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Fluid flow and solute transport within the vadose zone, the unsaturated zone between the land surface and the water table, can be the cause of expanded plumes arising from localized contaminant sources. An understanding of vadose zone processes is, therefore, an essential prerequisite for cost-effective contaminant remediation efforts. In addition, because such features are potential avenues for rapid transport of chemicals from contamination sources to the water table, the presence of fractures and other channel-like openings in the vadose zone poses a particularly significant problem, Conceptual Models of Flow and Transport in the Fractured Vadose Zone is based on the work of a panel established under the auspices of the U.S. National Committee for Rock Mechanics. It emphasizes the importance of conceptual models and goes on to review the conceptual model development, testing, and refinement processes. The book examines fluid flow and transport mechanisms, noting the difficulty of modeling solute transport, and identifies geochemical and environmental tracer data as important components of the modeling process. Finally, the book recommends several areas for continued research.
DOE faces the remediation of numerous contaminated sites, such as those at Hanford, INEEL, LLNL, and LBNL, where organic and/or radioactive wastes were intentionally or accidentally released to the vadose zone from surface spills, underground tanks, cribs, shallow ponds, and deep wells. Migration of these contaminants through the vadose zone has led to the contamination of (or threatens to contaminate) underlying groundwater. A key issue in choosing a corrective action plan to clean up contaminated sites is the determination of the location, total mass, mobility and travel time to receptors for contaminants moving in the vadose zone. These problems are difficult to solve in a technically defensible and accurate manner because contaminants travel downward intermittently, through narrow pathways, driven by variations in environmental conditions. These preferential flow pathways can be difficult to find and predict. The primary objective of this project is to determine if and when dynamical chaos theory can be used to investigate infiltration of fluid and contaminant transport in heterogeneous soils and fractured rocks. The objective of this project is being achieved through the following activities: Development of multi scale conceptual models and mathematical and numerical algorithms for flow and transport, which incorporate both (a) the spatial variability of heterogeneous porous and fractured media and (b) the temporal dynamics of flow and transport; Development of appropriate experimental field and laboratory techniques needed to detect diagnostic parameters for chaotic behavior of flow; Evaluation of chaotic behavior of flow in laboratory and field experiments using methods from non-linear dynamics; Evaluation of the impact these dynamics may have on contaminant transport through heterogeneous fractured rocks and soils and remediation efforts. This approach is based on the consideration of multi scale spatial heterogeneity and flow phenomena that are affected by nonlinear dynamics, and in particular, chaotic processes. The scientific and practical value of this approach is that we can predict the range within, which the parameters of flow and transport change with time, which allows us to design and manage the remediation even when we cannot predict the behavior at any point or time.
(1) To determine if and when dynamical chaos theory can be used to investigate infiltration of fluid and contaminant transport in heterogeneous soils and fractured rocks. (2) To introduce a new approach to the multiscale characterization of flow and transport in fractured basalt vadose zones and to develop physically based conceptual models on a hierarchy of scales. The following activities are indicative of the success in meeting the project s objectives: A series of ponded infiltration tests, including (1) small-scale infiltration tests (ponded area 0.5 m2) conducted at the Hell s Half Acre site near Shelley, Idaho, and (2) intermediate-scale infiltration tests (ponded area 56 m2) conducted at the Box Canyon site near Arco, Idaho. Laboratory investigations and modeling of flow in a fractured basalt core. A series of small-scale dripping experiments in fracture models. Evaluation of chaotic behavior of flow in laboratory and field experiments using methods from nonlinear dynamics; Evaluation of the impact these dynamics may have on contaminant transport through heterogeneous fractured rocks and soils, and how it can be used to guide remediation efforts; Development of a conceptual model and mathematical and numerical algorithms for flow and transport that incorporate (1) the spatial variability of heterogeneous porous and fractured media, and (2) the description of the temporal dynamics of flow and transport, both of which may be chaotic. Development of appropriate experimental field and laboratory techniques needed to detect diagnostic parameters for chaotic behavior of flow. This approach is based on the assumption that spatial heterogeneity and flow phenomena are affected by nonlinear dynamics, and in particular, by chaotic processes. The scientific and practical value of this approach is that we can predict the range within which the parameters of flow and transport change with time in order to design and manage the remediation, even when we can not predict the behavior at any point or time.
