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Vapor-liquid equilibrium (VLE) data are necessary for the design and operation of distillation processes. It is absolutely impossible to determine a distillation process without VLE data. The author of this book has had much experience designing and constructing distillation processes and towers and knows that VLE data must be easily retrievable, readily comprehensible, and precise. This volume contains the most important VLE data for 1,446 binary systems with Wilson parameters determined by computer processing. The data are also presented graphically. The Wilson equation, which is known as one of the most applicable to multicomponent systems, is employed for computer-aided determination of the optimum parameters using the non-linear least squares method.
High pressure vapor-liquid equilibrium data are important when very pure compounds are to be prepared, and they are also needed for high pressure liquid or supercritical chromatography. This volume is a compilation of high pressure vapor-liquid equilibrium data for 700 binary system, processed and plotted by computer for ready inspection of the whole spectrum. The information given for each system comprises: the components' names, chemical formulae, cited literature, and critical temperature, critical pressures, acentric factors of the components, optimized values of the parameters for the Peng-Robinson equations, the errors, and phase diagrams for visual comparison of the experimental data and calculated values. An alphabetical index by system name is included in the book which will be a useful reference for chemical engineers, research chemists, and graduate students who are interested in the chemical process industry.