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Chemical thermodynamics considers the energy transformations which drive or which occur as a result of chemical reactions. It is a central discipline of chemistry and chemical engineering, allowing prediction of the direction of spontaneous chemical change and the position of chemical equilibrium in any reacting system. Being grounded in maths, it is often perceived as a difficult subject and many students are never fully comfortable with it. Chemical Thermodynamics at a Glance provides a concise overview of the main principles of Chemical Thermodynamics for students studying chemistry and related courses at undergraduate level. Based on the highly successful and student friendly “at a Glance” approach, the information is presented in integrated, self contained double page spreads of text and illustrative material. The material developed in this book has been chosen to ensure the student grasps the essence of thermodynamics, so those wanting an accessible overview will find this book an ideal source of the information they require. In addition, the structured presentation will provide an invaluable aid to revision for students preparing for examinations.
Fields of Chemistry, Chemical Engineering & Material Sciences.
This expanded second edition provides a concise overview of the main principles and reactions of heterocyclic chemistry for undergraduate students studying chemistry and related courses. Using a successful and student-friendly "at a glance" approach, this book helps the student grasp the essence of heterocyclic chemistry, ensuring that they can confidently use that knowledge when required. The chapters are thoroughly revised and updated with references to books and reviews; extra examples and student exercises with answers online; and color diagrams that emphasize exactly what is happening in the reaction chemistry depicted.
Chemical Thermodynamics–4 presents the application of experimental methods of chemical thermodynamics. This book discusses the three properties of biological molecules, namely, colossal dimension, exclusive orderliness, and capability to be in different states or conformations depending on conditions. Organized into eight chapters, this book begins with an overview of the trends in thermochemistry that involve complex reaction systems and product mixtures. This text then discusses the problems relating to the standard state of solids and illustrates the utilization of enthalpy-of-mixing-data. Other chapters consider the available heat capacity results in the liquid–gas. This book discusses as well the high-temperature measurement of thermodynamic data for substances of metallurgical interest. The final chapter deals with the important advances in the experimental methods of heat-capacity measurements, including laser-flash calorimetry and the high-resolution heat-capacity calorimeter. This book is a valuable resource for chemists, physical chemists, thermochemists, thermophysicists, nuclear engineers, and research workers.
Thermodynamics is an ever evolving subject. This book aims to introduce to advanced undergraduate students and graduate students the fundamental ideas and notions of the first and second laws of thermodynamics in a manner unavailable in the usual textbooks on the subject of thermodynamics. For example, it treats the notions of unavailable work, compensated and uncompensated heats, and dissipation, which make it possible to formulate the thermodynamic laws in more broadened forms than those in the conventional treatment of equilibrium thermodynamics. It thus strives to prepare students for more advanced subjects of irreversible processes, which are encountered in our everyday scientific activities. In addition, it also aims to provide them with functional and practical knowledge of equilibrium chemical thermodynamics of reversible processes in real fluids. It discusses temperature, work and heat, thermodynamic laws, equilibrium conditions and thermodynamic stability, thermodynamics of reversible processes in gases and liquids, in surfaces, chemical equilibria, reversible processes in electrolyte solutions and dielectrics in static electric and magnetic fields. A couple of examples for irreversible processes associated with fluid flows and chemical pattern formation and wave propagations are discussed as examples for applications of broader treatments of the thermodynamic laws in the realm of irreversible phenomena.
In this volume (volume 1), the fundamental aspects of thermodynamics are presented. The first & second laws of thermodynamics are illustrated. The need to define thermodynamic temperature & the nature of entropy are explained. The book explores the meaning of auxiliary thermodynamic functions, the origin, usefulness & use of partial molar quantities. Gaseous systems & phase equilibrium, in systems where chemical reactions do not take place, are described In volume 2, the tools necessary to study & understand systems in which chemical reactions can take place are developed. The variables of reaction are the keys to understanding. Criteria for chemical equilibrium are established. It is shown how chemical reactions can provide work, as for example, in batteries. For complex systems, the number of independent reactions & their nature have to be determined systematically. The effect of external factors on chemical equilibria is analyzed & illustrated. The formalism necessary to study ideal & real solutions is provided. The various standard states in use & the corresponding activity coefficients are clearly defined. The statistical aspect of thermodynamics is best understood once students are familiar with the rest of the book, for this reason, is treated in the last chapter. Both volumes comply with the latest IUPC recommendations for symbols. Most of the specific mathematical tools are presented either directly in the text if they are used mostly in one chapter, while the others are included in an appendix. A primarily phenomenological approach has been selected to keep chemical thermodynamics easily accessible to beginners. Intermediate steps in the derivations have been kept to enhance the clarity of the presentation. A large number of problems, most of them original, will with complete solutions, are provided. They give this textbook a great pedagogical value. This book is primarily destined to students, graduate students & practicing scientists in the fields of Chemistry, Chemical Engineering & Material Sciences.
This book offers an easy to read, all-embracing history of thermodynamics. It describes the long development of thermodynamics, from the misunderstood and misinterpreted to the conceptually simple and extremely useful theory that we know today. Coverage identifies not only the famous physicists who developed the field, but also engineers and scientists from other disciplines who helped in the development and spread of thermodynamics as well.