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Constitutive Equations for Polymer Melts and Solutions presents a description of important constitutive equations for stress and birefringence in polymer melts, as well as in dilute and concentrated solutions of flexible and rigid polymers, and in liquid crystalline materials. The book serves as an introduction and guide to constitutive equations, and to molecular and phenomenological theories of polymer motion and flow. The chapters in the text discuss topics on the flow phenomena commonly associated with viscoelasticity; fundamental elementary models for understanding the rheology of melts, solutions of flexible polymers, and advanced constitutive equations; melts and concentrated solutions of flexible polymer; and the rheological properties of real liquid crystal polymers. Chemical engineers and physicists will find the text very useful.
Bringing together the world's leading researchers and practitioners of computational mechanics, these new volumes meet and build on the eight key challenges for research and development in computational mechanics.Researchers have recently identified eight critical research tasks facing the field of computational mechanics. These tasks have come about because it appears possible to reach a new level of mathematical modelling and numerical solution that will lead to a much deeper understanding of nature and to great improvements in engineering design.The eight tasks are: - The automatic solution of mathematical models - Effective numerical schemes for fluid flows - The development of an effective mesh-free numerical solution method - The development of numerical procedures for multiphysics problems - The development of numerical procedures for multiscale problems - The modelling of uncertainties - The analysis of complete life cycles of systems - Education - teaching sound engineering and scientific judgement Readers of Computational Fluid and Solid Mechanics 2003 will be able to apply the combined experience of many of the world's leading researchers to their own research needs. Those in academic environments will gain a better insight into the needs and constraints of the industries they are involved with; those in industry will gain a competitive advantage by gaining insight into the cutting edge research being carried out by colleagues in academia. Features - Bridges the gap between academic researchers and practitioners in industry - Outlines the eight main challenges facing Research and Design in Computational mechanics and offers new insights into the shifting the research agenda - Provides a vision of how strong, basic and exciting education at university can be harmonized with life-long learning to obtain maximum value from the new powerful tools of analysis
This is the second edition of Melt Rheology and its Role in Plastics Processing, although the title has changed to reflect its broadened scope. Advances in the recent years in rheometer technology and polymer science have greatly enhanced the usefulness of rheology in the plastics industry. It is now possible to design polymers having specific molecular structures and to predict the flow properties of melts having those structures. In addition, rheological properties now provide more precise information about molecular structure. This book provides all the information that is needed for the intelligent application of rheology in the development of new polymers, the determination of molecular structure and the correlation of processability with laboratory test data. Theory and equations are limited to what is essential for the use of rheology in the characterization of polymers, the development of new plastics materials and the prediction of plastics processing behavior. The emphasis is on information that will be of direct use to practitioners. Extensive references are provided for those wishing to pursue certain issues in greater depth. While the primary audience is applied polymer scientists and plastics engineers, the book will also be of use to postgraduate students in polymer science and engineering and as a text for a graduate course.
Integrating latest research results and characterization techniques, this book helps readers understand and apply fundamental principles in nonlinear polymer rheology. The author connects the basic theoretical framework with practical polymer processing, which aids practicing scientists and engineers to go beyond the existing knowledge and explore new applications. Although it is not written as a textbook, the content can be used in an upper undergraduate and first year graduate course on polymer rheology. • Describes the emerging phenomena and associated conceptual understanding in the field of nonlinear polymer rheology • Incorporates details on latest experimental discoveries and provides new methodology for research in polymer rheology • Integrates latest research results and new characterization techniques like particle tracking velocimetric method • Focuses on the issues concerning the conceptual and phenomenological foundations for polymer rheology • Has a companion website for readers to access with videos complementing the content within several chapters
The areas of suspension mechanics, stability and computational rheology have exploded in scope and substance in the last decade. The present book is one of the first of a comprehensive nature to treat these topics in detail. The aim of the authors has been to highlight the major discoveries and to present a number of them in sufficient breadth and depth so that the novice can learn from the examples chosen, and the expert can use them as a reference when necessary.The first two chapters, grouped under the category General Principles, deal with the kinematics of continuous media and the balance laws of mechanics, including the existence of the stress tensor and extensions of the laws of vector analysis to domains bounded by fractal curves or surfaces. The third and fourth chapters, under the heading Constitutive Modelling, present the tools necessary to formulate constitutive equations from the continuum or the microstructural approach. The last three chapters, under the caption Analytical and Numerical Techniques, contain most of the important results in the domain of the fluid mechanics of viscoelasticity, and form the core of the book.A number of topics of interest have not yet been developed to a theoretical level from which applications can be made in a routine manner. However, the authors have included these topics to make the reader aware of the state of affairs so that research into these matters can be carried out. For example, the sections which deal with domains bounded by fractal curves or surfaces show that the existence of a stress tensor in such regions is still open to question. Similarly, the constitutive modelling of suspensions, especially at high volume concentrations, with the corresponding particle migration from high to low shear regions is still very sketchy.
This title addresses the latest developments in the field, covering the major advances that have occurred over the past five years in the polymerization and structure of new generation polystyrenes that are broadening its scope of application. It covers the advent of branched polystyrenes, syndiotactic polystyrene, high-molecular weight general purpose PS, styrenic interpolymers, and clear SBS copolymers Presents voluminous research previously only reported at conferences in one reference Unique coverage of a topic not found in the field
Integrating fundamental research with the technical applications of this rapidly evolving field, Structure and Functional Properties of Colloidal Systems clearly presents the connections between structure and functional aspects in colloid and interface science. It explores the physical fundamentals of colloid science, new developments of synthesis