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Solvents, Surfactants, Solutes and Solids
CO2-responsive materials are a relatively recent innovation. In general, stimuli-responsive materials exhibit reversible changes in their physical or chemical properties in response to external triggers such as temperature, pH, light, or voltage. However, there are often limitations in applying these triggers including economic and environmental costs, and product contamination. The realization that CO2 can be used as an effective trigger for stimulating changes in material properties has prompted a surge in interest in this area within the past few years, with numerous new studies currently underway in several countries. CO2 is an ideal trigger for switchable or stimuli-responsive materials because it is benign, inexpensive, green, abundant, and does not accumulate in the system. Many different CO2-responsive materials including polymers, latexes, solvents, solutes, gels, surfactants, and catalysts have been prepared. Summarizing recent progress in the preparation, self-assembly, and functional applications of CO2-responsive materials, this book explores the physical chemistry of CO2-switching, including constraints on structural design and process conditions, together with applications. With emphasis on the environmental, health, and safety advantages and disadvantages compared to conventional materials, it is ideal for researchers and industrialists working in green chemistry, chemical engineering, and polymer chemistry.
Chemical analysis requires solvents, reagents and energy and generates waste. The main goal of green analytical chemistry is to avoid or reduce the undesirable environmental side effects of chemical analysis, while preserving the classic analytical parameters of accuracy, sensitivity, selectivity and precision. This book portrays the current and changing situation concerning adoption of the principles of green chemistry as applied to analysis. It begins by looking at the advantages of and problems associated with on-site analysis and how analytical techniques can lead to increased productivity, efficiency and accuracy, and thereby reduce the consumption of materials. It then focuses on sample preparation techniques minimising solvent consumption or using alternative solvents, concepts and methods of improving the ‘greenness’ of instrumental analysis where miniaturization is an important part, separation methods from the perspective of green analytical chemistry and chemometrics approaches, which can reduce or can even remove the need for conventional steps in chemical analysis. Aimed at graduates and novices just entering the field, managers of analytical research laboratories, teachers of analytical chemistry and green public policy makers, this title will be a useful addition to any analytical scientist's library.
Green Sustainable Process for Chemical and Environmental Engineering and Science: Switchable Solvents explores the preparation, properties, chemical processes and applications of this class of green solvents. The book provides an in-depth overview on the area of switchable solvents in various industrial applications, focusing on the purification and extraction of chemical compounds utilizing green chemistry protocols that include liquid-liquid, solid-liquid, liquid-gas and lipids separation technologies. In addition, it includes recent advances in greener extraction and separation processes. This book will be an invaluable guide to students, professors, scientists and R&D industrial specialists working in the field of sustainable chemistry, organic, analytical, chemical engineering, environmental and pharmaceutical sciences. - Provides a broad overview of switchable solvents in sustainable chemical processes - Compares the use of switchable solvents as greener solvents over conventional solvents - Outlines eco-friendly organic synthesis and chemical processes using switchable solvents - Lists various industrial separations/extraction processes using switchable solvents
Many of the polymers we use every day are highly flammable. Historically, a large number of home fires were caused by ignited polymeric materials until legislation was introduced requiring fire retardants to be added to these materials. Fire retardants increase the time it takes for materials to ignite, providing valuable time to prevent a fire or escape. However, it has become apparent that many of the traditional treatments used as fire retardants are harmful to human health and highly persistent in the environment. With evermore polymeric materials in our homes and lives it is still highly valuable to be able to make fire retardants, but consideration must be given to their environmental impact and sustainability. Green Fire Retardants for Polymeric Materials looks at both the choice of different materials and treatments for improving the fire retardancy of polymeric materials, as well as green approaches to synthesising these fire retardants. It is a timely resource both for green chemists interested in real world applications for their work and polymer scientists keen to increase the sustainability of their products and processes.
There is an increasing awareness that materials and chemicals produced from fossil fuels are not sustainable, both in terms of the pollution caused by the extraction and production processes, and the fact that there is only a finite supply of these fossil fuels. Therefore, there is a strong incentive to find sources for chemicals and materials from source materials that we know we can continue to generate. Plants are a source of a wide variety of chemicals, many with interesting properties, and these chemical feedstocks are considered renewable rather than finite. Green Chemistry and Green Materials from Plant Oils and Natural Acids covers the application of these natural materials in producing polymers, lubricants and plasticisers.
The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science.The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics.Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned.Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students.
Special topic volume with invited peer-reviewed papers only
The development of smart materials for environmental applications is a highly innovative and promising new approach to meet the increasing demands from society on water resources and pollution remediation. Smart materials with surfaces that can reversibly respond to stimuli from internal and external environments by changing their properties show great promise as solutions for global environmental issues. Many of these functional materials are inspired by biological systems, that use sophisticated material interfaces to display high levels of adaptability to their environment. Leading researchers present the latest information on the current and potential applications of omniphobic slippery coatings, responsive particle stabilized emulsions and self-healing surfaces among other functional materials. The book contains a section dedicated to water treatment and harvesting, describing and explaining strategies such as use of copolymer membranes and surfaces with patterned wettability. It provides a valuable source of information for environmental, materials, polymer and nano-scientists interested in environmental applications of functional material surfaces.
Transportation remains one of the largest contributors to global carbon dioxide emissions with the majority of vehicles using fossil-based fuels such as gasoline and diesel. Therefore, alternatives that come from a renewable feedstock and create fewer carbon emissions are urgently needed. Biodiesel, an alternative to fossil-based diesel fuel, can be produced from renewable or waste feedstocks such as biomass, animal fats and industrial wastes making it much more sustainable. However, challenges remain in improving and refining the properties of biodiesel, developing production processes and choosing feedstocks with optimal sustainability. Focusing on recent advances in the areas of feedstocks for biodiesel, production processes, and testing and enhancement of properties, Developments in Biodiesel provides a balance between academic and industrial viewpoints across a range of topics. It is an ideal reference for both academics and industrialists interested in sustainable energy, sustainable fuels and biomass/waste valorisation.