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Design and Operation of Solid Oxide Fuel Cells: The Systems Engineering Vision for Industrial Application presents a comprehensive, critical and accessible review of the latest research in the field of solid oxide fuel cells (SOFCs). As well as discussing the theoretical aspects of the field, the book explores a diverse range of power applications, such as hybrid power plants, polygeneration, distributed electricity generation, energy storage and waste management—all with a focus on modeling and computational skills. Dr. Sharifzadeh presents the associated risks and limitations throughout the discussion, providing a very complete and thorough analysis of SOFCs and their control and operation in power plants. The first of its kind, this book will be of particular interest to energy engineers, industry experts and academic researchers in the energy, power and transportation industries, as well as those working and researching in the chemical, environmental and material sectors. - Closes the gap between various power engineering disciples by considering a diverse variety of applications and sectors - Presents and reviews a variety of modeling techniques and considers regulations throughout - Includes CFD modeling examples and process simulation and optimization programming guidance
High Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications provides a comprehensive discussion of solid oxide fuel cells (SOFCs). SOFCs are the most efficient devices for the electrochemical conversion of chemical energy of hydrocarbon fuels into electricity, and have been gaining increasing attention for clean and efficient distributed power generation. The book explains the operating principle, cell component materials, cell and stack designs and fabrication processes, cell and stack performance, and applications of SOFCs. Individual chapters are written by internationally renowned authors in their respective fields, and the text is supplemented by a large number of references for further information. The book is primarily intended for use by researchers, engineers, and other technical people working in the field of SOFCs. Even though the technology is advancing at a very rapid pace, the information contained in most of the chapters is fundamental enough for the book to be useful even as a text for SOFC technology at the graduate level.
High-temperature Solid Oxide Fuel Cells, Second Edition, explores the growing interest in fuel cells as a sustainable source of energy. The text brings the topic of green energy front and center, illustrating the need for new books that provide comprehensive and practical information on specific types of fuel cells and their applications. This landmark volume on solid oxide fuel cells contains contributions from experts of international repute, and provides a single source of the latest knowledge on this topic. - A single source for all the latest information on solid oxide fuel cells and their applications - Illustrates the need for new, more comprehensive books and study on the topic - Explores the growing interest in fuel cells as viable, sustainable sources of energy
The book summarizes the current state of the solid oxide fuel cell (SOFC) technology in power generation applications. It describes the single cells, SOFC stacks, micro-combined heat and power systems, large-scale stationary power generators and polygeneration units. The principles of modeling, simulation and controls of power systems with solid oxide fuel cells are presented and discussed. Authors provide theoretical background of the technology followed by the essential insights into the integrated power systems. Selected aspects of the design, construction and operation of power units in range from single kilowatts to hundreds of kilowatts are presented. Finally, the book reports the selected studies on prototype systems which have been constructed in Europe. The book discusses the theoretical and practical aspects of operation of power generators with solid oxide fuel cells including fabrication of cells, design of stacks, system modeling, simulation of stationary and non-stationary operation of systems, fuel preparation and controls.
Fuel cells are widely regarded as the future of the power and transportation industries. Intensive research in this area now requires new methods of fuel cell operation modeling and cell design. Typical mathematical models are based on the physical process description of fuel cells and require a detailed knowledge of the microscopic properties that govern both chemical and electrochemical reactions. Advanced Methods of Solid Oxide Fuel Cell Modeling proposes the alternative methodology of generalized artificial neural networks (ANN) solid oxide fuel cell (SOFC) modeling. Advanced Methods of Solid Oxide Fuel Cell Modeling provides a comprehensive description of modern fuel cell theory and a guide to the mathematical modeling of SOFCs, with particular emphasis on the use of ANNs. Up to now, most of the equations involved in SOFC models have required the addition of numerous factors that are difficult to determine. The artificial neural network (ANN) can be applied to simulate an object’s behavior without an algorithmic solution, merely by utilizing available experimental data. The ANN methodology discussed in Advanced Methods of Solid Oxide Fuel Cell Modeling can be used by both researchers and professionals to optimize SOFC design. Readers will have access to detailed material on universal fuel cell modeling and design process optimization, and will also be able to discover comprehensive information on fuel cells and artificial intelligence theory.
