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Ionic polymers, like elephants, are easier to recognise than to define. Several methods of classification have been attempted but none is wholly satisfactory because of the extreme diversity of ionic polymers, which range from the organic, water-soluble polyelectrolytes, through hydrogels and ionomer carboxylate rubbers, to the almost infusible inorganic silicate minerals. For this reason, a general classification is not only difficult, but has minimal utility. However, there are some characteristics of these materials that should be highlighted. The role of counterions is the significant one. These ions, either singly or as clusters, take part in the formation of ionic bonds which have a varying structural role. Often they act as crosslinks, but in the halato-polymers the ionic bonds form an integral part of the polymer backbone itself. Conversely, in polymers contain ing covalent crosslinks, such as the ion-exchange resins, the coun terions have virtually no structural role to play, since they dwell in cage-like structures without affecting the crosslinking, and are readily exchanged. They are, perhaps, best described as ion-containing polymers rather than structural ionic polymers. Another crucial factor is the role of water in ionic polymers. The presence of ionic bonds means that there is a tendency for these materials to interact with water. Where the ionic polymer contains a high proportion of ionic units, it acts as a hydrogel and may be highly soluble. Such interactions with water decrease sharply as the ionic content is reduced, though even then water can act as a plasticiser.
This book focuses on electro active polymer material known as Ionic Polymer Metal Composite (IPMC) having unique applicability as sensor and actuator which finds extensive use in various domain of engineering and science research. Apart from fundamentals of the IPMC concept, various applications are covered extensively across the chapters including space, underwater and nanoscale, including manufacturing processes. Dedicated chapters are included for robotics and biomedical applications and possible research gaps. Future research perspectives for IPMC are also discussed. Features: Covers principle of Ionic Polymer Metal Composite (IPMC), manufacturing processes, applications, and future possibilities in a systematic manner Highlights IPMC practical applicability in biomedical engineering domain Explores Single-walled carbon nanotubes (SWNT) based IPMC soft actuators Discusses IPMC applications in underwater areas Includes IPMC application in robotics focusing on special compliant mechanism This book is aimed toward researchers, graduate students and professionals in materials and mechanical engineering, robotics, mechatronics, biomedical engineering, and physics.
The series covers the fundamentals and applications of different smart material systems from renowned international experts.
Polymers have achieved an enviable position as the class of materials having the highest volume of production, exceeding that of both metals and ceramics. The meteoric rise in the production and utilization of polymers has been due to advances in polymer synthesis which allow the creation of specific and well-defined molecular structures, to new knowledge concerning the relationships between polymer structure and properties, and to an improved understanding of how processing can be used as a tool to develop morphological features which result in desired properties. Polymers have truly become 'engineered materials' in every sense of the term. Polymer scientists and engineers are forever seeking to modify and improve the properties of synthetic polymeric systems for use in specific applications. Towards this end they have often looked to nature for advice on how to design molecules for specific needs. An excellent illustration of this is the use of noncovalent bonding (ionic, hydrogen, and van der Waals) in lipids, proteins, and nucleic acids, where these noncovalent bonds, acting both intra and intermolecularly, precisely control the structure and thus the function of the entire system. The utilization of ionic bonding, in particular in man-made polymers has attracted widespread interest in recent years, since ionic interactions exert a similar strong influence on the structure and properties of these synthetic systems.
Recent Advances in Ionic Liquids contains research on the preparation, characterization, and potential applications of stable ionic liquids (ILs). ILs are a class of low- and stable-melting point, ionic compounds that have a variety of properties allowing many of them to be sustainable green solvents. It is promising novel research from top to bottom and has received a lot of interest over the last few decades. It covers the advanced topics of physical, catalytic, chemical, polymeric, and potential applications of ILs. This book features interesting reports on cutting-edge science and technology related to the preparation, characterization, polymerization, and potential applications of ILs. This potentially unique work offers various approaches on the R
From the reviews: "...This very well written new book is recommended to academic and industrial researchers and specialists interested in green polymers and mainly in their thermal properties...This new and opportune book covers some important properties of green polymers and bio-composites." (D. Feldman, Concordia University, Montreal, Canada)
Solvents and ionic liquids are ubiquitous within our whole life since ancient times and their effects are actually being studied through basic sciences like Chemistry, Physics and Biology as well as being researched by a large number of scientific disciplines.This book represents an attempt to present examples on the utility of old and new solvents and the effects they exercise on several fields of academic and industrial interest. The first section, Solvents, presents information on bio-solvents and their synthesis, industrial production and applications, about per and trichloroethylene air monitoring in dry cleaners in the city of Sfax (Tunsia) and on the synthesis of polyimides using molten benzoic acid as the solvent. The second section, Ionic Liquids, shows information about the synthesis, physicochemical characterization and exploration of antimicrobial activities of imidazolium ionic liquid-supported Schiff base and its transition metal complexes, the technology of heterogenization of transition metal catalysts towards the synthetic applications in an ionic liquid matrix, the progress in ionic liquids as reaction media, monomers, and additives in high-performance polymers, a pre-screening of ionic liquids as gas hydrate inhibitor via application of COSMO-RS for methane hydrate, the extraction of aromatic compounds from their mixtures with alkanes from ternary to quaternary (or higher) systems and a review on ionic liquids as environmental benign solvent for cellulose chemistry. The final section, Solvent Effects, displays interesting information on solvent effects on dye sensitizers derived from anthocyanidins for applications in photocatalysis, about the solvent effect on a model of SNAr reaction in conventional and non-conventional solvents, and on solvent effects in supramolecular systems.
Ionic polymers are present almost everywhere in the world, biological systems being the most important reservoir of ionic polymers such as nucleic acids, and many proteins, alginic acid and so on. Artificial ionic polymers derived from natural polymers such as chitin, cellulose or starch, by adequate chemical transformations, and a multitude of synthetic ionic polymers are generated in the laboratory. They can contain ionic or ionisable groups. Ionic polymers, either artificial or synthetic, have a multitude of applications such as: stabilisation or destabilisation of dispersions, thickening of solutions, oil recovery aids, water purification, corrosion inhibitors, soil conditioners, anti-static agents, additives in cosmetics and foods, surface modification, and so forth. Solid ionic hybrid materials found applications such as polymer electrolytes or substrates for the organic synthesis in solid phase. Many books and article reviews were dedicated to this wide class of polymers but the permanent diversification of their structures and applications ask for new and updated overviews on this field. Therefore, this book reports updated information from literature as well as original contributions in the field of ionic (co)polymers and hybrids, mainly on the applications of ionic polymers and hybrids such as: self-assembled multi-layers, ionic polymers containing azobenzene chromophore, phase separation processes, chelating ion exchangers, polymer electrolytes, functionalised solid surfaces and ionic hybrid hydrogels.