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Since the discovery that polymer single crystals are composed of chain folded macromolecules in 1957, the crystallization of polymers has attracted considerable interest and still provides fascinating and fruitful areas of research. Only a few books have been fully devoted to the crystallization of polymers in the past. This book contains the proceedings of the NATO ARW devoted to the `Crystallization of Polymers' which took place in September 1992 at the University of Mons-Hainaut (Belgium). In view of the variety of papers devoted to the crystallization of polymers, this book will be used in the next few years as a reference book for scientists concerned in the field of polymer physical chemistry. Crystallization of Polymers is mainly devoted to the experimental and theoretical study of the crystallization of synthetic polymers. As a kinetic study of the growth of polymer crystals should always be preceded by a morphological or a structural investigation, the structure, the morphology of polymer crystals and more particularly the lamellar and supralamellar organizations, as well as the nature of the crystal amorphous interface are reviewed and discussed.
Crystallization is a natural occurring process but also a process abundantly used in the industry. Crystallization can occur from a solution, from the melt or via deposition of material from the gas phase (desublimation). Crystals distinguish themself from liquids, gases and amorphous substances by the long-range order of its building blocks that entail the crystals to be formed of well-defined faces, and give rise to a large number of properties of the solid. Crystallization is used at some stage in nearly all process industries as a method of production, purification or recovery of solid materials. Crystallization is practiced on all scales: from the isolation of the first milligrams of a newly synthesized substance in the research laboratory to isolating products on the mulit-million tonne scale in industry. The book describes the breadth of crystallization operations, from isolation from a reaction broth to purification and finally to tailoring product properties. In the first section of the book, the basic mechanisms - nucleation, growth, attrition and agglomeration are introduced. It ensures an understanding of supersaturation, the driving force of crystallization. Furthermore, the solubility of the substance and its dependences on process conditions and the various techniques of crystallization and their possibilities and limitations are discussed. Last but not least, the first part includes an intensive treatment of polymorphism . The second part builds on the basics, exploring how crystallization processes can be developed, either batch-wise or continuous, from solution or from the melt. A discussion of the purification during crystallization serves as a link between the two sections, where practical aspects and an insight using theoretical concepts are combined. Mixing and its influence on the crystallization as well as the mutual interference of down-stream processes with the crystallization are also treated. Finally, techniques to characterize the crop are discussed. The third part of the book is dedicated to accounts of actual developments and of carried-out crystallizations. Typical pitfalls and strategies to avoid these as well as the design of robust processes are presented.
Crystallization is a natural occurring process but also a process abundantly used in the industry. Crystallization can occur from a solution, from the melt or via deposition of material from the gas phase (desublimation). Crystals distinguish themself from liquids, gases and amorphous substances by the long-range order of its building blocks that entail the crystals to be formed of well-defined faces, and give rise to a large number of properties of the solid. Crystallization is used at some stage in nearly all process industries as a method of production, purification or recovery of solid materials. Crystallization is practiced on all scales: from the isolation of the first milligrams of a newly synthesized substance in the research laboratory to isolating products on the mulit-million tonne scale in industry. The book describes the breadth of crystallization operations, from isolation from a reaction broth to purification and finally to tailoring product properties. In the first section of the book, the basic mechanisms - nucleation, growth, attrition and agglomeration are introduced. It ensures an understanding of supersaturation, the driving force of crystallization. Furthermore, the solubility of the substance and its dependences on process conditions and the various techniques of crystallization and their possibilities and limitations are discussed. Last but not least, the first part includes an intensive treatment of polymorphism . The second part builds on the basics, exploring how crystallization processes can be developed, either batch-wise or continuous, from solution or from the melt. A discussion of the purification during crystallization serves as a link between the two sections, where practical aspects and an insight using theoretical concepts are combined. Mixing and its influence on the crystallization as well as the mutual interference of down-stream processes with the crystallization are also treated. Finally, techniques to characterize the crop are discussed. The third part of the book is dedicated to accounts of actual developments and of carried-out crystallizations. Typical pitfalls and strategies to avoid these as well as the design of robust processes are presented.
