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Advances in Organometallic Chemistry, Volume 69, contains authoritative review articles of world renowned researchers in the field of organometallic chemistry. This longstanding serial is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more, with this release focusing on topics such as C-H Activation Mediated by Main Group Inorganic and Organometallic Compounds, Transition-metals catalyzed intramolecular amination and hydroamination reactions of allenes, Green Fluorescent Protein-like and related organometallic fluorophores, Recent advances in the synthesis of C- S- bonds via metal-catalyzed functionalization of C- H- bonds, Current mechanistic understanding of Co-catalyzed C-H functionalization, and more. The book is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. - Contains contributions from leading authorities in the field of organometallic chemistry - Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more - Informs and updates readers on the latest developments in the field - Carefully edited to provide easy-to-read material
Written by world-class authors, this most recent major book on the topic highlights new and current trends as well as future directions. It is comprehensive in its scope, covering all aspects of gold chemistry -- from homogeneous to heterogeneous catalysis, from supramolecular assemblies to sensors and medicinal applications. The result is an invaluable work for both organic and inorganic chemists working in universities and industry, as well as material scientists.
Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium. Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers.
Chemical Modelling covers a wide range of disciplines and is the first stop for any materials scientist, biochemist, chemist or molecular physicist wishing to acquaint themselves with major developments and current opinion in the applications and theory of chemical modelling.
With contribution by numerous experts
Filling a gap in our systematic knowledge of gold, this monograph covers the fundamental aspects, while also considering new applications of gold compounds in catalysis, as nanoparticles, and their potential application as luminescent compounds. Written by an eminent team of authors from academia, the book analyzes the current status of gold chemistry, its special characteristics, oxidation states and main type of complexes, before going on to look at the synthesis of supramolecular aggregates due to the formation of gold-gold, gold-metal interactions or other secondary bonds. Final sections deal with LEDs, solvoluminescent and electroluminescent materials, liquid crystals and catalysis. While of interest to advanced chemistry students, this book is also useful for researchers interested in the chemistry of gold and its applications, as well as those involved in metal-metal interactions, heteronuclear chemistry or in the optical properties of coordination compounds.
This book is intended to offer the reader a snapshot of the field of optoelectronic materials from the viewpoint of inorganic chemists. The field of inorganic chemistry is transforming from one focused on the synthesis of compounds having interesting coordination numbers, structures, and stereochemistries, to one focused on preparing compounds that have potentially useful practical applica tions. Two such applications are in the area of optics and electronics. These are fields where the use of inorganic materials has a long history. As the field of microelectronics develops the demands on the performance of such materials increases, and it becomes necessary to discover compounds that will meet these demands. The field of optoelectronics represents a merging of the two disciplines. Its emergence is a natural one because many of the applications involve both of these properties, and also because the electronic structure of a metal compound that confers novel optical properties is often one that also influences its electron transfer and conductivity characteristics. Two of the more important growth areas that have led to these developments are communications and medicine. Within the communications field there is the microelectronics that is involved in information storage and transmittal, some of which will be transferred into the optical regime. Within the medical field there are chemical probes that transmit analytical information from an in vivo environment. This information needs to be readily accessible from an external site, and then quickly converted into images or data that yield accurate and inexpensive diagnoses.
This book reports the basics of hybrid phosphor materials, their synthesis routes and their special properties and characterization techniques. It gives the reader information about the natural origins and development of hybrid materials, which are developed by combining inorganic and organic species in one material interface-determined materials. The book provides a general classification of hybrid materials, wherein inorganic materials modified by organic moieties are distinguished from organic materials or matrices modified by inorganic constituents. It gives a focus to the functionalization of organic materials by inorganic additives. The application areas covered include optoelectronic field, sensor applications, biological and environmental applications.
Although it has long been possible to make organic materials emit light, it has only recently become possible to do so at the level and with the efficiency and control necessary to make the materials a useful basis for illumination or displays. The early electroluminescent devices provided reasonably bright light, but required high operating voltages, produced only a narrow range of colors, and had severely limited lifetimes. Recent developments, however, make it possible to manufacture organic light-emitting devices that are thin, bright, efficient, and stable and that produce a broad range of colors. This book surveys the current status of the field. It begins with an overview of the physics and chemistry of organic light emitting devices by J. Shinar and V. Savvateev. Subsequenbt chapters discuss the design of molecular materials for high performance devices (C. Adachi and T. Tsutsui) and chemical degradation and physical aging (K. Higginson, D. L. Thomsen, B. Yang, and F. Papadimitrakopoulos). A. Dodabalapur describes microcavity OLEDs, and Y. Shi, J. Liu, and Y. Yang discuss polymer morphology and device performance. Various aspects of devices based on polyparaphenylene vinylenes are discussed in chapters by N.C. Greenham and R.H. Friend and by H. Chayet, V. Savvateeyv, D. Davidov and R. Neumann. Chapters by S. Tasch, W. Graupner, and G. Leising and by Y. Z. Wang, D. Gebler, and A. J. Epstein describe OLEDs based on poly(paraphenylene) and poly(pyridine), respectively. The book concludes with a chapter on polyfluorene-based devices, which show great promise for producing light in all colors from blue to red.