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Organic photovoltaics (OPVs) are a promising carbon-neutral energy conversion technology, with recent improvements pushing power conversion efficiencies over 10%. A major factor limiting OPV performance is inefficiency of charge transport in organic semiconducting materials (OSCs). Due to strong coupling with lattice degrees of freedom, the charges form polarons, localized quasi-particles comprised of charges dressed with phonons. These polarons can be conceptualized as pseudo-atoms with a greater effective mass than a bare charge. Here we propose that due to this increased mass, polarons can be modeled with Langevin molecular dynamics (LMD), a classical approach with a computational cost much lower than most quantum mechanical methods. Here we present LMD simulations of charge transfer between a pair of fullerene molecules, which commonly serve as electron acceptors in OSCs. We find transfer rates consistent with experimental measurements of charge mobility, suggesting that this method may provide quantitative predictions of efficiency when used to simulate materials on the device scale. Our approach also offers information that is not captured in the overall transfer rate or mobility: in the simulation data, we observe exactly when and why intermolecular transfer events occur. In addition, we demonstrate that these simulations can shed light on the properties of polarons in OSCs. In conclusion, much remains to be learned about these quasi-particles, and there are no widely accepted methods for calculating properties such as effective mass and friction. Our model offers a promising approach to exploring mass and friction as well as providing insight into the details of polaron transport in OSCs.
The performance of organic semiconductor devices is heavily dependent on the precise molecular-level arrangement and overall morphology of the functional layers. In organic photovoltaic applications, exciton mobility, fission/fusion or dissociation, as well as charge transport and separation are some of the morphology-dependent processes that are of interest for efficient device design. In this work a combination of experimental and computational techniques are used to elucidate the behaviour of excitons in conjugated polymer and small-molecule semiconductor systems. While there is an emphasis on photovoltaic applications, many concepts are generally applicable to other organic electronic applications such organic light emitting diodes and photodetectors. In Chapter 3, a pump-push-probe transient absorption technique is used to observe high-energy "hot" excitons formed by photoexcitation of the conjugated polymer poly(3-hexylthiophene) (P3HT). The work demonstrates the ability to clearly isolate the transient signal of the hot exciton decay processes from the thermalised exciton population, where picosecond and sub-picosecond relaxation of hot excitons through torsional motion in the disordered polymer chain is observed. In addition, the push-induced dissociation of high-energy excitons into free charge carriers is able to be quantified and an upper bound on the exciton binding energy determined. Spectroscopic experiments on P3HT are accompanied by a hybrid quantum-classical exciton hopping model in Chapter 4. Coarse-grained molecular dynamics are used to obtain realistic structures of P3HT free chains and nanofibre aggregates, to which a Frenkel-Holstein exciton model and Monte Carlo hopping simulation is applied. This novel approach captures exciton transport properties of polymer systems with a monomer-level of detail unachievable with continuum or lattice style models, but at a large scale infeasible with fully quantum calculations. Reasonable quantitative agreement with experimental observables is obtained, offering insight into the morphology-dependence of exciton transport in conjugated polymers. In particular, the observed tendency for exciton migration to the core of the polymer aggregate can explain the relatively poor performance of highly crystalline or nanofibre-based polymer solar cells, as well as the unusually high fluorescence yield of aqueous P3HT nanoparticles. The effect of disorder in small molecule semiconductor films is investigated in Chapter 5 in the context of singlet exciton fission and triplet fusion under the influence of applied magnetic fields. A model is presented that extends the historical theory of molecular spin interactions in crystalline materials and corrects the current understanding in the literature regarding such disordered solid-phase systems. The possibility of using the fluorescence response to magnetic fields to probe the morphology and degree disorder in the films is demonstrated. Extending the model to solution-phase behaviour is then discussed in Chapter 6, where the potential of improving the light-harvesting ability of solar cells through a molecular triplet-triplet annihilation upconversion process is considered. Molecular dynamics simulations are used to obtain physical parameters and collision geometry of the emitter molecules in solution. The complications of applying a static model of triplet fusion to the dynamic solution-phase behaviour are elucidated and the potential of synthesising an ideal upconversion emitter molecule is discussed.
To aid the design of organic semiconductors, we study the charge transport properties of organic liquid crystals and single crystals. The aim is to find structure-property relationships linking the chemical structure as well as the morphology with the bulk charge carrier mobility of the compounds. To this end, molecular dynamics (MD) simulations are performed yielding realistic equilibrated morphologies. Partial charges and molecular orbitals are calculated using quantum chemical methods. The molecular orbitals are then mapped onto the molecular positions and orientations, which allows calculation of the transfer integrals between nearest neighbors using the molecular orbital overlap method. Thus realistic transfer integral distributions and their autocorrelations are obtained. In case of organic crystals two descriptions of charge transport, namely semi-classical dynamics (SCD) and kinetic Monte Carlo (KMC) based on Marcus rates, are studied. In KMC one assumes that the wave function is localized on one molecule, while in SCD it is spread over a limited number of neighboring molecules. The results are compared amongst each other and, where available, with experimental data.