Fluid flow and solute transport within the vadose zone, the unsaturated zone between the land surface and the water table, can be the cause of expanded plumes arising from localized contaminant sources. An understanding of vadose zone processes is, therefore, an essential prerequisite for cost-effective contaminant remediation efforts. In addition, because such features are potential avenues for rapid transport of chemicals from contamination sources to the water table, the presence of fractures and other channel-like openings in the vadose zone poses a particularly significant problem, Conceptual Models of Flow and Transport in the Fractured Vadose Zone is based on the work of a panel established under the auspices of the U.S. National Committee for Rock Mechanics. It emphasizes the importance of conceptual models and goes on to review the conceptual model development, testing, and refinement processes. The book examines fluid flow and transport mechanisms, noting the difficulty of modeling solute transport, and identifies geochemical and environmental tracer data as important components of the modeling process. Finally, the book recommends several areas for continued research.
Understanding subsurface flow and transport processes is critical for effective assessment, decision-making, and remediation activities for contaminated sites. However, for fluid flow and contaminant transport through fractured vadose zones, traditional hydrogeological approaches are often found to be inadequate. In this project, the authors examine flow and transport through a fractured vadose zone as a deterministic chaotic dynamical process, and develop a model of it in these terms. Initially, they examine separately the geometric model of fractured rock and the flow dynamics model needed to describe chaotic behavior. Ultimately they will put the geometry and flow dynamics together to develop a chaotic-dynamical model of flow and transport in a fractured vadose zone. They investigate water flow and contaminant transport on several scales, ranging from small-scale laboratory experiments in fracture replicas and fractured cores, to field experiments conducted in a single exposed fracture at a basalt outcrop, and finally to a ponded infiltration test using a pond of 7 by 8 m. In the field experiments, the authors measure the time-variation of water flux, moisture content, and hydraulic head at various locations, as well as the total inflow rate to the subsurface. Such variations reflect the changes in the geometry and physics of water flow that display chaotic behavior, which the authors try to reconstruct using the data obtained. In the analysis of experimental data, a chaotic model can be used to predict the long-term bounds on fluid flow and transport behavior, known as the attractor of the system, and to examine the limits of short-term predictability within these bounds. This approach is especially well suited to the need for short-term predictions to support remediation decisions and long-term bounding studies.
DOE faces the remediation of numerous contaminated sites, such as those at Hanford, INEEL, LLNL, and LBNL, where organic and/or radioactive wastes were intentionally or accidentally released to the vadose zone from surface spills, underground tanks, cribs, shallow ponds, and deep wells. Migration of these contaminants through the vadose zone has lead to the contamination of or threatens to contaminate underlying groundwater. A key issue in choosing a corrective action plan to clean up contaminated sites is to determine the location, total mass, mobility and travel time to receptors for contaminants moving in the vadose zone. These problems are difficult to solve in a technically defensible and accurate manner because contaminants travel downward intermittently through narrow pathways driven by variations in environmental conditions. These preferential pathways can be difficult to find and predict. The primary objective of this project is to determine if and when dynamical chaos theory can be used to investigate infiltration of fluid and contaminant transport in heterogeneous soils and fractured rocks. The objective of this project is being achieved through the following Activities (1) Evaluation of chaotic behavior of flow in laboratory and field experiments using methods from non-linear dynamics; (2) Evaluation of the impact these dynamics may have on contaminant transport through heterogeneous fractured rocks and soils, and how it can be used to guide remediation efforts; (3) Development of a conceptual model and mathematical and numerical algorithms for flow and transport, which incorporate both: (a) the spatial variability of heterogeneous porous and fractured media, and (b) the description of the temporal dynamics of flow and transport, which may be chaotic; and (4) Development of appropriate experimental field and laboratory techniques needed to detect diagnostic parameters for chaotic behavior of flow. This approach is based on the assumption that spatial heterogeneity and flow phenomena are affected by non-linear dynamics, and in particular, chaotic processes. The scientific and practical value of this approach is that the authors can predict the range within which the parameters of flow and transport change with time in order to design and manage the remediation, even when the authors can not predict the behavior at any point or time. This progress report summarizes work after 1.5 years of a 3-year project.