Several ceramic parts have already proven their suitability for serial application in automobile engines in very impressive ways, especially in Japan, the USA and in Germany. However, there is still a lack of economical quality assurance concepts. Recently, a new generation of ceramic components, for the use in energy, transportation and environment systems, has been developed. The efforts are more and more system oriented in this field. The only possibility to manage this complex issue in the future will be interdisciplinary cooperation. Chemists, physicists, material scientists, process engineers, mechanical engineers and engine manufacturers will have to cooperate in a more intensive way than ever before. The R&D activities are still concentrating on gas turbines and reciprocating engines, but also on brakes, bearings, fuel cells, batteries, filters, membranes, sensors and actuators as well as on shaping and cutting tools for low expense machining of ceramic components. This book summarizes the scientific papers of the 7th International Symposium "Ceramic Materials and Components for Engines". Some of the most fascinating new applications of ceramic meterials in energy, transportation and environment systems are presented. The proceedings shall lead to new ideas for interdisciplinary activities in the future.
Grounded in current knowledge and professional practice, this book provides up-to-date coverage of psychometric theory, methods, and interpretation of results. Essential topics include measurement and statistical concepts, scaling models, test design and development, reliability, validity, factor analysis, item response theory, and generalizability theory. Also addressed are norming and test equating, topics not typically covered in traditional psychometrics texts. Examples drawn from a dataset on intelligence testing are used throughout the book, elucidating the assumptions underlying particular methods and providing SPSS (or alternative) syntax for conducting analyses. The companion website presents datasets for all examples as well as PowerPoint slides of figures and key concepts. Pedagogical features include equation boxes with explanations of statistical notation, and end-of-chapter glossaries. The Appendix offers extensions of the topical chapters with example source code from SAS, SPSS, IRTPRO, BILOG-MG, PARSCALE, TESTFACT, and DIMTEST.
Crystallization is one of the most ancient and interdisciplinary topics of research known to mankind. Crystals can be organic or inorganic and may be produced from melts, liquid solutions, vapors or even in solid state. Notwithstanding its inherently high complexity, the crystallization process is part of our everyday lives, from ice making in our homes to the most state-of-the-art chemical and electronic industry. In this book, our purpose was to present new insights to the reader, as well as crucial and very useful information for researchers working in this field, while simultaneously creating a comprehensive text about crystallization processes which may serve as a starting point for people with different backgrounds.
In the context of polymer crystallization there are several still open and often controversially debated questions. The present volume addresses issues such as novel general views and concepts. It presents new ideas in a connected and accessible way. The intention is thus not only to provide a summary of the present state-of-the-art to all active works but to provide an entry point to newcomer and graduate students entering the field.
Migmatites are highly heterogeneous rocks found in high-grade metamorphic environments; they are commonly encountered in the continental crust. Until now, many geologists have been deterred from working with migmatites because of their complex appearance and an unhelpful non-genetic nomenclature. In his Atlas of Migmatites, Dr. Edward Sawyer provides genetically based definitions and a system of nomenclature with which it will be possible to describe and map migmatites effectively and to understand how combinations of factors and processes produce a bewildering morphological diversity. Migmatites are produced by partial melting; to aid the reader in the identification of migmatites, the author describes and illustrates microstructures that can be used to infer the presence of melt or a melt-producing reaction. He also describes how geochemical data can be used to infer petrological processes involved in migmatite development. This book includes the results from two decades of research in whole-rock geochemistry, partial melting, microstructural analysis and experimental deformation of partially molten rocks. It contains information from an outcrop through to a grain scale. Exceptionally well illustrated, with 272 colour plates and accompanying detailed captions, the Atlas provides descriptions and analyses of migmatites not previously available.
The classical view on polymer crystallization basically focused on the expla- tion of a few macroscopically observable parameters like the thickness of the resulting lamellar structure and the corresponding growth rates. However, the emerging paradigm for the description of chain crystals is too simple and cannot account for the complex non-equilibrium processes responsible for structure f- mation on various levels, ranging from the nanometer up to the millimeter scale. This complexity detected by several novel experimental results led to a renewed interest in this ”old” topic of polymer crystallization. These new ?ndings c- cern the early stages of the crystallization process, crystal formation in con?ned geometries like ultra-thin ?lms and the competition between (micro)phase s- aration and crystallization in copolymers and blends. In particular, high spatial resolution techniques such as atomic force microscopy provided deeper insight into the molecular organization of crystallizable polymers. Computer simu- tions based on microscopic processes were used to improve our understanding of how polymer crystals are nucleated and how they grow. New ideas emerged about possible multistage pathways which are followed during the formation of polymer lamellae. The importance and the consequences of the non-equilibrium character of polymer crystals got signi?cantly more attention. Links and ana- gies to growth phenomena and pattern formation in general are being developed. However, these ideas are still subject of intensive and controversial discussions.