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Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics introduces the general principles of diffusion in the subsurface environment and discusses the implications for the fate and transport of contaminants in soils and groundwater. Emphasis is placed on sorption/desorption and the dissolution kinetics of organic contaminants, both of which are limited by the slow speed of molecular diffusion. Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics compiles methods for calculating the diffusion coefficients of organic compounds (in aqueous solution or vapor phase) in natural porous media. The author uses analytical solutions of Fick's 2nd law and some simple numerical models to model diffusive transport under various initial and boundary conditions. A number of these models may be solved using spreadsheets. The book examines sorption/desorption rates of organic compounds in various soils and aquifer materials, and also examines the dissolution kinetics of nonaqueous phase liquids in aquifers, in both the trapped residual phase and in pools. Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics concludes with a discussion of the impact of slow diffusion processes on soil and groundwater decontamination and the implications of these processes for groundwater risk assessment.
This monograph gives an historical account of the development of the dusty-gas model for the description of gas transport in porous media, and describes the model and its applications in sufficient detail that it can be employed in engineering practice.
This volume contains the lectures presented at the NATO ADVANCED STUDY INSTITUTE that took place at Newark, Delaware, U. S. A. , July 14-23, 1985. The objective of this meeting was to present and discuss selected topics associated with transport phenomena in porous media. By their very nature, porous media and phenomena of transport of extensive quantities that take place in them, are very complex. The solid matrix may be rigid, or deformable (elastically, or following some other constitutive relation), the void space may be occupied by one or more fluid phases. Each fluid phase may be composed of more than one component, with the various components capable of interacting among themselves and/or with the solid matrix. The transport process may be isothermal or non-isothermal, with or without phase changes. Porous medium domains in which extensive quantities, such as mass of a fluid phase, component of a fluid phase, or heat of the porous medium as a whole, are being transported occur in the practice in a variety of disciplines.
Fluid and flow problems in porous media have attracted the attention of industrialists, engineers and scientists from varying disciplines, such as chemical, environmental, and mechanical engineering, geothermal physics and food science. There has been a increasing interest in heat and fluid flows through porous media, making this book a timely and appropriate resource.Each chapter is systematically detailed to be easily grasped by a research worker with basic knowledge of fluid mechanics, heat transfer and computational and experimental methods. At the same time, the readers will be informed of the most recent research literature in the field, giving it dual usage as both a post-grad text book and professional reference.Written by the recent directors of the NATO Advanced Study Institute session on 'Emerging Technologies and Techniques in Porous Media' (June 2003), this book is a timely and essential reference for scientists and engineers within a variety of fields.
This new edition includes nearly 1000 new references.
Turbulence in Porous Media introduces the reader to the characterisation of turbulent flow, heat and mass transfer in permeable media, including analytical data and a review of available experimental data. Such transport processes occurring a relatively high velocity in permeable media are present in a number of engineering and natural flows. This new edition features a completely updated text including two new chapters exploring Turbulent Combustion and Moving Porous Media. De Lemos has expertly brought together a text that compiles, details, compares and evaluates available methodologies for modelling and simulating flow, providing an essential tour for engineering students working within the field as well as those working in chemistry, physics, applied mathematics, and geological and environmental sciences. Brings together groundbreaking and complex research on turbulence in porous media Extends the original model to situations including reactive systems Now discusses movement of the porous matrix
This book deals with randomly moving objects and their spreading. The objects considered are particles like atoms and molecules, but also living beings such as humans, animals, plants, bacteria and even abstract entities like ideas, rumors, information, innovations and linguistic features. The book explores and communicates the laws behind these movements and reports about astonishing similarities and very specific features typical of the given object under considerations. Leading scientists in disciplines as diverse as archeology, epidemics, linguistics and sociology, in collaboration with their colleagues from engineering, natural sciences and mathematics, introduce the phenomena of spreading as relevant for their fields. An introductory chapter on “Spreading Fundamentals” provides a common basis for all these considerations, with a minimum of mathematics, selected and presented for enjoying rather than frustrating the reader.
Multicomponent Diffusion discusses the multicomponent diffusion of the three phases of matter. The book is comprised of nine chapters that cover studies of multicomponent diffusion and mass transfer with an emphasis on the chemical characteristics responsible for multicomponent diffusion. Chapter 1 provides an introductory discourse about multicomponent diffusion. Chapter 2 discusses binary diffusion, while Chapter 3 covers multicomponent flux equation. The measurement of ternary diffusion and the estimation of ternary diffusion coefficients are also explained in the book. A chapter then covers the interacting systems, and the subsequent chapter talks about membranes without mobile carriers. The text also discusses carrier-containing membranes and the multicomponent mass transfer. The book will be of great use to researchers and professionals whose work requires a good understanding of multicomponent diffusion.