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This report presents a cost analysis of Chlorine production from sodium chloride. The process examined is a typical membrane process. In this process, an aqueous solution of sodium chloride (brine) is decomposed electrolytically in a membrane cell, producing Chlorine. Caustic soda (50 wt%) and hydrogen are also generated as products. This report was developed based essentially on the following reference(s): (1) Handbook of Chlor-Alkali Technology, 2005 (2) "Chlorine", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Chlor-Alkali, Caustic Soda, NaOH
This report presents a cost analysis of Isophorone Diisocyanate (IPDI) production from isophorone and chlorine. The process examined is a typical phosgenation process. In this process, isophorone diamine (IPDA) intermediate is initially obtained from isophorone. Then, IPDA reacts with phosgene to produce IPDI. The phosgene used is generated from chlorine and carbon monoxide in an on-site unit. Hydrogen chloride (HCl) is generated as by-product. This report was developed based essentially on the following reference(s): (1) US Patent 9187412 B2, issued to Evonik Degussa in 2015 (2) US Patent 8884063 B2, issued to BASF SE in 2014 (3) US Patent 8563768, issued to Covestro (fromer Bayer MaterialScience) in 2013 Keywords: Isophorone Diisocyanate, IPDI, Isophorone Diamine, IPDA, Phosgenation
This report presents a cost analysis of Calcium Hypochlorite production from slaked lime, sodium hydroxide and chlorine. The process examined is a typical sodium process. This process consists mainly in passing chlorine into a slurry of slaked lime and sodium hydroxide, generating Calcium Hypochlorite and sodium chloride. After separation steps, Calcium Hypochlorite (about 70 wt%) and an aqueous solution of sodium chloride are obtained as products. This report was developed based essentially on the following reference(s): (1) US Patent 4390512, issued to PPG Industries, Inc., in 1983 (2) US Patent 4428919, issued to PPG Industries, Inc., in 1984 Keywords: Caustic Soda, Calcium Salt, Bleaching Powder, Chlorination, Sodium Method, Slaked Lime
This report presents a cost analysis of a typical Aluminium Chloride production process from aluminium metal and chlorine. In the process, chlorine gas is passed through molten aluminium powder in ceramic lined tube shaped reactors, producing Aluminium Chloride. This report examines one-time costs associated with the construction of a United States-based plant and the continuing costs associated with the daily operation of such a plant. More specifically, it discusses: * Capital Investment, broken down by: - Total fixed capital required, divided in production unit (ISBL); infrastructure (OSBL) and contingency - Alternative perspective on the total fixed capital, divided in direct costs, indirect costs and contingency - Working capital and costs incurred during industrial plant commissioning and start-up * Production cost, broken down by: - Manufacturing variable costs (raw materials, utilities) - Manufacturing fixed costs (maintenance costs, operating charges, plant overhead, local taxes and insurance) - Depreciation and corporate overhead costs * Raw materials consumption, products generation and labor requirements * Process block flow diagram and description of industrial site installations (production unit and infrastructure) Keywords: Aluminum Trichloride, Aluminium Scrap, Anhydrous Aluminium Chloride
This report presents a cost analysis of a typical Aluminum Chloride production process from aluminum metal and chlorine. In the process, chlorine gas is passed through molten aluminum in ceramic-lined, tube-shaped reactors, producing Anhydrous Aluminum Chloride. This report was developed based essentially on the following reference(s): (1) "Aluminum Chloride", McKetta, J., Inorganic Chemicals Handbook. Vol. 1 (2) "Aluminum Compounds, Inorganic", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Aluminum Trichloride, Aluminum Scrap, Anhydrous Aluminum Chloride
This report presents a cost analysis of Propylene Oxide (PO) production from chemical grade (CG) propylene and chlorine. The process examined is a typical chlorohydrin process. In this process, propylene and chlorine first react to produce propylene chlorohydrin intermediate. Then, the chlorohydrin intermediate is dehydrochlorinated to Propylene Oxide. Dichloropropane is generated as by-product in the process. This report was developed based essentially on the following reference(s): "Propylene Oxide", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Chlorohydrination, Saponification, Calcium Oxide, CaO, Calcium Hydroxide, CHPO
This report presents a cost analysis of Allyl Chloride production from chlorine and propylene The process examined is a typical chlorination process. In this process, hydrogen chloride (32 wt%) is generated as by-product. This report was developed based essentially on the following reference(s): (1) "Allyl Compounds", Ullmann's Encyclopedia of Industrial Chemistry, 2005 (2) "Allyl Chloride", Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition Keywords: HCl, 3-Chloropropene, Allyl Alcohol, Epichlorohydrin
This report presents a cost analysis of sodium hypochlorite production from sodium hydroxide and chlorine. The process examined is a typical chemical process. This report was developed based essentially on the following reference(s): "Chlorine Oxides and Chlorine Oxygen Acids", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Bleach, Chlorination, Caustic Soda, NaOH, Solvay Chemicals, Chlor-alkali
This report presents a cost analysis of Ethylene Dichloride (EDC) production from ethylene and chlorine using a direct chlorination process. The process examined is similar to OxyVinyls process. This process consists in a liquid-phase high temperature chlorination (HTC). This report was developed based essentially on the following reference(s): EP Patent 0260650, originally issued to B.F. Goodrich Company (assigned to OxyVinyls in 2000) Keywords: Ethene, 1,2-Dichloroethane, Inovyl, European Vinyls Corporation, EVC
This report presents a cost analysis of Polycarbonate (PC) production from bisphenol A (BPA) and phosgene. The process examined is a typical interfacial process. In this process, BPA, dissolved in an aqueous solution, is reacted with phosgene, in an organic solution, at the interface of the two-phase mixture. The carbonate oligomers produced are then polycondensed to Polycarbonate resin. This report was developed based essentially on the following reference(s): "Polycarbonates", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Thermoplastic Polymer, Interfacial Polymerization, Polycondensation