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A multi-disciplinary, multi-industry overview of microbiologically influenced corrosion, with strategies for diagnosis and control or prevention Microbiologically Influenced Corrosion helps engineers and scientists understand and combat the costly failures that occur due to microbiologically influenced corrosion (MIC). This book combines recent findings from diverse disciplines into one comprehensive reference. Complete with case histories from a variety of environments, it covers: Biofilm formation Causative organisms, relating bacteria and fungi to corrosion mechanisms for groups of metals Diagnosing and monitoring MIC Electrochemical techniques, with an overview of methods for detection of MIC The impact of alloying elements, including antimicrobial metals, and design features on MIC MIC of non-metallics Strategies for control or prevention of MIC, including engineering, chemical, and biological approaches This is a valuable, all-inclusive reference for corrosion scientists, engineers, and researchers, as well as designers, managers, and operators.
Failure Analysis of Microbiologically Influenced Corrosion serves as a complete guide to corrosion failure analysis with an emphasis on the diagnosis of microbiologically influenced corrosion (MIC). By applying the principles of chemistry, microbiology, and metallurgy, readers will be able to reliably determine the mechanistic cause of corrosion damage and failures and select the appropriate methods for mitigating future corrosion incidents. FEATURES Provides background information on the forensic process, types of data or evidence needed to perform the analysis, industrial case studies, details on the MIC failure analysis process, and protocols for field and lab use Presents up-to-date advances in molecular technologies and their application to corrosion failure investigations Offers specific guidelines for conducting MIC failure analyses and case studies to illustrate their application Examines state-of-the-art information on MIC analytical tools and methods With authors with expertise in microbiology, corrosion, materials, and failure investigation, this book provides tools for engineers, scientists, and technologists to successfully combat MIC issues.
Microbiologically influenced corrosion (MIC) is a difficult degradation mechanism to diagnose in pipeline systems due to the complex interaction between biotic (i.e., microbial) and abiotic (e.g., fluid chemistry, pipe/vessel metallurgy/corrosion, and operating conditions) factors. This complexity often makes it difficult to accurately assess pipeline failures due to MIC. However, even with available data, failure investigators often face a number of challenges in diagnosing MIC such as how to properly integrate the available datasets, questions regarding data accuracy (e.g., confidence in the sampling and/or analysis method used) and lack of available information from operators (e.g., missing data). As a result, practical MIC failure assessments are most often performed by experts or specialists with significant knowledge and working experience in this topic. Based on these issues, the objectives of this thesis are three-fold: 1) to quantify the actual prevalence of MIC related pipeline failures in Alberta's oil and gas sector, 2) to perform a gap analysis of failure investigation methods used to assess these pipeline failures, and 3) to develop a novel expert system based on machine learning to assist both experts and non-experts in assessing potential MIC related pipeline failures. The first part of this study highlights a review and analysis of MIC related pipeline incidents in the province of Alberta, Canada over a three-year period (2017-2019). This review was used to quantify the occurrence of MIC failures relative to other corrosion mechanisms, and to conduct a gap analysis of MIC failure investigation techniques being used relative to the current state of the art. Over this three-year period, MIC was found to be responsible for 13.6% and 4.8% of all pipeline leak incidents due to internal and external corrosion, respectively (either as the main failure mechanism or as a contributing factor). Most of these failures were seen to occur in small diameter upstream pipelines (with less than or equal to 220.3 mm outside diameter) carrying mainly multiphase fluids (oil-water emulsions) or produced water. In terms of the failure investigation methods currently being used, it was noted that there was some inconsistency among reports and a number of important gaps were identified. Various assessments lacked microbiological test data, in particular, tests which specifically identify microbial functional groups or speciation, which is critical to confirm observed corrosion mechanisms. Furthermore, a number of these assessments identified MIC primarily on the basis of corrosion morphology, which has been shown to be an incorrect assumption and approach without additional evidence. Details related to sampling methods were also lacking in these assessments, which created some uncertainty as to the quality of data obtained. Overall, most assessments did a reasonable job in characterizing and including chemical (solids, fluids, and corrosion products), metallurgical/ corrosion, and operating data. However, the integration of these various layers of evidence (i.e., connecting corrosion to microbiological activity, and eliminating possible abiotic corrosion mechanisms) was missing in many reports. The second part of this study highlights the modeling of an expert system for the classification of internal microbiologically influenced corrosion (MIC) failures related to pipelines in the upstream oil and gas industry. The model is based on machine learning (artificial neural network) and involves the participation of 15 MIC subject matter experts (SMEs). Each expert evaluated a number of model case studies representative of both MIC and non-MIC related upstream pipeline failures. The model accounts for variations in microbiological testing methods, microbiological sample types, degradation morphology, among others, and also incorporates cases with select missing datasets which is commonly found in actual failure assessments. The output classifications comprised elements of both potential for MIC and confidence in the data available. The results were contrasted for 5- and 3-output classification models (5OC and 3OC, respectively). The 5OC model had an overall accuracy of 62.0% while the simpler 3OC model had a better accuracy of 74.8%. This modelling exercise has demonstrated that knowledge from subject matter experts can be captured in a reasonably effective model to screen for possible MIC failures. It is hoped that this study contributes to a better understanding of the prevalence of MIC in the oil and gas sector, and highlights the key areas necessary to improve the diagnosis of MIC failures in the future.