Understanding subsurface flow and transport processes is critical for effective assessment, decision-making, and remediation activities for contaminated sites. However, for fluid flow and contaminant transport through fractured vadose zones, traditional hydrogeological approaches are often found to be inadequate. In this project, the authors examine flow and transport through a fractured vadose zone as a deterministic chaotic dynamical process, and develop a model of it in these terms. Initially, the authors examine separately the geometric model of fractured rock and the flow dynamics model needed to describe chaotic behavior. Ultimately they will put the geometry and flow dynamics together to develop a chaotic-dynamical model of flow and transport in a fractured vadose zone. They investigate water flow and contaminant transport on several scales, ranging from small-scale laboratory experiments in fracture replicas and fractured cores, to field experiments conducted in a single exposed fracture at a basalt outcrop, and finally to a ponded infiltration test using a pond of 7 by 8 m. In the field experiments, they measure the time-variation of water flux, moisture content, and hydraulic head at various locations, as well as the total inflow rate to the subsurface. Such variations reflect the changes in the geometry and physics of water flow that display chaotic behavior, which they try to reconstruct using the data obtained. In the analysis of experimental data, a chaotic model can be used to predict the long-term bounds on fluid flow and transport behavior, known as the attractor of the system, and to examine the limits of short-term predictability within these bounds. This approach is especially well suited to the need for short-term predictions to support remediation decisions and long-term bounding studies. View-graphs from ten presentations made at the annual meeting held December 3--4, 1997 are included in an appendix to this report.
The Department of Energy Environmental Management Program is faced with two major issues involving two-phase flow in fractured rock; specifically, transport of dissolved contaminants in the Vadose Zone, and the fate of Dense Nonaqueous Phase Liquids (DNAPLs) below the water table. Conceptual models currently used to address these problems do not correctly include the influence of the fractures, thus leading to erroneous predictions. Recent work has shown that it is crucial to understand the topology, or 'structure' of the fluid phases (air/water or water/DNAPL) within the subsurface.
The Department of Energy Environmental Management Program is faced with two major issues involving two-phase flow in fractured rock; specifically, transport of dissolved contaminants in the Vadose Zone, and the fate of Dense Nonaqueous Phase Liquids (DNAPLs) below the water table. Conceptual models currently used to address these problems do not correctly include the influence of the fractures, thus leading to erroneous predictions. Recent work has shown that it is crucial to understand the topology, or ''structure'' of the fluid phases (air/water or water/DNAPL) within the subsurface. It has also been shown that even under steady boundary conditions, the influence of fractures can lead to complex and dynamic phase structure that controls system behavior, with or without the presence of a porous rock matrix. Complicated phase structures within the fracture network can facilitate rapid transport, and lead to a sparsely populated and widespread distribution of concentrated contaminants; these qualities are highly difficult to describe with current conceptual models. The focus of our work is to improve predictive modeling through the development of advanced conceptual models for two-phase flow in fractured rock.
Mankind has manipulated the quantity and quality of soil water for millennia. Food production was massively increased through fertilization, irrigation and drainage. But malpractice also caused degradation of immense areas of once fertile land, rendering it totally unproductive for many generations. In populated areas, the pollutant load ever more often exceeds the soil’s capacity for buffering and retention, and large volumes of potable groundwater have been polluted or are threatened to be polluted in the foreseeable future. In the past decades, the role of soil water in climate patterns has been recognized but not yet fully understood. The soil-science community responded to this diversity of issues by developing numerical models to simulate the behavior of water and solutes in soils. These models helped improve our understanding of unsaturated-zone processes and develop sustainable land-management practices. Aimed at professional soil scientists, soil-water modelers, irrigation engineers etc., this book discusses our progress in soil-water modeling. Top scientists present case studies, overviews and analyses of strengths, weaknesses, opportunities and threats related to soil-water modeling. The contributions cover a wide range of spatial scales, and discuss fundamental aspects of unsaturated-zone modeling as well as issues related to the application of models to real-world problems.