High temperature solid oxide fuel cell (SOFC) technology is a promising power generation option that features high electrical efficiency and low emissions of environmentally polluting gases such as CO2, NOox and SOx. It is ideal for distributed stationary power generation applications where both high-efficiency electricity and high-quality heat are in strong demand. For the past few decades, SOFC technology has attracted intense worldwide R&D effort and, along with polymer electrolyte membrane fuel cell (PEMFC) technology, has undergone extensive commercialization development.This book presents a systematic and in-depth narrative of the technology from the perspective of fundamentals, providing comprehensive theoretical analysis and innovative characterization techniques for SOFC technology. The book initially deals with the basics and development of SOFC technology from cell materials to fundamental thermodynamics, electronic properties of solids and charged particle transport. This coverage is extended with a thorough analysis of such operational features as current flow and energy balance, and on to voltage losses and electrical efficiency. Furthermore, the book also covers the important issues of fuel cell stability and durability with chapters on performance characterization, fuel processing, and electrode poisoning. Finally, the book provides a comprehensive review for SOFC materials and fabrication techniques. A series of useful scientific appendices rounds off the book.Solid oxide fuel cell technology is a standard reference for all those researching this important field as well as those working in the power industry. - Provides a comprehensive review of solid oxide fuel cells from history and design to chemistry and materials development - Presents analysis of operational features including current flow, energy balance, voltage losses and electrical efficiency - Explores fuel cell stability and durability with specific chapters examining performance characterization, fuel processing and electrode poisoning
This book fills the need for a practical reference for all scientists and graduate students who are seeking to define a mathematical model for Solid Oxide Fuel Cell (SOFC) simulation. Structured in two parts, part one presents the basic theory, and the general equations describing SOFC operation phenomena. Part two deals with the application of the theory to practical examples, where different SOFC geometries, configurations, and different phenomena are analyzed in detail.
This book covers all the proposed fuel cell systems including PEMFC, SOFC, PAFC, MCFC, regenerative fuel cells, direct alcohol fuel cells, and small fuel cells to replace batteries.
Intermediate Temperature Solid Oxide Fuel Cells: Electrolytes, Electrodes and Interconnects introduces the fundamental principles of intermediate solid oxide fuel cells technology. It provides the reader with a broad understanding and practical knowledge of the electrodes, pyrochlore/perovskite/oxide electrolytes and interconnects which form the backbone of the Solid Oxide Fuel Cell (SOFC) unit. Opening with an introduction to the thermodynamics, physiochemical and electrochemical behavior of Solid Oxide Fuel Cells (SOFC), the book also discusses specific materials, including low temperature brownmillerites and aurivillius electrolytes, as well as pyrochlore interconnects. This book analyzes the basic concepts, providing cutting-edge information for both researchers and students. It is a complete reference for Intermediate Solid Oxide Fuel Cells technology that will be a vital resource for those working in materials science, fuel cells and solid state chemistry. - Provides a single source of information on glass, electrolytes, interconnects, vanadates, pyrochlores and perovskite SOFC - Includes illustrations that provide a clear visual explanation of concepts being discussed - Progresses from a discussion of basic concepts that will enable readers to easily comprehend the subject matter
A comprehensive guide to the modelling and design of solid oxide fuel cell hybrid power plants This book explores all technical aspects of solid oxide fuel cell (SOFC) hybrid systems and proposes solutions to a range of technical problems that can arise from component integration. Following a general introduction to the state-of-the-art in SOFC hybrid systems, the authors focus on fuel cell technology, including the components required to operate with standard fuels. Micro-gas turbine (mGT) technology for hybrid systems is discussed, with special attention given to issues related to the coupling of SOFCs with mGTs. Throughout the book emphasis is placed on dynamic issues, including control systems used to avoid risk conditions. With an eye to mitigating the high costs and risks incurred with the building and use of prototype hybrid systems, the authors demonstrate a proven, economically feasible approach to obtaining important experimental results using simplified plants that simulate both generic and detailed system-level behaviour using emulators. Computational models and experimental plants are developed to support the analysis of SOFC hybrid systems, including models appropriate for design, development and performance analysis at both component and system levels. Presents models for a range of size units, technology variations, unit coupling dynamics and start-up and shutdown behaviours Focuses on SOFCs integration with mGTs in light of key constraints and risk avoidance issues under steady-state conditions and during transient operations Identifies interaction and coupling problems within the GT/SOFC environment, including exergy analysis and optimization Demonstrates an economical approach to obtaining important experimental results while avoiding high-cost components and risk conditions Presents analytical/computational and experimental tools for the efficient design and development of hardware and software systems Hybrid Systems Based on Solid Oxide Fuel Cells: Modelling and Design is a valuable resource for researchers and practicing engineers involved in fuel cell fundamentals, design and development. It is also an excellent reference for academic researchers and advanced-level students exploring fuel cell technology.