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This book provides a concise overview of thermodynamics, and is written in a manner which makes the difficult subject matter understandable. Thermodynamics is systematic in its presentation and covers many subjects that are generally not dealt with in competing books such as: Carathéodory's approach to the Second Law, the general theory of phase transitions, the origin of phase diagrams, the treatment of matter subjected to a variety of external fields, and the subject of irreversible thermodynamics.The book provides a first-principles, postulational, self-contained description of physical and chemical processes. Designed both as a textbook and as a monograph, the book stresses the fundamental principles, the logical development of the subject matter, and the applications in a variety of disciplines. This revised edition is based on teaching experience in the classroom, and incorporates many exercises in varying degrees of sophistication. The stress laid on a didactic, logical presentation, and on the relation between theory and experiment should provide a reader with a more intuitive understanding of the basic principles.Graduate students and professional chemists in physical chemistry and inorganic chemistry, as well as graduate students and professionals in physics who wish to acquire a more sophisticated overview of thermodynamics and related subject matter will find this book extremely helpful. - Takes the reader through various steps to understanding - Review of fundamentals - Development of subject matter - Applications in a variety of disciplines
Fundamentals of Chemical Engineering Thermodynamics is the clearest and most well-organized introduction to thermodynamics theory and calculations for all chemical engineering undergraduates. This brand-new text makes thermodynamics far easier to teach and learn. Drawing on his award-winning courses at Penn State, Dr. Themis Matsoukas organizes the text for more effective learning, focuses on "why" as well as "how," offers imagery that helps students conceptualize the equations, and illuminates thermodynamics with relevant examples from within and beyond the chemical engineering discipline. Matsoukas presents solved problems in every chapter, ranging from basic calculations to realistic safety and environmental applications.
This book is an excellent companion to Chemical Thermodynamics: Principles and Applications. Together they make a complete reference set for the practicing scientist. This volume extends the range of topics and applications to ones that are not usually covered in a beginning thermodynamics text. In a sense, the book covers a "middle ground" between the basic principles developed in a beginning thermodynamics textbook, and the very specialized applications that are a part of an ongoing research project. As such, it could prove invaluable to the practicing scientist who needs to apply thermodynamic relationships to aid in the understanding of the chemical process under consideration. The writing style in this volume remains informal, but more technical than in Principles and Applications. It starts with Chapter 11, whichsummarizes the thermodynamic relationships developed in this earlier volume. For those who want or need more detail, references are given tothe sections in Principles and Applications where one could go to learn more about the development, limitations, and conditions where these equations apply. This is the only place where Advanced Applications ties back to the previous volume. Chapter 11 can serve as a review of the fundamental thermodynamic equations that are necessary for the more sophisticated applications described in the remainder of this book. This may be all that is necessary for the practicing scientist who has been away from the field for some time and needs some review. The remainder of this book applies thermodynamics to the description of a variety of problems. The topics covered are those that are probably of the most fundamental and broadest interest. Throughout the book, examples of "real" systems are used as much as possible. This is in contrast to many books where "generic" examples are used almost exclusively. A complete set of references to all sources of data and to supplementary reading sources is included. Problems are given at the end of each chapter. This makes the book ideally suited for use as a textbook in an advanced topics course in chemical thermodynamics. - An excellent review of thermodynamic principles and mathematical relationships along with references to the relevant sections in Principles and Applications where these equations are developed - Applications of thermodynamics in a wide variety of chemical processes, including phase equilibria, chemical equilibrium, properties of mixtures, and surface chemistry - Case-study approach to demonstrate the application of thermodynamics to biochemical, geochemical, and industrial processes - Applications at the "cutting edge" of thermodynamics - Examples and problems to assist in learning - Includes a complete set of references to all literature sources
Elementary Principles of Chemical Processes, 4th Edition Student International Version prepares students to formulate and solve material and energy balances in chemical process systems and lays the foundation for subsequent courses in chemical engineering. The text provides a realistic, informative, and positive introduction to the practice of chemical engineering.
An introductory textbook presenting the key concepts and applications of thermodynamics, including numerous worked examples and exercises.
This book develops the theory of chemical thermodynamics from first principles, demonstrates its relevance across scientific and engineering disciplines, and shows how thermodynamics can be used as a practical tool for understanding natural phenomena and developing and improving technologies and products. Concepts such as internal energy, enthalpy, entropy, and Gibbs energy are explained using ideas and experiences familiar to students, and realistic examples are given so the usefulness and pervasiveness of thermodynamics becomes apparent. The worked examples illustrate key ideas and demonstrate important types of calculations, and the problems at the end of chapters are designed to reinforce important concepts and show the broad range of applications. Most can be solved using digitized data from open access databases and a spreadsheet. Answers are provided for the numerical problems. A particular theme of the book is the calculation of the equilibrium composition of systems, both reactive and non-reactive, and this includes the principles of Gibbs energy minimization. The overall approach leads to the intelligent use of thermodynamic software packages but, while these are discussed and their use demonstrated, they are not the focus of the book, the aim being to provide the necessary foundations. Another unique aspect is the inclusion of three applications chapters: heat and energy aspects of processing; the thermodynamics of metal production and recycling; and applications of electrochemistry. This book is aimed primarily at students of chemistry, chemical engineering, applied science, materials science, and metallurgy, though it will be also useful for students undertaking courses in geology and environmental science. A solutions manual is available for instructors.
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.
A revised edition of the well-received thermodynamics text, this work retains the thorough coverage and excellent organization that made the first edition so popular. Now incorporates industrially relevant microcomputer programs, with which readers can perform sophisticated thermodynamic calculations, including calculations of the type they will encounter in the lab and in industry. Also provides a unified treatment of phase equilibria. Emphasis is on analysis and prediction of liquid-liquid and vapor-liquid equilibria, solubility of gases and solids in liquids, solubility of liquids and solids in gases and supercritical fluids, freezing point depressions and osmotic equilibria, as well as traditional vapor-liquid and chemical reaction equilibria. Contains many new illustrations and exercises.