Microorganisms are ubiquitously present in petroleum reservoirs and the facilities that produce them. Pipelines, vessels, and other equipment used in upstream oil and gas operations provide a vast and predominantly anoxic environment for microorganisms to thrive. The biggest technical challenge resulting from microbial activity in these engineered environments is the impact on materials integrity. Oilfield microorganisms can affect materials integrity profoundly through a multitude of elusive (bio)chemical mechanisms, collectively referred to as microbiologically influenced corrosion (MIC). MIC is estimated to account for 20 to 30% of all corrosion-related costs in the oil and gas industry. This book is intended as a comprehensive reference for integrity engineers, production chemists, oilfield microbiologists, and scientists working in the field of petroleum microbiology or corrosion. Exhaustively researched by leaders from both industry and academia, this book discusses the latest technological and scientific advances as well as relevant case studies to convey to readers an understanding of MIC and its effective management.
Significantly extended from the first edition, this book presents the basics of microbiologically influenced corrosion (MIC) in an accessible and concise manner. It explores strategies for recognizing, understanding, mitigating and preventing this type of corrosion, and investigates this topic from the point of view of an engineer. Chapters cover issues including stress corrosion cracking and microbial corrosion, the pros and cons of biocides, the involvement of magnetic bacteria in microbial corrosion, and cathodic protection based on recent research in microbial environments. The 2nd Edition provides new material examining the following topics: *The corrosion-related bacteria clostridia *Mathematical modelling of MIC, in particular fuzzy logic *A comparison of culture-independent methods with culture-dependent methods *Further practical strategies for dealing with MIC *Natural biocidesThis book has provided course material for the author’s microbial corrosion workshops around the world, and it presents an invaluable resource to corrosion and integrity professionals working in a wide range of industries including power generation, oil and gas, marine, and mining. It is also intended for students and academics of corrosion engineering, materials science, microbiology, chemical engineering and welding.
Microorganisms can be both beneficial and harmful to the oil and gas industry and therefore there is an increasing need for the oil industry to characterize, quantify and monitor microbial communities in real time. Oilfield Microbiology offers a fundamental insight into how molecular microbiological methods have enabled researchers in the field to analyze and quantify in situ microbial communities and their activities in response to changing environmental conditions. Such information is fundamental to the oil industry to employ more directed, cost-effective strategies to prevent the major problems associated with deleterious microbial activities (e.g., souring and biocorrosion), as well as to encourage beneficial microbe activity (e.g. oil bioremediation). The aim of the book is to understand how the technological advances in molecular microbiological methods over the last two decades are now being utilized by the oil industry to address the key issues faced by the sector. This book contains a comprehensive collection of chapters written by invited experts in the field from academia and industry and provides a solid foundation of the importance of microbes to the oil and gas industry. It is aimed at microbial ecologists, molecular biologists, operators, engineers, chemists, and academics involved in the sector.
This four-volume reference work builds upon the success of past editions of Elsevier’s Corrosion title (by Shreir, Jarman, and Burstein), covering the range of innovations and applications that have emerged in the years since its publication. Developed in partnership with experts from the Corrosion and Protection Centre at the University of Manchester, Shreir’s Corrosion meets the research and productivity needs of engineers, consultants, and researchers alike. Incorporates coverage of all aspects of the corrosion phenomenon, from the science behind corrosion of metallic and non-metallic materials in liquids and gases to the management of corrosion in specific industries and applications Features cutting-edge topics such as medical applications, metal matrix composites, and corrosion modeling Covers the benefits and limitations of techniques from scanning probes to electrochemical noise and impedance spectroscopy
The overall program objective is to develop and evaluate environmentally benign agents or products that are effective in the prevention, inhibition, and mitigation of microbially influenced corrosion (MIC) in the internal surfaces of metallic natural gas pipelines. The goal is to develop one or more environmentally benign (a.k.a. ''green'') products that can be applied to maintain the structure and dependability of the natural gas infrastructure. The technical approach for this quarter includes the application of new methods of Capsicum sp. (pepper) extraction by soxhlet method and analysis of a new set of extracts by thin layer chromatography (TLC) and high performance liquid chromatography (HPLC); isolation and cultivation of MIC-causing microorganisms from corroded pipeline samples; and evaluation of antimicrobial activities of the old set of pepper extracts in comparison with major components of known biocides and corrosion inhibitors. Twelve new extracts from three varieties of Capsicum sp. (Serrano, Habanero, and Chile de Arbol) were obtained by soxhlet extraction using 4 different solvents. Results of TLC done on these extracts showed the presence of capsaicin and some phenolic compounds, while that of HPLC detected capsaicin and dihydrocapsaicin peaks. More tests will be done to determine specific components. Additional isolates from the group of heterotrophic, acid-producing, denitrifying and sulfate-reducing bacteria were obtained from the pipeline samples submitted by gas companies. Isolates of interest will be used in subsequent antimicrobial testing and test-loop simulation system experiments. Results of antimicrobial screening of Capsicum sp. extracts and components of known commercial biocides showed comparable activities when tested against two strains of sulfate-reducing bacteria.