The field of charge conduction in disordered materials is a rapidly evolving area owing to current and potential applications of these materials in various electronic devices This text aims to cover conduction in disordered solids from fundamental physical principles and theories, through practical material development with an emphasis on applications in all areas of electronic materials. International group of contributors Presents basic physical concepts developed in this field in recent years in a uniform manner Brings up-to-date, in a one-stop source, a key evolving area in the field of electronic materials
Great progress has been made in the field of ordinary semiconductor physics and associated technologies. For the time being, if we could use new materials such as organic semiconductors progress in electronics could be accelerated. Characteristics of organic semiconductors that are superior to others are: i) high photo-conductivity under irradiation along with low leakage current in the dark, ii) high sensitivity of the conductivity to various gases and to pressure. iii) possibility of using them in the amorphous state, iv) possibility of making devices of extremely small size, v) large variety of the materials, which makes suitable choice of material component easy. A possible future development is a highly conductive material which could be used for electric power transmission - and which might help solve some of the problems posed by transmission losses. The U.S.-Japan Seminar on Energy and Charge Transfer in Organic Semiconductors was held in Osaka Japan, 6-9 August, 1973. Completed results were summarized and the direction for the future was discussed. Information was exchanged quite freely and actively in a pleasant atmosphere. Many of the papers presented at the seminar are published here but unfortunately a few could not be included. It would give us great pleasure if this seminar could be one step in the further development of the research in this field.
To aid the design of organic semiconductors, we study the charge transport properties of organic liquid crystals, i.e. hexabenzocoronene and carbazole macrocycle, and single crystals, i.e. rubrene, indolocarbazole and benzothiophene derivatives (BTBT, BBBT). The aim is to find structure-property relationships linking the chemical structure as well as the morphology with the bulk charge carrier mobility of the compounds. To this end, molecular dynamics (MD) simulations are performed yielding realistic equilibrated morphologies. Partial charges and molecular orbitals are calculated based on single molecules in vacuum using quantum chemical methods. The molecular orbitals are then mapped onto the molecular positions and orientations, which allows calculation of the transfer integrals between nearest neighbors using the molecular orbital overlap method. Thus we obtain realistic transfer integral distributions and their autocorrelations. In case of organic crystals the differences between two descriptions of charge transport, namely semi-classical dynamics (SCD) in the small polaron limit and kinetic Monte Carlo (KMC) based on Marcus rates, are studied. The liquid crystals are investigated solely in the hopping limit. To simulate the charge dynamics using KMC, the centers of mass of the molecules are mapped onto lattice sites and the transfer integrals are used to compute the hopping rates. In the small polaron limit, where the electronic wave function is spread over a limited number of neighboring molecules, the Schroedinger equation is solved numerically using a semi-classical approach. The results are compared for the different compounds and methods and, where available, with experimental data. The carbazole macrocycles form columnar structures arranged on a hexagonal lattice with side chains facing inwards, so columns can closely approach each other allowing inter-columnar and thus three-dimensional transport. When taking only intra-columnar transport into account, t.
The school held at Villa Marigola, Lerici, Italy, in July 1997 was very much an educational experiment aimed not just at teaching a new generation of students the latest developments in computer simulation methods and theory, but also at bringing together researchers from the condensed matter computer simulation community, the biophysical chemistry community and the quantum dynamics community to confront the shared problem: the development of methods to treat the dynamics of quantum condensed phase systems.This volume collects the lectures delivered there. Due to the focus of the school, the contributions divide along natural lines into two broad groups: (1) the most sophisticated forms of the art of computer simulation, including biased phase space sampling schemes, methods which address the multiplicity of time scales in condensed phase problems, and static equilibrium methods for treating quantum systems; (2) the contributions on quantum dynamics, including methods for mixing quantum and classical dynamics in condensed phase simulations and methods capable of treating all degrees of freedom quantum-mechanically.
Like its predecessor this book is devoted to the materials, manufacturing and applications aspects of organic thin-film transistors. Once again authored by the most renowned experts from this fascinating and fast-moving area of research, it offers a joint perspective both broad and in-depth on the latest developments in the areas of materials chemistry, transport physics, materials characterization, manufacturing technology, and circuit integration of organic transistors. With its many figures and detailed index, this book once again also serves as a ready reference.