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Solutions of ethylene glycol are being considered as beat-transfer media for radiators in manned space capsules. This report was prepared to summarize the available corrosion data on uninhibited and inhibited ethylene glycol solutions. Much of the corrosion data are based on automotive and diesel engine coolant systems. Several factors considered are: time dependence, effect of pH, concentration, temperature, aeration, chloride ion, velocity, heat- transfer rate, and galvanic couples. Inhibitors for which corrosion data are presented include: borax, sodium benzoate, sodium nitrite, triethanolamine, Sodium mercaptobenzothiazole, soluble oil, chromates, as well as miscellaneous inhibitors. A number of patented inhibitors based on borax are discussed. Descriptions of test procedures including automobile service tests are presented.
This book makes it easy for you to find what effect environment has on the corrosion of metals and alloys. However, this volume offers information on additional environments including concrete, soil, groundwater, distilled water, sodium acetate and more. ThereAs also updated and expanded coverage of previously discussed environments as well as information on environments which deal with the dairy, food, brewing, aerospace, petrochemical and building industries. The environments are listed alphabetically. Each listing includes a general description of the conditions, a comment on the corrosion characteristics of various alloys in such a situation, a bibliography of recent articles specific to the environment, tables consolidating and comparing corrosion rates at various temperatures and concentrations for various alloys, and graphical information. Also included are summaries on the general corrosion characteristics of major metals and alloys.
The corrosion behavior of aluminum, copper, and iron in inhibited ethylene glycol-ASTM corrosive water solutions was evaluated in a laboratory loop under isothermal and heat-flux conditions for 1000 h at temperatures between 378 and 413/sup 0/K, in static autoclave tests at 450/sup 0/K for 500 h, and by potentiodynamic polarization measurements at temperatures between 298 and 348/sup 0/K. The effect of time, temperature, and ethylene glycol concentration of the heat-transfer fluid on the extent of inhibitor depletion was determined from analyses of the reserve alkalinity, pH, and inhibitor content of the solutions. The performance of an electrochemical sensor as a monitor of fluid quality was also evaluated. A heat flux of 0.4 to 1.0 kW/m/sup 2/ did not have a significant effect on the corrosion behavior of the various materials at temperatures between 378 and 413/sup 0/K. The corrosion rates of aluminum, copper, and iron in the 50 volume percent inhibited ethylene glycol-corrosive water solution decreased as a function of time during the 1000-h test. At 413/sup 0/K, the corrosion rate of copper was considerably higher than that of iron or aluminum at low flow velocity. Significant degradation of the fluid quality, as indicated by the measurement of the pH, reserve alkalinity, and inhibitor concentrations, occurred after several hundred hours at temperatures of approx. 450/sup 0/K.
This book is a comprehensive guide to the compositions, properties, processing, performance, and applications of nickel, cobalt, and their alloys. It includes all of the essential information contained in the ASM Handbook series, as well as new or updated coverage in many areas in the nickel, cobalt, and related industries.
This book provides an overview of causes, types of corrosion and inhibitors to combat corrosion. The corrosion journals in this book provide broad international coverage of research and practice in corrosion processes and corrosion control. Peer-reviewed contributions address all aspects of corrosion engineering and corrosion science; there is strong emphasis on effective design and materials selection to combat corrosion and the journal carries failure case studies to further knowledge in these areas.
These volumes cover the properties, processing, and applications of metals and nonmetallic engineering materials. They are designed to provide the authoritative information and data necessary for the appropriate selection of materials to meet critical design and performance criteria.