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A review of the issues surrounding clays in the mineral processing value chain, from mining to processing and waste disposal.
Clays are increasingly becoming a major problem in the mining, extraction and value-adding processes for a wide range of commodity raw materials. Clays can impact negatively on virtually every unit process within the mining and minerals processing sector, having long-term environmental implications that go well beyond the lifetime of the mining operation. This book is the first to compile, explain and evaluate the effects of clays in the mineral processing value chain, from mining to minerals processing, and finally, tailings disposal. Focusing on topics from the chemistry and rheology of clays to their detection and dissolution behaviour, this book provides comprehensive coverage of the effects on processes such as settling, preg-robing, flotation and comminution. It is an excellent reference for professional mineralogists and geologists, industrial engineers, and researchers interested in clays and clay minerals.
Clays are increasingly becoming a major problem in the mining, extraction and value-adding processes for a wide range of commodity raw materials. Clays can impact negatively on virtually every unit process within the mining and minerals processing sector, having long-term environmental implications that go well beyond the lifetime of the mining operation. This book is the first to compile, explain and evaluate the effects of clays in the mineral processing value chain, from mining to minerals processing, and finally, tailings disposal. Focusing on topics from the chemistry and rheology of clays to their detection and dissolution behaviour, this book provides comprehensive coverage of the effects on processes such as settling, preg-robing, flotation and comminution. It is an excellent reference for professional mineralogists and geologists, industrial engineers, and researchers interested in clays and clay minerals.
Of huge relevance in a number of fields, this is a survey of the different processes of soil clay mineral formation and the consequences of these processes concerning the soil ecosystem, especially plant and mineral. Two independent systems form soil materials. The first is the interaction of rocks and water, unstable minerals adjusting to surface conditions. The second is the interaction of the biosphere with clays in the upper parts of alteration profiles.
A comprehensive review of environmental remediation is presented with an emphasis on the role of clay minerals in water purification. In the first chapter, important aspects of environmental problems and possible solutions are discussed. In the second chapter, the application of natural clay minerals as environmental cleaning agents are explained. The discussion is focused on the role of different types of clay materials in hazardous substance removal from air, aqueous solutions, wastewater, aquaculture, ground water, etc. In the next chapter, the modification of clay materials is explored including the preparation of clay composite materials for environmental remediation. Various aspects of clay material modifications and the effects of clay surface chemistry on the removal of hazardous material is also discussed. Next, the equilibrium and kinetics of hazardous substance adsorption is presented. This chapter summarizes recent studies on the removal of hazardous substances from aqueous solutions and the environment using various types of clay minerals. The brief also includes various models used in adsorption studies and touches on the characterization of clay minerals.
Introduction to Clay Minerals is designed to give a detailed, concise and clear introduction to clay mineralogy. Using the information presented here, one should be able to understand clays and their mineralogy, their uses and importance in modern life.
This volume is the edited proceedings of a conference seeking to clarify the possible role of clays in the origin of life on Earth. At the heart of the problem of the origin of life lie fundamental questions such as: What kind of properties is a model of a primitive living system required to exhibit and what would its most plausible chemical and molecular makeup be? Answers to these questions have traditionally been sought in terms of properties that are held to be common to all contemporary organisms. However, there are a number of different ideas both on the nature and on the evolutionary priority of 'common vital properties', notably those based on protoplasmic, biochemical and genetic theories of life. This is therefore the first area for consideration in this volume and the contributors then examine to what extent the properties of clay match those required by the substance which acted as the template for life.
The peculiar characteristics of clays provide it with very interesting adsorption qualities, especially for polar or ionisable molecules. Some of these characteristics include the silicates' sheet structure that makes a large surface area accessible for adsorption; the usually significant surface charge that can be responsible for strong electrostatic interactions; and clays' swelling properties and presence of exchangeable surface cations that facilitate ion-exchange mechanisms. Added to their wide availability and associated low cost, these characteristics have motivated in recent years an increasing interest in utilising natural, processed or chemically-modified clays for the removal of organic contaminants from aqueous solutions. This book discusses the application of clay materials for the removal of organic compounds from contaminated waters. It also discusses several other topics that include time and temperature related behaviour of clays; mechanical treatment of clay minerals; the workability of natural clays and clays in the ceramics industry; recent advances in hydraulic performance of clay liners; and the genesis, properties and industrial applications of bauxitic lithomargic clay.
Surface and Interface Chemistry of Clay Minerals, Volume 9, delivers a fundamental understanding of the surface and interface chemistry of clay minerals, thus serving as a valuable resource for researchers active in the fields of materials chemistry and sustainable chemistry. Clay minerals, with surfaces ranging from hydrophilic, to hydrophobic, are widely studied and used as adsorbents. Adsorption can occur at the edges and surfaces of clay mineral layers and particles, and in the interlayer region. This diversity in properties and the possibility to tune the surface properties of clay minerals to match the properties of adsorbed molecules is the basis for study. This book requires a fundamental understanding of the surface and interface chemistry of clay minerals, and of the interaction between adsorbate and adsorbent. It is an essential resource for clay scientists, geologists, chemists, physicists, material scientists, researchers, and students. - Presents scientists and engineers with a resource they can rely on for their own research and work involving clay minerals - Includes an in-depth look at ion exchange, adsorption of inorganic and organic molecules, including polymers and proteins, and catalysis occurring at the surfaces of clay minerals - Includes materials chemistry of clay minerals with chiral clay minerals, optical materials and functional films