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Coordination polymer is a general term used to indicate an infinite array composed of metal ions which are bridged by certain ligands among them. This incorporates a wide range of architectures including simple one-dimensional chains with small ligands to large mesoporous frameworks. Generally, the formation process proceeds automatically and, therefore, is called a self-assembly process. In general, the type and topology of the product generated from the self-assembly of inorganic metal nodes and organic spacers depend on the functionality of the ligand and valences and the geometric needs of the metal ions used. In this book the authors explain main group metal coordination polymer in bulk and nano size with some of their application, synthesis method and etc, The properties of these efficient materials are described at length including magnetism (long-range ordering, spin crossover), porosity (gas storage, ion and guest exchange), non-linear optical activity, chiral networks, reactive networks, heterogeneous catalysis, luminescence, multifunctional materials and other properties.
Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.
The contributors to this book discuss inorganic synthesis reactions, dealing with inorganic synthesis and preparative chemistry under specific conditions. They go on to describe the synthesis, preparation and assembly of six important categories of compounds with wide coverage of distinct synthetic chemistry systems
Metal–organic frameworks (MOFs) are porous crystalline polymers con­structed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable mor­phology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community. This breakthrough new volume aims to explore down-to-earth applications in fields such as bio­medical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strate­gies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must-have for any library.
Data on the synthesis and physicochemical studies of salts of mono- or dibasic unsaturated carboxylic acids and macromolecular metal carboxylates are generalised and described systematically in this monograph. The structures and properties of the COO group in various compounds and characteristic features of the structures of carboxylate are analysed. The main routes and kinetics of polymerisation transformations of unsaturated metal carboxylates are considered. The attention is focused on the effect of the metal ion on the monomer reactivity and the polymer morphology and structure. The possibility of stereochemical control of radical polymerisation of unsaturated metal carboxylates is demonstrated. The electronic, magnetic, optical, absorption and thermal properties of metal (co)polymers and nanocomposites and their main applications are also considered.
Electrochemistry affects several relevant research subjects of physics, chemistry and biology such as the transformation of materials, the transfer of information (especially in living systems), or the conversion and storage of energy. In addition, electrochemical processes constitute a major class of chemical reactions both in the laboratory and on large industrial scales. While conventional analytical electrochemistry provides excellent methods to determine concentrations (e.g. in sensor technology), to yield energy data in the form of redox potentials and to elucidate formal reaction mechanisms via kinetic analysis, these techniques alone are often not immediately suitable to identify unknown species which are formed as intermediates or as products in a redox reaction. The combination of reaction-oriented electrochemistry with species-focussed spectroscopy in spectroelectrochemistry can solve this problem and thus allow for a more complete analysis of electron transfer processes and complex redox reactions. Many research groups from various sub-fields of the chemical sciences have engaged in recent years in using and developing this combined methodology. While the technique has been well developed during the last few decades, its application in various fields of chemistry has only recently become more widespread. Readily accessible, inexpensive equipment and lower barriers to application have contributed to this situation and, at the same time, it is becoming less and less acceptable in chemical research to assign redox transformations without spectral evidence. Spectroelectrochemistry has therefore evolved as a powerful yet usually inexpensive technique which yields mechanistic (chemistry), energy-relevant (electro) as well as electronic structure information (spectro). The whole range of the electromagnetic spectrum can be employed from x-ray absorption to NMR spectroscopies. Yet while the method has become more commonplace, there are still aspects to be considered which require sound knowledge and experience. This book serves as a guide and as an illustration of the kind of research where spectroelectrochemistry can make a difference in the understanding of redox reactions through identification of their intermediates and products. Relevant examples involving UV-VIS-NIR and IR absorption spectroscopy as well as electron paramagnetic resonance (EPR) are presented in this book with the objective to illustrate the potential and the applications of this technique and to provide practical information. The topics covered include: " organometallics " coordination compounds (mixed-valent complexes, metalloporphyrins) " compounds of biochemical interest such as iron-containing proteins The breadth and variety of reactions and materials covered are complemented by the straightforward interpretation of results in the understanding of redox reactions. The solutions available from the spectroelectrochemical investigation in the book do not only provide simultaneous reaction analysis and species identification but also an assessment of electronic situations and of intra- and intermolecular electron transfer. The book aims to familiarise the scientific community with this method by describing the experimental approaches possible and by pointing out under what diverse circumstances this technique can be useful. This book is essential reading for experts and newcomers alike to acquaint themselves with this simple, inexpensive, yet powerful method and it will also appeal to scientists from all chemical sub-fields who have a basic understanding and experience in electrochemistry.
Research on metal-containing liquid crystals is a rapidly expanding, multidisciplinary field with new materials continually being synthesized and novel applications being developed. 'Metallomesogens' is the first comprehensive survey of the field, introducing the reader to: * materials design * synthesis * physical properties * emerging applications Carefully selected references round off this well-organized compendium. It is an indispensable guide to experienced researchers in coordination and organometallic chemistry as well as in liquid-crystal and materials science. Newcomers and graduate students will also benefit from this didactically sound introduction to the field.
Providing vital knowledge on the design and synthesis of specific metal-organic framework (MOF) classes as well as their properties, this ready reference summarizes the state of the art in chemistry. Divided into four parts, the first begins with a basic introduction to typical cluster units or coordination geometries and provides examples of recent and advanced MOF structures and applications typical for the respective class. Part II covers recent progress in linker chemistries, while special MOF classes and morphology design are described in Part III. The fourth part deals with advanced characterization techniques, such as NMR, in situ studies, and modelling. A final unique feature is the inclusion of data sheets of commercially available MOFs in the appendix, enabling experts and newcomers to the field to select the appropriate MOF for a desired application. A must-have reference for chemists, materials scientists, and engineers in academia and industry working in the field of catalysis, gas and water purification, energy storage, separation, and sensors.
Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn't require organic solvents), with special attention paid to 'greener' methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. - Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more - Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water - Includes experimental procedures, with examples of direct synthesis, at the end of each chapter
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