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Recent discoveries enabling the growth of crystalline diamond by chemical vapor deposition offer the potential for a wide variety of new applications. This new book examines the state of the technology arising from these discoveries in relation to other allied materials, such as high-pressure diamond and cubic boron nitride. Most of the potential defense, space, and commercial applications are related to diamond's hardness, but some utilize its other qualities, such as optical and electronic properties. The authors review growth processes and discuss techniques for characterizing the resulting materials' properties. Crystalline diamond is emphasized, but other diamond-like materials (e.g. silicon carbide and amorphous carbon containing hydrogen) are also examined. In addition, the authors identify scientific, technical, and economic problems that could impede the rapid exploitation of these materials, and present recommendations covering broad areas of research and development.
Diamond-like carbons (DLCs) display a number of attractive properties that make them versatile coating materials for a variety of applications, including extremely high hardness values, very low friction properties, very low gas permeability, good biocompatibility, and very high electrical resistivity, among others. Further research into this material is required to produce hydrogen-free DLC films and to synthesize it together with other materials, thereby obtaining better film properties. Diamond-Like Carbon Coatings: Technologies and Applications examines emerging manufacturing technologies for DLCs with the aim of improving their properties for use in practical applications. Discusses DLC coatings used in mechanical, manufacturing, and medical applications Details recent developments in the novel synthesis of DLC films Covers advances in understanding of chemical, structural, physical, mechanical, and tribological properties for modern material processing Highlights methods to yield longer service life Considers prospects for future applications of emerging DLC technologies This work is aimed at materials science and engineering researchers, advanced students, and industry professionals.
The use of diamond for electronic applications is not a new idea. As early as the 1920's diamonds were considered for their use as photoconductive detectors. However limitations in size and control of properties naturally limited the use of diamond to a few specialty applications. With the development of diamond synthesis from the vapor phase has come a more serious interest in developing diamond-based electronic devices. A unique combination of extreme properties makes diamond partiCularly well suited for high speed, high power, and high temperature applications. Vapor phase deposition of diamond allows large area films to be deposited, whose properties can potentially be controlled. Since the process of diamond synthesis was first realized, great progress have been made in understanding the issues important for growing diamond and fabricating electronic devices. The quality of both intrinsic and doped diamond has improved greatly to the point that viable applications are being developed. Our understanding of the properties and limitations has also improved greatly. While a number of excellent references review the general properties of diamond, this volume summarizes the great deal of literature related only to electronic properties and applications of diamond. We concentrate only on diamond; related materials such as diamond-like carbon (DLC) and other wide bandgap semiconductors are not treated here. In the first chapter Profs. C. Y. Fong and B. M. Klein discuss the band structure of single-crystal diamond and its relation to electronic properties.
This work, written by leading international authorities, deals with nucleation growth and processing, characterization and electrical, thermal, optical and mechanical properties of thin film diamond. The final chapters are devoted to the broad range of applications of this material.
This book highlights some of the most important structural, chemical, mechanical and tribological characteristics of DLC films. It is particularly dedicated to the fundamental tribological issues that impact the performance and durability of these coatings. The book provides reliable and up-to-date information on available industrial DLC coatings and includes clear definitions and descriptions of various DLC films and their properties.
This volume entitled "Protective Coatings and Thin Films : Synthesis, Characterization and Applications" contains the Proceedings of the NATO Advanced Research Workshop (ARW) held in Alvor, Portugal from May 30 to June 5, 1996. This NATO-ARW was an expert meeting on the surface protection and modification of solid materials subjected to interactions with the environment. The meeting attracted 10 key speakers, 40 contributing speakers and 3 observers from various countries. The existing knowledge and current status of the science and technology related to protective coatings and thin films were assessed through a series of oral presentations, key notes (titles underlined in the volume content) and contributed papers distributed over various sessions dealing with: (a) plasma-assisted physical and chemical vapor deposition processes to enhance wear and corrosion protection of materials, (b) low friction coatings operating in hostile environment (vacuum, space, extreme temperatures, . . . ), (c) polymer films for protection against mechanical damage and chemical attack, (d) characterization of the structure of films and correlations with mechanical properties, (e) wear and corrosion resistant thermal spray coatings, (f) functional gradient ceramic/metallic coatings produced by high energy laser beam and energetic deposition processes for high temperature applications, (g) protective coatings for optical systems, and (h) ion beam assisted deposition of coatings for protection of materials against aqueous corrosion.
All living things contain carbon in some form, as it is the primary component of macromolecules including proteins, lipids, nucleic acids (RNA and DNA), and carbohydrates. As a matter of fact, it is the backbone of all organic (chemistry) compounds forming different kinds of bonds. Carbon: The Black, the Gray and the Transparent is not a complete scientific history of the material, but a book that describes key discoveries about this old faithful element while encouraging broader perspectives and approaches to its research due to its vast applications. All allotropes of carbon are described in this book, along with their properties, uses, and methods of procurement or manufacturing. Black carbon is represented by coal, gray carbon is represented by graphite, and transparent carbon is represented by diamond.
Magnetic recording is presently a $50 billion industry. It spans audio, video, and digi tal applications in the form of tapes and disks. The industry is expected to grow by a factor of five or more in the next decade. This growth will be accompanied by dramatic improvements in the technology, and the potential exists for magnetic-recording den sities to improve by at least one order of magnitude! Magnetic-recording process is accomplished by relative motion between a mag netic head and a magnetic medium. Types of magnetic media for digital recording are: flexible media (tapes and floppy disks) and rigid disks. Physical contact between head and medium occurs during starts and stops and hydrodynamic air film develops at high speeds. Hying heights (mean separation between head and medium) are on the order of 0. 1 micrometer comparable to surface roughness of the mating members. Need for higher and higher recording densities requires that surfaces be as smooth as possible and flying heights be as low as possible. Smoother surfaces lead to increased static/ kinetic friction and wear. In the case of magnetic tapes, in order to have high bit capac ity for a given size of a spool, we like to use as thin a tape substrate as possible. Thinner tapes are prone to local or bulk viscoelastic deformation during storage. This may lead to variations in head-tape separations resulting in problems in data reliability.