integration of the scrubber in the power plant 35 2. 4. 1. Power loss caused by steam extraction 36 2. 4. 2. Power saved by avoiding preheating boiler feed water . . . 38 2. 4. 3. Power consumption by the carbon dioxide scrubber . . . . . 38 2. 4. 4. Power consumption for carbon dioxide compression . . . . . 38 2. 4. 5. Calculation of plant efficiency losses " . . . . . . . . . . . . . . 39 2. 5.
Any comprehensive approach to substantially reduce greenhouse gases must address the world's dependency on coal for a quarter of its energy demand, including almost half of its electricity demand. To maintain coal in the world's energy mix in a carbon-constrained future would require development of a technology to capture and store its carbon dioxide emissions. This situation suggests to some that any greenhouse gas reduction program be delayed until such carbon capture technology has been demonstrated. However, technological innovation and the demands of a carbon control regime are interlinked; a technology policy is no substitute for environmental policy and must be developed in concert with it. Much of the debate about developing and commercializing carbon capture technology has focused on the role of research, development, and deployment (technology-push mechanisms). However, for technology to be fully commercialized, it must also meet a market demand -- a demand created either through a price mechanism or a regulatory requirement (demand-pull mechanisms). Any conceivable carbon capture technology for coal-fired powerplants will increase the cost of electricity generation from affected plants because of efficiency losses. Therefore, few companies are likely to install such technology until they are required to, either by regulation or by a ...