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Industrial applications of Metal complexes have gained significant importance especially in the area of Catalysis in the last three decades. Scope for further development of such applications is extensive as several biological processes in living cells involve metal complexes. Coordination Chemistry is a subject uniquely involving application of Quantum Mechanics, Spectroscopy, Kinetics, Catalysis, Biology and Industrial Chemistry. This book has been written keeping these important aspects of the subject in mind.
This textbook is divided into six parts: theoretical concepts and hydrogen, the s-block, the p-block, the d-block, the f-block, and other topics (the nucleus and spectra). It also focuses on the commercial exploitation of inorganic chemicals and the treatment of the inorganic aspects of environmental chemistry has also been extended.· Atomic structure and the Periodic table· Introduction to bonding· The ionic bond· The covalent bond· The metallic bond· General properties of the elements· Coordination compounds· Hydrogen and the hydrides· Group 1 - The alkali metals· The chlor-alkali industry· Group 2 - The alkaline earth elements· The group 13 elements· The group 14 elements· The group 15 elements· Group 16 - the chalcogens· Group 17 - the halogens· Group 18 - the noble gases· An introduction to the transition elements· Group 3 - The scandium group· Group 4 - The titanium group· Group 5 - The vanadium group· Group 6 - The chromium group· Group 7 - The manganese group· Group 8 - The iron group· Group 9 - The cobalt group· Group 10 - The nickel Group· Group 11 - The copper group: Coinage metals· Group 12 - The zinc group· The lanthanide series· The actinides· The atomic nucleus· Spectra
This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.
This textbook provides essential information for students of inorganic chemistry or for chemists pursuing self-study. The presentation of topics is made with an effort to be clear and concise so that the book is portable and user friendly. Inorganic Chemistry 2E is divided into five major themes (structure, condensed phases, solution chemistry, main group and coordination compounds) with several chapters in each. There is a logical progression from atomic structure to molecular structure to properties of substances based on molecular structures, to behavior of solids, etc. The author emphasizes fundamental principles-including molecular structure, acid-base chemistry, coordination chemistry, ligand field theory, and solid state chemistry -and presents topics in a clear, concise manner. There is a reinforcement of basic principles throughout the book. For example, the hard-soft interaction principle is used to explain hydrogen bond strengths, strengths of acids and bases, stability of coordination compounds, etc. The book contains a balance of topics in theoretical and descriptive chemistry. New to this Edition: New and improved illustrations including symmetry and 3D molecular orbital representationsExpanded coverage of spectroscopy, instrumental techniques, organometallic and bio-inorganic chemistryMore in-text worked-out examples to encourage active learning and to prepare students for their exams . Concise coverage maximizes student understanding and minimizes the inclusion of details students are unlikely to use. . Discussion of elements begins with survey chapters focused on the main groups, while later chapters cover the elements in greater detail. . Each chapter opens with narrative introductions and includes figures, tables, and end-of-chapter problem sets.
The 'Red Book' is the definitive guide for scientists requiring internationally approved inorganic nomenclature in a legal or regulatory environment.
Joseph Chatt was a pioneering figure in coordination chemistry. Intended as a record of Chatt's life, work, and influence, this book begins with a description of Chatt's career presented by co-workers, contemporaries, and students, then goes on to show that many of today's leading practitioners in the field have been influenced by Chatt. The latest research in coordination chemistry is presented to highlight Chatt's continuing legacy, in sections on the synthesis and reactivity of hydrido and dihydrogen complexes, the chemistry of phosphines, transition metal complexes of olefins and related isolobal ligands, chemistry related to dinitrogen complexes, the biological work of the ARC unit of nitrogen fixation at the University of Sussex, and patterns and generalizations in stability and reactivity. Leigh is affiliated with the University of Sussex, UK, and Winterton is affiliated with the University of Liverpool, UK. The book is distributed in the US by Springer Verlag. Annotation copyrighted by Book News Inc., Portland, OR.
Advanced Inorganic Chemistry - Volume II is a concise book on basic concepts of inorganic chemistry. Beginning with Coordination Chemistry, it presents a systematic treatment of all Transition and Inner-Transition chemical elements and their compounds according to the periodic table. Special topics such as Pollution and its adverse effects, chromatography, use of metal ions in biological systems, to name a few, are discussed to provide additional relevant information to the students. It primarily caters to the undergraduate courses (Pass and Honours) offered in Indian universities.